GB2048286A - Polyalkylene Terephthalate and Organopolysiloxane-Polycarbonate Block Copolymer Blends - Google Patents
Polyalkylene Terephthalate and Organopolysiloxane-Polycarbonate Block Copolymer Blends Download PDFInfo
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- GB2048286A GB2048286A GB7914502A GB7914502A GB2048286A GB 2048286 A GB2048286 A GB 2048286A GB 7914502 A GB7914502 A GB 7914502A GB 7914502 A GB7914502 A GB 7914502A GB 2048286 A GB2048286 A GB 2048286A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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Abstract
Blends comprising a polyalkylene terephthalate resin, an organopolysiloxane-polycarbonate block copolymer and a calcium carbonate filler have improved warp and impact properties. The polymer blends can be molded or formed into films, sheets, fibers, laminates, or other improved molded articles of manufacture including reinforced articles by conventional techniques.
Description
SPECIFICATION
Polyalkylene Terephthalate and Organopolysiloxane-polycarbonate Block Copolymer Blends
This invention relates to polymer blends comprising a polyalkylene terephthalate resin, an organopolysiloxane-polycarbonate block copolymer, and a calcium carbonate filler. The polymer blends have improved mechanical properties including improved warp and impact values.
Polyalkylene terephthalate resins are well-known to those skilled in the art-including their associated physical and chemical characteristics--as reported in numerous publications e.g. U.S.
2,465,319 (Whinfield et al). issued March 22, 1949; U.S. 3,047,539 (Pengilly) issued July 31, 1962: U.S. 3,859,246 (Jackson, Jr. et al.) issued January 7, 1 975; U.S. 4,043,971 (Wurmb et al.) issued
August 23, 1977; and the Encyclopedia of Polymer Science and Technology Vol. II, entitled Polyesters, pages 62-128, Interscience Publishers (1969), which publications are incorporated herein in their entirety by reference.
Organopolysiloxane-polycarbonate block copolymers are also well-known to those skilled in the art and are described in various U.S. and foreign patent applications including U.S. 3,821,325 (Merritt,
Jr. et al.) issued June 28, 1974; U.S. 3,419,635 and U,S. 3,419,634 (both of Vaughn, Jr.) both issued December 1968; U.S. 3,832,419 (Merritt, Jr.) issued August 1974 and U.S. 3,189,662 (Vaughn, Jr.) issued June 1 5, 1965, among others.
Heretofore, to the best of the knowledge of applicants, blends of polyalkylene terephthalate resins and organopolysiloxane polycarbonate block copolymers containing calcium carbonate fillers having improved mechanical properties have not been reported by the prior art.
Description of the Invention
This invention embodies polymer blends comprising a polyalkylene terephthalate resin, an organopolysiloxane-polycarbonate block copolymer and a calcium carbonate filler having improved warp and impact properties.
The "polyalkylene terephthalate resin" can be any resin comprising a high molecular weight poly(1,4-alkylene terephthalate) having repeating units of the general formula:
n being a number of from 1 to 50. The poly(1 4-alkylene terephthalate resins can contain mixtures thereof, including copolyesters, i.e. esters that contain a minor amount, e.g. from about 0.5 to about 2% by weight, of repeating units derived from an aliphatic or another aromatic dicarboxylic acid and/or another aliphatic diol or polyol.Among the units which can be present in the copolyesters are those derived from aliphatic dicarboxylic acids, e.g. acids having up to about 50 carbon atoms, including cycloaliphatic, straight and branched chain acids, such as adipic acid, cyclohexanediacetic acid, dimerized Cia is unsaturated acids (which have 32 to 36 carbon atoms), trimerized such acids, and the like. Among the units in the copolyesters can also be minor amounts derived from aromatic dicarboxylic acids, e.g. acids having up to about 36 carbon atoms, such as isophthalic acid and the like.
In a preferred embodiment, in addition to polybutylene terephthalate (PBT) units derived from 1,4butylene glycol, there can also be minor amounts of units derived from other aliphatic glycols and polyols, e.g. di- and polyols having up to about 50 carbon atoms, including ethylene glycol, propylene glycol, cyclohexanediol, and the like. Such copolyesters can be made by techniques well known to those skilled in the art including techniques taught by Winfield et al., U.S. 2,465,319; Pengilly, U.S.
3,047,539, among others.
Illustratively, presently preferred PBT resin blend components have an intrinsic viscosity, when employed in blends containing nonreinforcing and reinforcing fillers, of at least 0.2 and preferably at
least 0.8 deciliters per gram (dl./g.), as measured in o-chlorophenol, a 60/40 phenol-tetrachloroethane mixture or a similar solvent at 25-300C. The upper intrinsic viscosity limit is not critical, however, will generaily be about 2.5 dl./g. Presently preferred PBT resin blend components will have intrinsic viscosity within the ranges of from about 1.0 to about 1.5 when employed in either nonreinforced or reinforced blends.
The "organopolysiloxane-polycarbonate block copolymer" can be any copolymer comprising organopolysiloxane-polycarbonate blocks having repeating units of the general formulae:
where X is an integer equal to 1 to 1000, inclusive, preferably 2 to 100, Z is equal to 1, n is a number average equal to 1 to 100, inclusive, preferably 5 to 50, a is a number average equal to 1.1 to 100, m is equal to 1, and Z is an integer equal to 1 to 1000, inclusive, preferably 5 to 12, E, R, and R' being as defined hereinafter.
Illustratively, well known organopolysiloxane-polycarbonates are described by the following general formulae:
where m is at least 1, and preferably m is an integer equal to from 1 to about 1,000, inclusive, p is equal to from 1 to about 200, inclusive, q is equal to from about 5 to about 200, inclusive, and preferably q has an average value from about 10 to about 90, inclusive, while the ratio of p to q can vary from about 0.005 to about 40, inclusive.B is
A is a member selected from the class of hydrogen and
R is a member selected from the class of hydrogen, monovalent hydrocarbon radicals and halogenated
monovalent hydrocarbon radicals, R' is a member selected from the class of monovalent hydrocarbon
radicals, halogenated monovalent hydrocarbon radicals and cyanoalkyl radicals, R" is a member
selected from the class consisting of monovalent hydrocarbon radicals and halogenated hydrocarbon
radicals, and E is a member selected from the class of hydrogen, lower alkyl radicals and halogen
radicals and mixtures thereof.
Included within the radicals represented by R of Formulas II and Ill are aryl radicals and halogenated aryl radicals such as phenyl, chlorophenyl, xylyl, tolyl, etc.; aralkyl radicals such as phenylethyl, benzyl, etc.; aliphatic, haloaliphatic and cycloaliphatic radicals such as alkyl, alkenyl, cycloalkyl, haloalkyl including methyl, ethyl propyl, chlorobutyl, cyclohexyl, etc.; R can be all the same radical or any two or more of the aforementioned radicals, while R is preferably methyl, R' includes all radicals included by R above except hydrogen, where R' also can be all the same radical or any two or more of the aforementioned R radicals except hydrogen and R' is preferably methyl. R' also includes, in addition to all the radicals included by R, except hydrogen, cyanoalkyl radicals such as cyanoethyl, cyanobutyl, etc. radicals. Radicals that are included within the definition of E of Formulas II and Ill are hydrogen, methyl, ethyl, propyl, chloro, bromo, iodo, etc. and combinations thereof, and E is preferably hydrogen.
The organopolysiloxane-polycarbonate block copolymers can be made by any technique known to those skilled in the art including the techniques described by Merritt, Jr., Merritt, Jr. et al., and
Vaughn Jr. in the U.S. patents referenced in the description of the prior art hereinbefore. Accordingly, all of the procedures described in the aforesaid patents relating to methods for the preparation of the
organopolysiloxane-polycarbonate block copolymers are incorporated herein in their entirety by
reference.
Illustratively presently preferred organopolysiloxane-polycarbonate block copolymers contain
repeating units of Formula II, set out herein before wherein X, Y, Z, a, n and m are as defined
hereafter:
Copolymer Type "A": X equals 7 Y equals --8 to 10
Z equals --1 a equals~2 nequals -10 m equals N1 Copolymer Type "B": X equals -10 Y equals --8 to 10
Z equals --1 a equals "2 "equals --20 m equals~1 Copolymer Type "C":X equals --5 Y equals --8 to 10
Z equals --1 a equals 2 n equals~20 m equals~1 Blends of polyalkylene terephtha late (PAT) resins and organopolysiloxane-polycarbonate (PS-PC) block copolymers comprise blends of any proportion of the aforesaid resins and copolymers. In general, a presently preferred blend contains at least 5 parts of PS-PC block copolymer per 100 parts of PAT resin. Even more preferably are compositions wherein the PS-PC block copolymer component is present in an amount of at least about 5-30 parts, and more preferably from about 10-25 parts per 100 parts of PAT resin.
The calcium carbonate filler can be any calcium carbonate comprising calcium carbonate having a particle size limit of 40 microns, preferably 25 microns and even more preferably having in addition to a top limitation of 25 microns, an average particle size of 10, preferably 5 microns or less. Those skilled in the art recognize calcium carbonate generally can comprise in addition to calcium carbonate as a major constituent derived from limestone other chemical constituents such as silicon dioxide (8it7), aluminum oxide (Al203) and ferric oxide (Fe203) in amounts of less than 3 percent combined and less than about 1-1/2 percent by weight of the calcium carbonate content of the limestone product.
The calcium carbonates can be surface treated with fatty acids, fatty acid soaps, silanes, titanates, or other suitable materials to provide improved dispersibility.
Since the relative proportions of polyalkylene terephthalate resins, organopolysiloxanepolycarbonate block copolymer and calcium carbonate filler significantly affect the warp and impact properties of the polymer blends, calcium carbonate is limited to amounts of less than 35 parts per 100 parts of blend of polyalkylene terephthalate and polysiloxane polycarbonate block copolymer, and preferably is within the range of from about 5-30 and more preferably from 10-25 parts per 100 parts of PAT and PS-PC polymer blend.
Although it is not necessary that a reinforcing agent be present in the compositions of this invention, in another presently preferred embodiment, where glass filaments, e.g. fiber glass, are employed having an aspect ratio (lId), preferably within the range of 1:1 to 100:1 the reinforcing agent is present in amounts of less than about 20 parts, and more preferably less than 10 parts per 100 parts of PAT/PS-PC blend components. As used herein, the term fiberglass refers to the common fiberglass reinforcements used as reinforcing fillers for thermoplastic materials.In addition or as an alternate to fiberglass, other reinforcing agents can be employed, e.g. fibers, whiskers or platelets of metals, e.g. aluminum, iron or nickel and the like; nonmetals, e.g. ceramics, carbon filaments, silicates, asbestos, titanium dioxide and titanate whiskers, and quartz, etc. The term "reinforcing filler" is used herein to define materials which add to the strengths, stiffness and impact strength of the polymer blends. Where the material does not add to all three of the aforementioned properties, the material is defined herein as an extending filler and not a reinforcing filler by definition.
Any of the methods well known to the art can be employed in the preparation of the compositions of this invention. Illustrative techniques include mixing of polyalkylene terephthalate resin organopolysiloxane-polycarbonate block copolymer and calcium carbonate fillers in powder or granular form, extruding and shaping into pellets or other suitable forms. Any reinforcing agent or any other additive can be added to a PAT and PS-PC composition in any conventional manner, e.g. dry mixing, hot melt mixing, etc., employing an extruder, a heated mill or any other mixing device, such as a
Banbury mixer.
The compositions can be molded with any equipment conventionally used for unreinforced or reinforced thermoplastic compositions. For example, good results can be obtained using conventional molding machines, which employ plungers or reciprocating-screws, etc., conventional molding temperatures, e.g. about 450--5000F., and conventional mold temperatures, e.g. 1 500 F.
In order that those skilled in the art may better understand our invention, the following examples are given which are illustrative of the best mode of this invention, however, these examples are not intended to limit the invention in any manner whatsoever. In all the examples, the compositions were prepared in accordance with the following general procedure. Also, in all of the examples, all parts are by weight unless otherwise stated.
General Procedure
A series of blends were prepared from commercially available materials comprising (A) poly(1 4- butylene terephthalate) having an intrinsic viscosity of 1.2 dl./g., measured at 25 OC. in hexafluoroisopropanol, (B) an organopolysiloxane-polycarbonate block copolymer having an intrinsic viscosity within the range of 0.5 to 1.5 dl./g., measured at 250C. in chloroform or methylene chloride, and (C) calcium carbonate by dry blending and precompounding in a hot melt extruder. The extrudate was pelletized. For comparative purposes, compositions containing poly(1,4-butylene terephthalate) alone or in combination were also prepared in pellet form. The resin and copolymer blends, and control compositions were separately molded into appropriate test shapes, e.g. bars, rods, etc.
Example I
Several combinations of polybutylene terephthalate, polysilicone-polycarbonate block copolymer and calcium carbonate were blended at 460-4800 F. in a Werner a Pfleiderertwin screw extruder.
The blends were extruded at a rate of 8 pounds per hour. The extruded blends were injection molded under nominally identical conditions, and injected into appropriate mold samples at 1500 F. A summary of the mechanical properties of the blends with the proportions of the polybutylene terephthalate resin, polysilicone-polycarbonate block copolymer and calcium carbonate fillers are set out in Tables IA, iB and IC hereafter.The test procedures employed to record the physical properties of the blends of this invention and the controls were as follows: Izod Impact Strength (ASTMD 256, Method A), Gardner
Impact Strength (Modified ASTMD 3029-72; 0.625" diameter dart into a 1/8" thick plaque resting on a 0.640" diameter of hole), Tensile Properties-Yield Strength (ASTMD 1822), Flexural Properties (ASTMD 790), Heat Deflection Temperature (ASTMD 648-56). The Warp Index was measured in millimeters and is defined herein as the maximum height attainable above horizontal at the edge of a 4" diameter 1/1 6" disk that a disk reaches when the opposite edge of the disk is pressed flat.
Table IA
Properties of PBT Resin, PS-PC Block Copolymers
and Calcium Carbonate
Run No. 1 2 3 4 5
Composition (parts by weight) Polybutylene Terephthalate(') 100 100 100 100 100 LR-33202 6 12.5 20 CaCO33? 11 12 12.5 13.3
Physical Properties
Impact Strength
Izod (ft-lbs/in. notch) 0.7 0.7 0.9 1.2 1.5
Gardner (in.Ibs.) 240 210 220 270 90
Tensile Properties
Yield Strength (103 psi) 7.0 7.1 6.7 5.9 5.2
Ultimate Elongation (%) 298 90 80 1 50 1 99 Flexural Properties Modulus(105psi) 3.6 3.8 3.4 3.1 3.0
Yield Strength (104 psi) 1.3 1.3 1.2 1.0 1.0
Heat Deflection Temperature at 264 psi (OC) As molded 55 57 57 53 50 Annealed'a' 60 60 57 54 54
Warp Index (mm)
As molded 0 0 0 0 0 Annealed(4) 8.5 4 10.5 6 4 Polybutylene terephthalate-Valox( 310commercial product GE) Company '2'Polysiloxane-polycarbonate-analogous to copolymer Type A, page 6 '3'Superflex-Pfizer average particle size 0.7 microns
4)Annealed for 30 minutes in air at 1770 C. prior to testing
Table IB
Properties of PBT Resin, PS-PC Block Copolymers
and Calcium Carbonate
Run No. 1 2 3 4 5
Composition (parts by weight) Polybutylene Terephthalate(t) 100 100 100 100 100 LR-33202 7 14.3 23 CaCO33 25 27 29 31
Physical Properties
Impact Strength
Izod (ft-lbs/in. notch) 0.7 0.5 0.7 1.0 1.3
Gardner (in.Ibs) 240 160 210 40 160
Tensile Properties Yield Strength (103 psi) 7.0 6.5 6.4 5.6 4.9
Ultimate Elongation (%) 298 21 20 23 44
Flexural Properties
Modulus(105psi) 3.6 4.1 3.9 3.6 3.1
Yield Strength (104psi) 1.3 1.3 1.1 1.1 1.0
Heat Deflection Temperature at 264 psi ( C)
As Molded 55 57 54 53 52
Annealed(a) 60 75 60 57 56
Warp Index (mm)
As Molded O 0 0 0 0 Annealed(4) 8.5 1 0 6 4.5
(1)Polybutylene terephthalate-Valox#310-commercial product GE Company
(2)Polysiloxane-polycarbonateanalogous to copolymer Type A, page 6 3)Superflex-Pfizer# average particle size 0.7 microns
4)Annealed for 30 minutes in air at 177 C prior to testing
Table IC
Properties of PBT Resin, PS-PC Block Copolymers
and Calcium Carbonate
Run No. 1 2 3 4 5
Composition (parts by weight)
Polybutylene Terephthalate(1) 100 100 100 100 100 LR-33202 7.7 16.7 27 CaCO3 3 43 46 50 54
Physical Properties
Impact Strength
Izod (ft-lbs/in. notch) 0.7 0.5 0.5 0.6 0.6
Gardner (in. Ibs.) 240 10 40 8 8
Tensile Properties Yield Strength (103 psi) 7.0 7,4(a) 5.9(a) 5.4(a) 4.3(a)
Ultimate Elongation (%) 298 9 11 11 11
Flexural Properties Modulus(105psi) 3.6 4.8 4.4 4.1 3.4 Yield Strength (104 psi) 1.3 1.3 1.1 1.0 0.8
Heat Deflection Temperature at 264 psi ( C)
As Molded 55 78 61 56 55
Annealed(a) 60 114 64 62 59
Warp Index (mm)
As Molded O 0 0 0 0 Annealed(4) 8.5 0.5 1 5.5 3.5 Specimens did not yield before failure ')Polybutylene terephthalate-Valox 310-commercial product GE Company '2'Polysiloxane-polycarbonate-analogous to copolymer Type A, page 6 3Superflex-Pfizer average particle size 0.7 microns (4)Annealed for 30 minutes in air at 177 C. prior to testing
The polymer blends comprising polyalkylene terephthalate resin, organopolysiloxanepolycarbonate block copolymers and calcium carbonate filler, in both reinforced and unreinforced form as defined herein, can be injection, compression and transfer molded into various shaped articles of manufacture, e.g. automotive and appliance utilized articles, extruded to produce films, and other forms having complicated cross-sections as well as cross head extruded hoses, wires, cables and other substrate covers.
Claims (11)
1. A polymer composition which comprises a polyalkylene terephthalate resin, an organopolysiloxane-polycarbonate block copolymer, and a calcium carbonate filler.
2. A composition as claimed in Claim 1 which comprises at least 5 parts by weight of the copolymer per 100 parts by weight of resin, and less than 35 parts by weight of the carbonate per 100 parts by weight of resin and copolymer.
3. A composition as claimed in Claim 2 which comprises 5 to 30 parts by weight of the copolymer and 5 to 30 parts by weight of the carbonate.
4. A composition as claimed in Claim 2 which comprises 10 to 25 parts by weight of the copolymer and 10 to 25 parts by weight of the carbonate.
5. A composition as claimed in any preceding Claim wherein the copolymer has the formula
where X is from 1 to 1000, Z is equal to 1 ,n is a number average equal to 1 to 100, inclusive, a is a number average equal to 1.1 to 100, m is equal to 1, and Z is 1 to 1000, inclusive, E is hydrogen, lower alkyl, halogen, or a mixture thereof, R is hydrogen, or a monovalent hydrocarbon or halohydrocarbon radical, and R' is a monovalent hydrocarbon or halohydrocarbon radical or cyanoalkyl radical.
6. A composition as claimed in Claim 5 wherein X equals --7; Y equals 8 to 10; Z equals 1; a equals 2; n equals 10; and equals 1.
7. A composition as claimed in Claim 5 wherein X equals 10; Y equals 8 to 10; Z equals 1; a equals 2; n equals 20; and m equals --1.
8. A composition as claimed in Claim 5 wherein X equals 5; Y equals 8 to 10; Z equals 1; a equals 2; n equals 20; and m equals 1.
9. A composition as claimed in any preceding Claim wherein the carbonate has a particle size of less than 40 microns.
10. A composition as claimed in any preceding Claim which comprises less than 20 parts by weight of fiber glass reinforcing filler per 100 parts by weight of resin and copolymer.
11. A composition as claimed in Claim 1 and substantially as hereinbefore described with reference to the Example.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB7914502A GB2048286B (en) | 1979-04-26 | 1979-04-26 | Polyalkylene terephthalate and organopolysiloxane-polycarbonate block copolymer blends |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB7914502A GB2048286B (en) | 1979-04-26 | 1979-04-26 | Polyalkylene terephthalate and organopolysiloxane-polycarbonate block copolymer blends |
Publications (2)
Publication Number | Publication Date |
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GB2048286A true GB2048286A (en) | 1980-12-10 |
GB2048286B GB2048286B (en) | 1983-04-27 |
Family
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Application Number | Title | Priority Date | Filing Date |
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GB7914502A Expired GB2048286B (en) | 1979-04-26 | 1979-04-26 | Polyalkylene terephthalate and organopolysiloxane-polycarbonate block copolymer blends |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2169908A (en) * | 1984-12-12 | 1986-07-23 | Inventa Ag | Moulding materials comprising polyesters |
US4616042A (en) * | 1985-06-14 | 1986-10-07 | General Electric Company | Low temperature impact modified thermoplastic foam |
-
1979
- 1979-04-26 GB GB7914502A patent/GB2048286B/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2169908A (en) * | 1984-12-12 | 1986-07-23 | Inventa Ag | Moulding materials comprising polyesters |
US4616042A (en) * | 1985-06-14 | 1986-10-07 | General Electric Company | Low temperature impact modified thermoplastic foam |
Also Published As
Publication number | Publication date |
---|---|
GB2048286B (en) | 1983-04-27 |
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