GB2013222A - Preparation of components of olefine polymerisation catalysts - Google Patents

Preparation of components of olefine polymerisation catalysts

Info

Publication number
GB2013222A
GB2013222A GB7902624A GB7902624A GB2013222A GB 2013222 A GB2013222 A GB 2013222A GB 7902624 A GB7902624 A GB 7902624A GB 7902624 A GB7902624 A GB 7902624A GB 2013222 A GB2013222 A GB 2013222A
Authority
GB
United Kingdom
Prior art keywords
ticl3
particles
particle size
average particle
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7902624A
Other versions
GB2013222B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB7902624A priority Critical patent/GB2013222B/en
Publication of GB2013222A publication Critical patent/GB2013222A/en
Application granted granted Critical
Publication of GB2013222B publication Critical patent/GB2013222B/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

A process for the preparation of an active TiCl3 component of an olefine polymerisation catalysts comprises: (a) reacting TiCl4 with a complexing agent in a molar ratio of from 1:0.3 to 1:2; (b) reacting an organo-aluminium compound with a complexing agent in a molar ratio of at most 1:0.25; (c) reducing the complexed TiCl4 with the complexed organo- aluminium compound over a period of less than one hour at a temperature within the range 60 DEG to 110 DEG C to produce TiCl3 particles having an average particle size of from 50 to 500 mu m; (d) subjecting the TiCl3 particles to a treatment to reduce the average particle size thereof to less than 50 mu m; and (e) classifying the TiCl3 particles to separate a fraction having an average particle size of from 0-1 to 30 mu m. The fraction is used with an organometallic cocatalyst in the polymerisation of olefines.
GB7902624A 1978-01-27 1979-01-25 Preparation of an active ticl3 catalyst Expired GB2013222B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB7902624A GB2013222B (en) 1978-01-27 1979-01-25 Preparation of an active ticl3 catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB337778 1978-01-27
GB7902624A GB2013222B (en) 1978-01-27 1979-01-25 Preparation of an active ticl3 catalyst

Publications (2)

Publication Number Publication Date
GB2013222A true GB2013222A (en) 1979-08-08
GB2013222B GB2013222B (en) 1982-06-03

Family

ID=26238267

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7902624A Expired GB2013222B (en) 1978-01-27 1979-01-25 Preparation of an active ticl3 catalyst

Country Status (1)

Country Link
GB (1) GB2013222B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3107571A1 (en) * 1980-02-27 1982-01-28 Exxon Research and Engineering Co., 07932 Florham Park, N.J. METHOD FOR PRODUCING A SOLID TITANIUM TRIHALOGENIDE PRODUCT, ZIEGLER CATALYST SYSTEM CONTAINING THIS PRODUCT, AND USE THEREOF

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3107571A1 (en) * 1980-02-27 1982-01-28 Exxon Research and Engineering Co., 07932 Florham Park, N.J. METHOD FOR PRODUCING A SOLID TITANIUM TRIHALOGENIDE PRODUCT, ZIEGLER CATALYST SYSTEM CONTAINING THIS PRODUCT, AND USE THEREOF

Also Published As

Publication number Publication date
GB2013222B (en) 1982-06-03

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Legal Events

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PCNP Patent ceased through non-payment of renewal fee