GB2018232A - Preparation of zeolites - Google Patents

Preparation of zeolites

Info

Publication number
GB2018232A
GB2018232A GB7911857A GB7911857A GB2018232A GB 2018232 A GB2018232 A GB 2018232A GB 7911857 A GB7911857 A GB 7911857A GB 7911857 A GB7911857 A GB 7911857A GB 2018232 A GB2018232 A GB 2018232A
Authority
GB
United Kingdom
Prior art keywords
roh
compound
al2o3
sio2
zeolites
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7911857A
Other versions
GB2018232B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB2018232A publication Critical patent/GB2018232A/en
Application granted granted Critical
Publication of GB2018232B publication Critical patent/GB2018232B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)

Abstract

Crystalline aluminosilicate zeolites having an SiO2Al2O3 molar ratio of at least 12 and a constraint index between 1 and 12 are prepared from an aqueous mixture containing a compound of an alkali or alkaline- earth metal (M), an Al-compound, a Si-compound, an alcohol (ROH) and ammonia. The compounds are present in the following molar ratios: SiO2:Al2O3>/=12; (M)2/nO:SiO2= 0.01-1.0; H2O : (M)2/nO = 10-500; ROH : Al2O3 = 5-500; ROH:NH3>2. (n is valency of M). The mixture is maintained at elevated temperature.
GB7911857A 1978-04-06 1979-04-04 Preparation of zeolites Expired GB2018232B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7803662A NL7803662A (en) 1978-04-06 1978-04-06 PROCESS FOR THE PREPARATION OF ZEOLITES.

Publications (2)

Publication Number Publication Date
GB2018232A true GB2018232A (en) 1979-10-17
GB2018232B GB2018232B (en) 1982-07-21

Family

ID=19830606

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7911857A Expired GB2018232B (en) 1978-04-06 1979-04-04 Preparation of zeolites

Country Status (7)

Country Link
JP (1) JPS54151600A (en)
CA (1) CA1135679A (en)
DE (1) DE2913552A1 (en)
FR (1) FR2421846A1 (en)
GB (1) GB2018232B (en)
IT (1) IT1112972B (en)
NL (1) NL7803662A (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0030811A1 (en) * 1979-12-07 1981-06-24 The British Petroleum Company p.l.c. Process for the production of crystalline aluminosilicates and their use as catalysts and catalyst supports
EP0037168A1 (en) * 1980-03-27 1981-10-07 Mobil Oil Corporation Shape selective reactions with group IB modified zeolite catalysts
EP0051741A1 (en) * 1980-11-06 1982-05-19 BASF Aktiengesellschaft Process for the preparation of a crystalline aluminosilicate (zeolite) and use thereof as a catalyst
US4431621A (en) * 1980-03-13 1984-02-14 Snamprogetti S.P.A. Method for preparing aluminum-silicate having a zeolite-like structure
EP0104800A1 (en) * 1982-09-07 1984-04-04 The British Petroleum Company p.l.c. Improved method of preparing crystalline aluminosilicates
EP0038116B1 (en) * 1980-04-11 1984-04-18 Mobil Oil Corporation Shape selective reactions with cadmium-modified zeolite catalysts
EP0051346B1 (en) * 1980-10-29 1984-11-28 Mobil Oil Corporation Shape selective reactions utilizing zeolites modified with group v a metals
US4532226A (en) * 1980-03-17 1985-07-30 Mobil Oil Corporation Zeolite catalysts modified with Group VI A metal
US5011622A (en) * 1988-10-10 1991-04-30 Lever Brothers Company, Division Of Conopco, Inc. Liquid cleaning compositions and process for their preparation
US5589153A (en) * 1994-11-03 1996-12-31 The Dow Chemical Company Synthesis of crystalline porous solids in ammonia
US7229941B2 (en) 2002-12-01 2007-06-12 Sud-Chemie Ag Catalysts based on crystalline aluminosilicate
EP2130586A1 (en) 2008-06-06 2009-12-09 Total Petrochemicals Research Feluy Process for making crystalline metallosilicates

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4374045A (en) 1980-05-27 1983-02-15 Mobil Oil Corporation Group IB metal modified zeolite catalysts
JPS577820A (en) * 1980-06-18 1982-01-16 Mitsubishi Heavy Ind Ltd Novel crystalline silicate and its manufacture
JPS5711819A (en) * 1980-06-24 1982-01-21 Mitsubishi Heavy Ind Ltd Preparation of crystalline zeolite
US4371457A (en) 1980-10-29 1983-02-01 Mobil Oil Corporation Zeolites modified with group VA metals
JPS59184722A (en) * 1983-04-06 1984-10-20 Res Assoc Petroleum Alternat Dev<Rapad> Manufacture of crystalline metallosilicate
JPS59184723A (en) * 1983-04-06 1984-10-20 Res Assoc Petroleum Alternat Dev<Rapad> Manufacture of crystalline metallosilicate
JPS60195018A (en) * 1984-03-16 1985-10-03 Agency Of Ind Science & Technol Production of mordenite zeolite
JPS6197387A (en) * 1984-10-18 1986-05-15 Nippon Oil Co Ltd Dewaxing of hydrocarbon oil
JPS61200928A (en) * 1985-03-04 1986-09-05 Agency Of Ind Science & Technol Production of lower olefin

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA933911A (en) * 1971-03-18 1973-09-18 Mobil Oil Corporation Method of preparation for crystalline aluminosilicate zeolites

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0030811A1 (en) * 1979-12-07 1981-06-24 The British Petroleum Company p.l.c. Process for the production of crystalline aluminosilicates and their use as catalysts and catalyst supports
US4452907A (en) * 1979-12-07 1984-06-05 The British Petroleum Company Limited Process for the production of crystalline aluminosilicates and their use as catalysts and catalyst supports
US4431621A (en) * 1980-03-13 1984-02-14 Snamprogetti S.P.A. Method for preparing aluminum-silicate having a zeolite-like structure
US4532226A (en) * 1980-03-17 1985-07-30 Mobil Oil Corporation Zeolite catalysts modified with Group VI A metal
EP0037168A1 (en) * 1980-03-27 1981-10-07 Mobil Oil Corporation Shape selective reactions with group IB modified zeolite catalysts
EP0038116B1 (en) * 1980-04-11 1984-04-18 Mobil Oil Corporation Shape selective reactions with cadmium-modified zeolite catalysts
EP0051346B1 (en) * 1980-10-29 1984-11-28 Mobil Oil Corporation Shape selective reactions utilizing zeolites modified with group v a metals
EP0051741A1 (en) * 1980-11-06 1982-05-19 BASF Aktiengesellschaft Process for the preparation of a crystalline aluminosilicate (zeolite) and use thereof as a catalyst
EP0104800A1 (en) * 1982-09-07 1984-04-04 The British Petroleum Company p.l.c. Improved method of preparing crystalline aluminosilicates
US5011622A (en) * 1988-10-10 1991-04-30 Lever Brothers Company, Division Of Conopco, Inc. Liquid cleaning compositions and process for their preparation
US5589153A (en) * 1994-11-03 1996-12-31 The Dow Chemical Company Synthesis of crystalline porous solids in ammonia
US5599520A (en) * 1994-11-03 1997-02-04 Garces; Juan M. Synthesis of crystalline porous solids in ammonia
US7229941B2 (en) 2002-12-01 2007-06-12 Sud-Chemie Ag Catalysts based on crystalline aluminosilicate
EP2130586A1 (en) 2008-06-06 2009-12-09 Total Petrochemicals Research Feluy Process for making crystalline metallosilicates

Also Published As

Publication number Publication date
GB2018232B (en) 1982-07-21
NL7803662A (en) 1979-10-09
IT1112972B (en) 1986-01-20
FR2421846A1 (en) 1979-11-02
CA1135679A (en) 1982-11-16
JPS54151600A (en) 1979-11-28
DE2913552A1 (en) 1979-10-18
FR2421846B1 (en) 1980-10-24
IT7921594A0 (en) 1979-04-04

Similar Documents

Publication Publication Date Title
GB2018232A (en) Preparation of zeolites
ES8300643A1 (en) Crystalline alumino silicates and their use as catalysts.
DE3379398D1 (en) Process for preparing zms-5 zeolites
KR970707040A (en) Process for producing alumino-silicate derivatives (PROCESS FOR FORMING ALUMINO-SILICATE DERIVATIVES)
JPS57123815A (en) Production of crystalline aluminosilicate zeolite
CA2081698A1 (en) Synthesis of zeolite beta using diethanolamine in the reaction mixture
GB1005949A (en) Molecular sieve adsorbents
ES8300642A1 (en) Silicon substituted zeolite compositions and process for preparing same
GB2023562B (en) Silica and germania
EP0178687A3 (en) Zeolite catalyst preparation
ES2053966T3 (en) ZEOLITE L.
EP0190903A3 (en) A crystalline zeolite composition having a cancrinite-like structure and a process for its preparation
ES537517A0 (en) A PROCEDURE FOR PREPARING A CRYSTALLINE ZEOLITE, WHICH CONTAINS POTASSIUM
GB1094994A (en) Physically stable alumino-silicate zeolite catalysts
UA32404C2 (en) synthetic crystalline aluminum silicate
GB2101110B (en) Synthesis of zsm-type zeolites
DE3361758D1 (en) ZEOLITE LZ-133
JPS577819A (en) Manufacture of crystalline aluminosilicate zeolite
GB1413470A (en) Zeolites
EP0101254A3 (en) Process for separating ethanol from dilute aqueous solutions thereof
ES430419A1 (en) Zeolite
AU582258B2 (en) Synthesising faujasites
EP0174780A3 (en) A crystalline metallosilicate, the synthesis thereof and its use in organic conversion
EP0293998A3 (en) Crystalline silicates
Midivnishvili et al. Production of Synthetic Zeolites Based on Diatomite and Sodium Aluminate

Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee