GB2008113A - Co-oxidation of olefins and beta - substituted aldehydes - Google Patents
Co-oxidation of olefins and beta - substituted aldehydesInfo
- Publication number
- GB2008113A GB2008113A GB7844080A GB7844080A GB2008113A GB 2008113 A GB2008113 A GB 2008113A GB 7844080 A GB7844080 A GB 7844080A GB 7844080 A GB7844080 A GB 7844080A GB 2008113 A GB2008113 A GB 2008113A
- Authority
- GB
- United Kingdom
- Prior art keywords
- beta
- oxidation
- saturated aliphatic
- olefins
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- 150000001299 aldehydes Chemical class 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- -1 saturated aliphatic aldehyde Chemical class 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 150000002118 epoxides Chemical class 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
Abstract
The co-oxidation of an olefin and a beta-substituted saturated aliphatic aldehyde of the formula R<1>-CR<2>-CR<3>- CHO, wherein Z<1> and R<4>, R<1>, R<2>, R<3> and R<4> are hydrogen atoms or alkyl groups and Z is -OR<5>, -CN or -OC(O)R<5>, R<5> being an alkyl aryl or cycloalkyl group to the corresponding epoxide and beta- substituted saturated aliphatic acid is effected by contacting the olefin and aldehyde with molecular oxygen in a fluid medium, preferably in the presence of a liquid reaction medium comprising a saturated aliphatic nitrile.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US85031577A | 1977-11-10 | 1977-11-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2008113A true GB2008113A (en) | 1979-05-31 |
| GB2008113B GB2008113B (en) | 1982-08-25 |
Family
ID=25307802
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7844080A Expired GB2008113B (en) | 1977-11-10 | 1978-11-10 | Process for simultaneous epoxidation of olefins and oxidation of beta-substituted saturated aldehydes |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5476505A (en) |
| BE (1) | BE871882A (en) |
| BR (1) | BR7807403A (en) |
| DE (1) | DE2848868C2 (en) |
| FR (1) | FR2408598A1 (en) |
| GB (1) | GB2008113B (en) |
| IT (1) | IT1193748B (en) |
| NL (1) | NL179127C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009001948A1 (en) * | 2007-06-27 | 2008-12-31 | Sumitomo Chemical Company, Limited | Method for producing propylene oxide |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB890697A (en) * | 1959-08-19 | 1962-03-07 | Shell Int Research | A process for the preparation of beta-ether-substituted propionaldehydes |
| US3210380A (en) * | 1962-06-29 | 1965-10-05 | Monsanto Co | Process for the direct epoxidation of olefins with molecular oxygen |
| GB1143577A (en) * | 1965-06-09 | |||
| SE349027B (en) * | 1967-12-14 | 1972-09-18 | Basf Ag | |
| CA941836A (en) * | 1970-12-21 | 1974-02-12 | Nazar S. Aprahamian | Process for the production of olefin oxides |
-
1978
- 1978-11-03 NL NLAANVRAGE7810951,A patent/NL179127C/en not_active IP Right Cessation
- 1978-11-08 IT IT51828/78A patent/IT1193748B/en active
- 1978-11-09 BR BR7807403A patent/BR7807403A/en unknown
- 1978-11-09 BE BE191624A patent/BE871882A/en not_active IP Right Cessation
- 1978-11-09 FR FR7831740A patent/FR2408598A1/en active Granted
- 1978-11-10 JP JP13797078A patent/JPS5476505A/en active Pending
- 1978-11-10 GB GB7844080A patent/GB2008113B/en not_active Expired
- 1978-11-10 DE DE2848868A patent/DE2848868C2/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009001948A1 (en) * | 2007-06-27 | 2008-12-31 | Sumitomo Chemical Company, Limited | Method for producing propylene oxide |
Also Published As
| Publication number | Publication date |
|---|---|
| BE871882A (en) | 1979-05-09 |
| JPS5476505A (en) | 1979-06-19 |
| NL179127B (en) | 1986-02-17 |
| FR2408598B1 (en) | 1983-01-28 |
| BR7807403A (en) | 1979-07-24 |
| IT1193748B (en) | 1988-08-24 |
| IT7851828A0 (en) | 1978-11-08 |
| NL7810951A (en) | 1979-05-14 |
| FR2408598A1 (en) | 1979-06-08 |
| DE2848868A1 (en) | 1979-05-17 |
| NL179127C (en) | 1986-07-16 |
| GB2008113B (en) | 1982-08-25 |
| DE2848868C2 (en) | 1984-05-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| IT1152299B (en) | PROCEDURE FOR THE EXPOSSIDATION OF HYDRAULIC COMPOUNDS | |
| BE831438A (en) | OLEFINS OXIDATION PROCESS USING CATALYSTS CONTAINING VARIOUS ACTIVATOR ELEMENTS | |
| NL134286C (en) | ||
| ES456012A1 (en) | Sulfonated metal phthalocyanine catalyst | |
| FR2656304B1 (en) | PROCESS FOR SELECTIVE EPOXIDATION OF UNSATURATED (METH) ACRYLIC COMPOUNDS AND NOVEL BIFUNCTIONAL ACHYLATES (METH) ACRYLATES OBTAINED. | |
| GB2008113A (en) | Co-oxidation of olefins and beta - substituted aldehydes | |
| JPS646222A (en) | Conversion of aromatic hydrocarbons using carbon monoxide | |
| ES464549A1 (en) | Epoxidation of olefins | |
| FR2273800A1 (en) | CATALYTIC AMMONIACAL OXIDATION OF OLEFINS TO NITRILS | |
| KR890011899A (en) | Process for preparing alkyl arsine compound | |
| IT1082125B (en) | INTERNALLY COATED REACTION VESSEL, FOR OLEFINE POLYMERIZATION | |
| ATE20745T1 (en) | PROCESS FOR PRODUCTION OF EPOXY. | |
| ES463527A1 (en) | Epoxidation | |
| NO155440C (en) | PROCEDURE FOR THE PREPARATION OF CIMETIDIN. | |
| JPS55153732A (en) | Alcohol manufacture | |
| FR2484403B1 (en) | ||
| GB1465512A (en) | 2-2-methyl-1-propen-1-yl-1,3-dioxans useful as perfumes | |
| ES392123A1 (en) | Process for the preparation of olefine oxides | |
| JPS5325504A (en) | Isolation of glycols | |
| ATE32884T1 (en) | PRODUCTION OF NITRO COMPOUNDS BY VAPOR PHASE NITRIATION OF OLEFINS. | |
| IE42365L (en) | 4-hydroxy-3-methoxyphenyl acetonitrile. | |
| ES426285A1 (en) | Process for preparing alkyllation catalyst adjuvant solution | |
| BR8005345A (en) | VANADIO TETRAVALENTE COMPOUNDS, PROCESS FOR ITS PRODUCTION, AND ITS APPLICATION | |
| SE7704738L (en) | PROCEDURE FOR PRODUCTION OF NEW OPTICALLY ACTIVE ASSOCIATIONS | |
| ES405509A1 (en) | New procedure for the obtaining of bis - (2- (p-chlorofenoxi) -2-methyl-pripionate) of hydroxylaminum. (Machine-translation by Google Translate, not legally binding) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PCNP | Patent ceased through non-payment of renewal fee |