GB2038214A - Abrasive tool - Google Patents

Abrasive tool Download PDF

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Publication number
GB2038214A
GB2038214A GB7943002A GB7943002A GB2038214A GB 2038214 A GB2038214 A GB 2038214A GB 7943002 A GB7943002 A GB 7943002A GB 7943002 A GB7943002 A GB 7943002A GB 2038214 A GB2038214 A GB 2038214A
Authority
GB
United Kingdom
Prior art keywords
abrasive
matrix
tool
nickel
resistant layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB7943002A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DIANITE COATINGS Ltd
Original Assignee
DIANITE COATINGS Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DIANITE COATINGS Ltd filed Critical DIANITE COATINGS Ltd
Priority to GB7943002A priority Critical patent/GB2038214A/en
Publication of GB2038214A publication Critical patent/GB2038214A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/04Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
    • B24D3/06Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
    • B24D3/08Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements for close-grained structure, e.g. using metal with low melting point
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D7/00Bonded abrasive wheels, or wheels with inserted abrasive blocks, designed for acting otherwise than only by their periphery, e.g. by the front face; Bushings or mountings therefor
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

An abrasive tool comprises abrasive material 3 held on the tool body 1 by a matrix 2 on whose surface is provided a wear resistant layer 4 to prevent abrasion of the matrix by particles from a workpiece when the tool is in use. The tool may be single or multipoint and used for dressing or drilling. <IMAGE>

Description

SPECIFICATION Abrasive tool This invention relates to an abrasive tool.
Abrasive tools (especially those made with diamond and cubic boron nitrode) are conventionally manufactured by encapsulating one or more abrasive particles in a resin, metal or ceramic matrix. The properties of this matrix have to be balanced between having adequate mechanical properties to retain the abrasive against the mechanical cutting loads, and having extreme wear resistance to resist abrasion by cutting debris. This dual requirement has made it necessary to use expensive matrix materials and, in the case of meal bonded tools, high processing temperatures.
Further, electro-plated tools using abrasives have in the past suffered in many applications from erosion of the electro-deposited matrix, which allows the abrasive particles to be pulled out of the matrix before the end of its useful cutting life.
An object of the invention is to allow the wear resistance of an abrasive tool to be increased.
According to the present invention there is provided an abrasive tool having a tool body, abrasive material held on the tool body by a matrix, and a layer of wear resistant material on the matrix around the abrasive material.
The abrasive material may be encapsulated in the matrix, but preferably projects from the matrix and the wear resistant layer; the matrix should have mechanical properties sufficient to retain the abrasive against mechanical cutting loads.
The matrix may be, for example, bronze, nickel, nickel alloy, iron or iron alloy. The invention allows the use of a material in the matrix having a coefficient of thermal expansion closer to that of the abrasive material than has previously been the case; this is particularly so when the abrasive material is diamond, as the alloy Invar can be used in the matrix by virtue of the invention.
The wear resistant layer may contain a secondary abrasive, preferably in a concentration of from 5 to 65% (most preferably 10 to 40%) and preferably having particle sizes of from 1 to 100 microns.
Diamond or cubic boron nitride are suitable secondary abrasives. The layer may also contain binder material, for example, a matrix of electro-less nickel (such as nickel phosphide or nickel boride) or of resin, plated nickel or plated cobalt. A solid lubricant may also be included in the wear resistant layer, for example, polytetrafluorethylene, graphite or molybdenum disulphide, preferably in particle sizes of from 0 to 100 Ft.
The wear resistant layer may be applied to the matrix by various methods. When a secondary abrasive is present, the layer may be applied by flame spraying, plasma deposition, ion plating, electro-plating or electro-less plating, and subsequent heat treatment may be required. Electro-less plating has been found to be most suitable.
An element, for example chromium, molybdenum, tungsten, aluminium, nickel or boron may be used in the layer and may be applied by solid state diffusion and subsequent heat treatment.
Ion implantation techniques may also be used to improve the properties of the surface layer of the matrix and thereby provide wear resistance.
Embodiments of the present invention will now be described by way of illustration in the following Examples, which refer to the accompanying drawings, in which: Figures 1 to 4are sectional views of portions of abrasive tools of the invention.
Example 1 The abrasive tool shown in Figure 1 has a steel tool body 1 which has applied to it a matrix 2 of nickel. Diamond particles 3 are embedded in the nickel matrix 2 to act as abrasive, and are also held by a wear-resistant layer 4 of a nickel and diamond composite. The diamond particles 3 project beyond the surface ofthewear-resistant layer 4.
The tool of this Example displays excellent resistance to abrasion of its surface by cutting debris when the tool is in use, as the layer 4 confers a great measure of wear resistance to the tool surface, while allowing the inner matrix 2 to be selected for its retention of the diamond 3.
The tool of this Example is produced by electroplating the tool body 1 with nickel around the diamond particles 3 to a depth of 0.004 inch. The matrix 2 thus formed is then coated by electro-less deposition to a depth of 0.002 inch with a composite of 75% by volume nickel and 25% by volume diamond. The diamond particles 3 in this Example are about 0.009 inch in size and therefore extend from the surface of the layer 4 by about one-third of their extent.
Examples 2, 3 and 4 Figures 2, 3, and 4 show respectively a single point tool, a multi-point tool and an abrasive drilling tool, and in each the tool body, matrix, abrasive particles and wear-resistant layer are indicated by the same reference numerals as in Figure 1. The tools of Figures 2 and 3 may be used as surface set wheel dressing tools and the tool of Figure 4 may be used as a surface set drilling bit.
While the depths of the matrix and wear resistant layers are given above only by way of example, it is preferable that the abrasive particles should project from the wear resistant layer of about one-third of their size.
Modifications and improvements can be made without departing from the scope of the invention.
1. An abrasive tool having a tool body, abrasive material held on the tool body by a matrix, and a layer of wear resistant material on the matrix around the abrasive material.
2. An abrasive tool according to Claim 1, wherein the abrasive material is particulate and projects from the wear resistant layer.
3. An abrasive tool according to Claim 2, wherein the abrasive particles project from the wear resistant layer by about one third of their size.
**WARNING** end of DESC field may overlap start of CLMS **.

Claims (16)

**WARNING** start of CLMS field may overlap end of DESC **. SPECIFICATION Abrasive tool This invention relates to an abrasive tool. Abrasive tools (especially those made with diamond and cubic boron nitrode) are conventionally manufactured by encapsulating one or more abrasive particles in a resin, metal or ceramic matrix. The properties of this matrix have to be balanced between having adequate mechanical properties to retain the abrasive against the mechanical cutting loads, and having extreme wear resistance to resist abrasion by cutting debris. This dual requirement has made it necessary to use expensive matrix materials and, in the case of meal bonded tools, high processing temperatures. Further, electro-plated tools using abrasives have in the past suffered in many applications from erosion of the electro-deposited matrix, which allows the abrasive particles to be pulled out of the matrix before the end of its useful cutting life. An object of the invention is to allow the wear resistance of an abrasive tool to be increased. According to the present invention there is provided an abrasive tool having a tool body, abrasive material held on the tool body by a matrix, and a layer of wear resistant material on the matrix around the abrasive material. The abrasive material may be encapsulated in the matrix, but preferably projects from the matrix and the wear resistant layer; the matrix should have mechanical properties sufficient to retain the abrasive against mechanical cutting loads. The matrix may be, for example, bronze, nickel, nickel alloy, iron or iron alloy. The invention allows the use of a material in the matrix having a coefficient of thermal expansion closer to that of the abrasive material than has previously been the case; this is particularly so when the abrasive material is diamond, as the alloy Invar can be used in the matrix by virtue of the invention. The wear resistant layer may contain a secondary abrasive, preferably in a concentration of from 5 to 65% (most preferably 10 to 40%) and preferably having particle sizes of from 1 to 100 microns. Diamond or cubic boron nitride are suitable secondary abrasives. The layer may also contain binder material, for example, a matrix of electro-less nickel (such as nickel phosphide or nickel boride) or of resin, plated nickel or plated cobalt. A solid lubricant may also be included in the wear resistant layer, for example, polytetrafluorethylene, graphite or molybdenum disulphide, preferably in particle sizes of from 0 to 100 Ft. The wear resistant layer may be applied to the matrix by various methods. When a secondary abrasive is present, the layer may be applied by flame spraying, plasma deposition, ion plating, electro-plating or electro-less plating, and subsequent heat treatment may be required. Electro-less plating has been found to be most suitable. An element, for example chromium, molybdenum, tungsten, aluminium, nickel or boron may be used in the layer and may be applied by solid state diffusion and subsequent heat treatment. Ion implantation techniques may also be used to improve the properties of the surface layer of the matrix and thereby provide wear resistance. Embodiments of the present invention will now be described by way of illustration in the following Examples, which refer to the accompanying drawings, in which: Figures 1 to 4are sectional views of portions of abrasive tools of the invention. Example 1 The abrasive tool shown in Figure 1 has a steel tool body 1 which has applied to it a matrix 2 of nickel. Diamond particles 3 are embedded in the nickel matrix 2 to act as abrasive, and are also held by a wear-resistant layer 4 of a nickel and diamond composite. The diamond particles 3 project beyond the surface ofthewear-resistant layer 4. The tool of this Example displays excellent resistance to abrasion of its surface by cutting debris when the tool is in use, as the layer 4 confers a great measure of wear resistance to the tool surface, while allowing the inner matrix 2 to be selected for its retention of the diamond 3. The tool of this Example is produced by electroplating the tool body 1 with nickel around the diamond particles 3 to a depth of 0.004 inch. The matrix 2 thus formed is then coated by electro-less deposition to a depth of 0.002 inch with a composite of 75% by volume nickel and 25% by volume diamond. The diamond particles 3 in this Example are about 0.009 inch in size and therefore extend from the surface of the layer 4 by about one-third of their extent. Examples 2, 3 and 4 Figures 2, 3, and 4 show respectively a single point tool, a multi-point tool and an abrasive drilling tool, and in each the tool body, matrix, abrasive particles and wear-resistant layer are indicated by the same reference numerals as in Figure 1. The tools of Figures 2 and 3 may be used as surface set wheel dressing tools and the tool of Figure 4 may be used as a surface set drilling bit. While the depths of the matrix and wear resistant layers are given above only by way of example, it is preferable that the abrasive particles should project from the wear resistant layer of about one-third of their size. Modifications and improvements can be made without departing from the scope of the invention. CLAIMS
1. An abrasive tool having a tool body, abrasive material held on the tool body by a matrix, and a layer of wear resistant material on the matrix around the abrasive material.
2. An abrasive tool according to Claim 1, wherein the abrasive material is particulate and projects from the wear resistant layer.
3. An abrasive tool according to Claim 2, wherein the abrasive particles project from the wear resistant layer by about one third of their size.
4. An abrasive tool according to Claim 1, 2 or 3, wherein the wear resistant layer contains a secondary abrasive.
5. An abrasive tool according to Claim 4, wherein the secondary abrasive is diamond or cubic boron nitride.
6. An abrasive tool according to Claim 4 or 5, wherein the secondary abrasive is present in a concentration of from 5 to 65% by volume.
7. An abrasive tool according to Claim 6, wherein the secondary abrasive is present in a concentration of from 10 to 40% by volume.
8. An abrasive tool according to any one of Claims 4 to 7, wherein the secondary abrasive is present in particle sizes of from 1 to 100 microns.
9. An abrasive tool according to any one of Claims 4 to 8, wherein the wear resistant layer contains nickel and powered diamond.
10. An abrasive tool according to any one of the preceding claims, wherein the wear resistant layer is applied by electro-less deposition.
11. An abrasive tool according to any one of the preceding claims, wherein the wear resistant layer contains a solid lubricant.
12. An abrasive tool according to any one of the preceding claims, wherein the wear resistant layer is about half as deep as the matrix.
13. An abrasive tool according to any one of the preceding claims, wherein the matrix is selected from bronze, nickel, nickel alloy, iron and iron alloy.
14. An abrasive tool according to Claim 13, wherein the matrix is of the alloy Invar and the abrasive material is diamond.
15. An abrasive tool substantially as hereinbefore described with reference to any one of the Examples.
16. An abrasive tool substantially as hereinbefore described with reference to and as shown in any one of Figures 1,2,3 and 4 of the accompanying drawings.
GB7943002A 1978-12-21 1979-12-13 Abrasive tool Withdrawn GB2038214A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB7943002A GB2038214A (en) 1978-12-21 1979-12-13 Abrasive tool

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB7849607 1978-12-21
GB7943002A GB2038214A (en) 1978-12-21 1979-12-13 Abrasive tool

Publications (1)

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GB2038214A true GB2038214A (en) 1980-07-23

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GB7943002A Withdrawn GB2038214A (en) 1978-12-21 1979-12-13 Abrasive tool

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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0166676A2 (en) * 1984-06-25 1986-01-02 United Technologies Corporation Abrasive surfaced article for high temperature service
US4805586A (en) * 1986-07-30 1989-02-21 Ernst Winter & Sohn (Gmbh & Co.) Dressing tool for grinding wheels
EP0478912A2 (en) * 1990-08-31 1992-04-08 Peter Wolters Ag Working disc for lapping, honing and polishing machine
EP0514586A2 (en) * 1991-05-21 1992-11-25 Sunnen Products Company Work abrading member, particularly honing member and method for attaching abrasive particles on such a member
WO1996006206A1 (en) * 1994-08-24 1996-02-29 National Industrial Technology Institute Method for the deposition of diamond film on the electroless-plated nickel layer
GB2312386A (en) * 1996-04-25 1997-10-29 Jon Henry Dobson Raking bit
WO2001036711A1 (en) * 1999-11-12 2001-05-25 Kerr Corporation Adherent hard coatings for dental burs and other applications
EP1300485A1 (en) * 2001-10-04 2003-04-09 Wacker-Chemie GmbH Power transmitting surface layer and method for the production thereof
WO2003029604A1 (en) * 2001-10-03 2003-04-10 Lyng Diamond Tools Prevention of bit balling by metallic coasting
EP1462218A1 (en) * 2003-03-27 2004-09-29 United Technologies Corporation Point superabrasive machining of nickel alloys
EP1590099A1 (en) * 2003-02-07 2005-11-02 Diamond Innovations, Inc. Process equipment wear surfaces of extended resistance and methods for their manufacture
WO2006040223A1 (en) * 2004-10-07 2006-04-20 Siemens Aktiengesellschaft Layer system
CN102059423A (en) * 2010-11-30 2011-05-18 中原工学院 Method for manufacturing diamond tool with self-lubrication function
DE102010009901A1 (en) * 2010-03-02 2011-09-08 Aktiebolaget Skf Roller bearing cage, has bolt provided with lengthwise-extending portion arranged in hole formed in bars, where part of external periphery of portion is provided with friction-increasing coating e.g. molybdenum coating or nickel coating
EP2578180A1 (en) * 2011-10-05 2013-04-10 Gebr. Brasseler GmbH & Co. KG Dental tool and method for its manufacture
US8927101B2 (en) 2008-09-16 2015-01-06 Diamond Innovations, Inc Abrasive particles having a unique morphology
US9095914B2 (en) 2008-09-16 2015-08-04 Diamond Innnovations Inc Precision wire saw including surface modified diamond
CN105695993A (en) * 2016-02-04 2016-06-22 安捷利(番禺)电子实业有限公司 Method for preparing embedded resistance copper foil
CN114144539A (en) * 2019-04-18 2022-03-04 生态涂层股份有限公司 Coated grinding tool, method for manufacturing the tool and grinding dental product
CN115106936A (en) * 2022-06-24 2022-09-27 中国地质大学(武汉) Diamond dressing disc and preparation method thereof

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0166676A3 (en) * 1984-06-25 1987-08-05 United Technologies Corporation Abrasive surfaced article for high temperature service
EP0166676A2 (en) * 1984-06-25 1986-01-02 United Technologies Corporation Abrasive surfaced article for high temperature service
US4805586A (en) * 1986-07-30 1989-02-21 Ernst Winter & Sohn (Gmbh & Co.) Dressing tool for grinding wheels
EP0478912A2 (en) * 1990-08-31 1992-04-08 Peter Wolters Ag Working disc for lapping, honing and polishing machine
EP0478912A3 (en) * 1990-08-31 1992-06-03 Peter Wolters Ag Working disc for lapping, honing and polishing machine
EP0514586A2 (en) * 1991-05-21 1992-11-25 Sunnen Products Company Work abrading member, particularly honing member and method for attaching abrasive particles on such a member
EP0514586A3 (en) * 1991-05-21 1993-03-24 Sunnen Products Company Work abrading member, particularly honing member and method for attaching abrasive particles on such a member
US5824367A (en) * 1994-08-24 1998-10-20 National Institute Of Technology And Quality Method for the deposition of diamond film on an electroless-plated nickel layer
WO1996006206A1 (en) * 1994-08-24 1996-02-29 National Industrial Technology Institute Method for the deposition of diamond film on the electroless-plated nickel layer
GB2312386A (en) * 1996-04-25 1997-10-29 Jon Henry Dobson Raking bit
GB2312386B (en) * 1996-04-25 1999-09-29 Jon Henry Dobson Raking bit
WO2001036711A1 (en) * 1999-11-12 2001-05-25 Kerr Corporation Adherent hard coatings for dental burs and other applications
WO2003029604A1 (en) * 2001-10-03 2003-04-10 Lyng Diamond Tools Prevention of bit balling by metallic coasting
EP1300485A1 (en) * 2001-10-04 2003-04-09 Wacker-Chemie GmbH Power transmitting surface layer and method for the production thereof
US8105692B2 (en) 2003-02-07 2012-01-31 Diamond Innovations Inc. Process equipment wear surfaces of extended resistance and methods for their manufacture
EP1590099A1 (en) * 2003-02-07 2005-11-02 Diamond Innovations, Inc. Process equipment wear surfaces of extended resistance and methods for their manufacture
EP1590099A4 (en) * 2003-02-07 2009-08-05 Diamond Innovations Inc Process equipment wear surfaces of extended resistance and methods for their manufacture
KR100558798B1 (en) * 2003-03-27 2006-03-14 유나이티드 테크놀로지스 코포레이션 Point superabrasive machining of nickel alloys
EP1462218A1 (en) * 2003-03-27 2004-09-29 United Technologies Corporation Point superabrasive machining of nickel alloys
US7144307B2 (en) 2003-03-27 2006-12-05 United Technologies Corporation Point superabrasive machining of nickel alloys
WO2006040223A1 (en) * 2004-10-07 2006-04-20 Siemens Aktiengesellschaft Layer system
US9095914B2 (en) 2008-09-16 2015-08-04 Diamond Innnovations Inc Precision wire saw including surface modified diamond
US9382463B2 (en) 2008-09-16 2016-07-05 Diamond Innovations Inc Abrasive particles having a unique morphology
US9982176B2 (en) 2008-09-16 2018-05-29 Diamond Innovations Inc. Abrasive particles having a unique morphology
US8927101B2 (en) 2008-09-16 2015-01-06 Diamond Innovations, Inc Abrasive particles having a unique morphology
DE102010009901A1 (en) * 2010-03-02 2011-09-08 Aktiebolaget Skf Roller bearing cage, has bolt provided with lengthwise-extending portion arranged in hole formed in bars, where part of external periphery of portion is provided with friction-increasing coating e.g. molybdenum coating or nickel coating
DE102010009901B4 (en) * 2010-03-02 2017-11-02 Aktiebolaget Skf Rolling bearing cage
CN102059423A (en) * 2010-11-30 2011-05-18 中原工学院 Method for manufacturing diamond tool with self-lubrication function
CN102059423B (en) * 2010-11-30 2012-11-21 中原工学院 Method for manufacturing diamond tool with self-lubrication function
EP2578180A1 (en) * 2011-10-05 2013-04-10 Gebr. Brasseler GmbH & Co. KG Dental tool and method for its manufacture
CN105695993A (en) * 2016-02-04 2016-06-22 安捷利(番禺)电子实业有限公司 Method for preparing embedded resistance copper foil
CN105695993B (en) * 2016-02-04 2018-07-06 安捷利(番禺)电子实业有限公司 A kind of preparation method of embedded resistor copper foil
CN114144539A (en) * 2019-04-18 2022-03-04 生态涂层股份有限公司 Coated grinding tool, method for manufacturing the tool and grinding dental product
CN115106936A (en) * 2022-06-24 2022-09-27 中国地质大学(武汉) Diamond dressing disc and preparation method thereof
CN115106936B (en) * 2022-06-24 2023-03-28 中国地质大学(武汉) Diamond dressing disc and preparation method thereof

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