GB1596179A - Process for the level dyeing of plyester or cellulose triacetate material - Google Patents
Process for the level dyeing of plyester or cellulose triacetate material Download PDFInfo
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- GB1596179A GB1596179A GB5379277A GB5379277A GB1596179A GB 1596179 A GB1596179 A GB 1596179A GB 5379277 A GB5379277 A GB 5379277A GB 5379277 A GB5379277 A GB 5379277A GB 1596179 A GB1596179 A GB 1596179A
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- United Kingdom
- Prior art keywords
- liquor
- muff
- process according
- dyes
- aqueous
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Polyesters Or Polycarbonates (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Description
(54) PROCESS FOR THE LEVEL DYEING OF POLYESTER
OR CELLULOSE TRIACETATE MATERIAL
(71) We, CIBA-GEIGY AG, a Swiss Body corporate, of Basle,
Swizerland, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement:- The invention relates to a process for the level dyeing of polyester and cellulose triacetate material using specific disperse dyes, to the dye liquor suitable for carrying out said process, and to the dyed polyester and cellulose triacetate material obtained by this process.
It is known to dye polyester material by the exhaust method, in particular under high temperature conditions, from an aqueous liquor. The drawback of this known method is that unlevel dyeings are often obtained, especially on wound packages. To obtain level dyeings, especially in bright shades, the heating phase of the bath is critical. A slow, controlled heating and a good circulation must be ensured, to which end special machines are necessary. Once unlevel dyeings have been obtained, the unlevelness can generally not be removed even by keeping the dyebath at 1300C for a prolonged period of time.
To obtain level dyeings on polyester material it is therefore necessary that the control of the increase in temperature in the heating phase must be effected subject to specific exhaustion characteristics of the disperse dyes employed; and machinerelated conditions, such as liquor circulations, have to be included in complicated and elaborate calculations.
To avoid these difficulties, the proposal has already been made to add specific, in particular non-ionic, dyeing assistants to the dyebath. Not infrequently, however, these assistants have the drawback that they adversely affect the stability of the dyestuff dispersion in the heating phase, which in turn can result in unlevel dyeings.
All these methods consequently do not solve the problem of the level dyeing of polyester material in a satisfactory manner.
Surprisingly, it has now been found that the disadvantages initially referred to, in particular complicated calculations for carrying out the dyeing, such as the heating phase and the circulation rate, can be eliminated by dyeing polyester material with a combination of migrating disperse dyes having specific physicochemical properties.
Accordingly the process of the present invention comprises treating the material with an aqueous dye liquor which contains at least two migrating disperse dyes which have a diffusion coefficient Do at 1300C of 2 to 10x10-'0 cm2/sec, a distribution coefficient K at 1 300C of 20 to 500 I/kg, and a migration half-life t/2 of less than 50 minutes, as well as optionally, further ingredients by the aqueous exhaust method at a temperature above 100bC as well as the aqueous dye liquors which can be used.
The migrating disperse dyes which are suitable are those having a diffusion coefficient Do at 1300C-measured by the densitometric method [Melliand
Textilberichte 55, 463H67 (1974)]--of 2 to 10, preferably 2.5 to 10x 10-l cm2/sec, and a distribution coefficient K at 1300C of 20 to 500, preferably of 60 to 350, 11keg.
They also have a migration half-life t/2 of less than 50, preferably less than 30, minutes. The migration half-life t/2 is the time in which an undyed polyester material, which is treated together with a dyed piece of the same material of equal size at 1300C in an aqueous liquor, is so dyed that the amount of dye it contains is 50% of the amount of the dyed material.
Suitable disperse dyes which fulfill these conditions are, from a chemical point of view, those which belong to a variety of different classes of disperse dyes.
They are, for example, dyes which do not contain sulphonic acid groups and which are only sparingly soluble in water at room temperature, such as quinophthalone dyes, nitrosdyes, methine dyes, naphthoquinonimine dyes, styryl dyes, azostyryl dyes, naphthoperinone dyes and, in particular, anthraquinone and azo dyes, such as mono- and disazo dyes.
The dyeings obtained with these migrating disperse dyes unexpectedly show a good fastness of sublimation, especially in bright shades, i.e. in those shades which have a reference type strength of 41/2.
Particularly good results, chiefly based on a dichromatic or trichromatic system, can be obtained with the following dyes:
Yellow dyes
Do = 3,7
K = 152 tl2= 35
Do = 6,0
K = 193 t/2= 17
Red dyes
Do = 5,0
K = 81 t/2= 25
Blue dyes
CI Disperse Blue 26 (methylated mixture Do = 4,8
of diaminoanthrarufine and diamino- K = 315
chrysazine) t/2 = 22
CI Disperse Blue 95 (mixture of diamino- Do = 4,8
anthrarufine and diaminochrysazine K = 315
treated with formaldehyde) t/2 = 22
These dyes have a sufficiently high rate of diffusion to permit level dyeings to be obtained upon migration. a trichromatic system of migrating disperse dyes is therefore available. By a trichromatic system is meant a mixture which contains a blue, a red and a yellow dye.
The determination of the distribution coefficient K is made according to the formula V.Az K= I-Az wherein Az denotes the degree of exhaustion and V denotes the liquor ratio (the number of litres of liquor per kg of material, Textilpraxis inter 1973, 231-233), the
K value being determined at a liquor ratio of at least 100:1 on Crimplene (a
Registered Trade Mark of ICI).
Other dyes which can be used include the following:
Do = 6
K = 49.4 t/2 = 36
Do = 10
K = 68 t/2 = 14
Dye 0 2OCH2CI2OH K = 54 Do Do =4,9 t!2= 29 CH, CH3 N=N Do- Do 2,8 t/2=40 HO O2 H3 CN K=443 CH3 d N=N Do=2,7 H CH3 t/2=30 CH3 P 2 CH3 CN Do=2,7 t/2=25 t/2=25 HNCiH4O 3 02 CH3 K = 204 CN CN Do 3,5 ClN=NN t/2= 30 HO I 0 CH3 NO CH3 K = 120 2CHA3N Do 4,1 CH3 Depending on the desired depth of shade, the amounts in which the migration disperse dyes are used in the dyebaths can vary within wide limits. In general, amounts from 0.001 to 10, preferably 0.01 to 2, percent by weight of one or more of the above disperse dyes, based on the weight of the polyester material, are advantageous. The dyes are known and can be obtained by methods known in the art.
Further ingredients which can be added to the aqueous dye liquor are in particular acids and salts, such as formic and acetic acid, as well as ammonium sulphate for providing the optimum pH value, and dispersants, especially anionic dispersants.
Suitable anionic dispersants are, for example: sulphated primary or secondary, purely aliphatic alcohols containing 8 to 18 carbon atoms in the alkyl chain, for example sodium laurylsulphate, or the sodium salts of coconut fatty alcohol sulphates; sulphated unsaturated higher fatty acids or fatty acid esters, such as the sulphates of oleic acid, elaidic acid or ricinolic acid and the lower alkyl esters thereof, and the oils which contain such fatty acids, such as olive oil, castor oil, colza oil; the adducts of 1 to 20 moles of ethylene oxide with fatty amines, fatty acids or aliphatic alcohols containing 1 to 18 carbon atoms in the alkyl chain, which have been converted into an acid ester with an organic dicarboxylic acid, such as maleic acid, malonic acid or succinic acid, but preferably with an inorganic polyacid, such as o - phosphoric acid or, in particular, sulphuric acid, for example the acid sulphuric acid ester of the adduct of 2 moles of ethylene oxide with 1 mole of p- nonylphenol; sulphated esterified polyoxy compounds, for example sulphated, partially esterified polyhydric alcohols, such as the sodium salt of the sulphated monoglyceride of palmitic acid; primary and secondary alkylsulphonates containing 8 to 20 carbon atoms in the alkyl chain, for example ammonium decylsulphonate, sodium dodecylsulphonate, sodium hexadecanesulphonate, sodium stearylsulphonate; alkylarylsulphonates, such as alkylbenzenesulphonates with straight or branched alkyl chain containing at least 7 carbon atoms, for example sodium dodecylbenzene sulphonate; sulphonates of polycarboxylic acid esters, for example sodium dioctylsulphosuccinate; the sodium, potassium, ammonium, N- alkyl, N- hydroxyalkyl, N- alkoxyalkyl or Ncyclohexylammonium or hydrazinium and morpholinium salts of fatty acids containing 10 to 20 carbon atoms which are termed soaps, for example of lauric, palmitic, stearic or oleic acid, of naphthenoic acids, of resinic acids, such as abietic acid, for example the so-called colophonium soap.
Particularly suitable anionic dispersants are ligninsulphonates and polyphosPhates as well as condensation products of aromatic sulphonic acid with formaldehyde, such as condensation products of formaldehyde and naphthalenesulphonic acids, for example the disodium salt of di(6sulphonaphthyl - 2)methane, or of formaldehyde, naphthalenesulphonic and benzenesulphonic acid, or a condensation product of crude cresol, formaldehyde and naphthalensulphonic acid.
However, it is also possible to use mixtures of anionic dispersants. The anionic dispersants are usually in the form of their alkali metal salts, ammonium salts, or of their water-soluble amine salts.
Suitable textile materials are polyester materials and cellulose triacetate fabrics. By polyester materials are meant polycondensates of aromatic polycarboxylic acids, especially dicarboxylic acids or derivatives thereof, and polyfunctional alcohols, in particularly glycols. The polyester used hitherto almost exclusively in the textile industry is derived from terephthalic acid and ethylene glycol.
Copolymers of terephthalic acid and isophthalic acid with ethylene glycol as well as modified polyester materials can also be used, for example those which can be dyed without a carrier at 1000C. These materials can be in the most diverse stages of processing, for example in the form of piece goods, such as woven and knitted fabrics, and of yarn in the form of wound packages or muffs.
The dyeing process of the present invention can be carried out in all kinds of closed and, advantageously, pressure-resistant machines, for example in jet dyeing machines and winch becks, in circulating-liquor machines, such as circu ating machines for cheeses and muffs, and in beam dyeing machines.
The dyeing process consists in putting the textile material at a temperature of, say, 700 to 900C into the aqueous liquor which may contain the further ingredients, keeping the liquor for, say, 5 minutes at this temperature and the heating it, preferably continuously, generally in the course of 15 to 25 minutes, to a temperature of above 100"C, for example up to 1400C. The liquor is generally kept for 30 to 120 minutes, preferably for about 60 minutes, at this temperature. The temperature at which the dye in question is added to the liquor is not critical. The preferred dyeing temperature is in the range 110 to 1400C Liquor circulation can be carried out from the outside to the inside of the material or conversely and alternating.
The dyeing is generally aftertreated by cooling the dyebath to, say, 80"C, rinsing the goods with water, followed, if required, by a reductive afterclear, and drying them.
The process of the present invention consequently differs from known processes which use no or only moderately migrating disperse dyes in that a shortened heating phase is possible and in the possibility of adding the dye to the liquor at any temperature. Because of the good migration of the dyes, a certain unlevelness when the dyes exhaust onto the material is entirely permissible, since this unlevelness can be rectified during the dwell at the dyeing temperature.
The process is conveniently carried out at a liquor ratio of especially 1:4 to 1:100, preferably 1:10 to 1:50, by which is meant the ratio of goods (in kg) to liquor (in litres).
The dyeing process using at least two of the migrating disperse dyes as defined herein permits:
an uncontrolled heating of the liquor to dyeing temperature without taking particular account of a particular or critical dyeing rate (see Melliand 10, 1974, pp.
876-879), so that complicated programmings and calculations are not necessary;
a pronounced migration of the disperse dyes under HT conditions;
the production of level compound shade dyeings, with good coverage of barriness;
a simple, rational and safe operation;
a simple correcton of faulty dyeings, since a better adjustment takes place;
carrying out the process without the addition of carriers and levelling agents;
a shading under conventional HT conditions on account of the very good migration of the disperse dyes as defined herein;
the production of very level dyeings have good fastness properties.
Finally, unlevel dyeings, even those which differ in depth of shade and occur in particular on rapid and uncontrolled heating, can be rectified in the subsequent dwell of the textile material in the liquor, so that level dyeings can be obtained.
By means of the process of this invention it has been possible to solve an old problem in a novel and technically simple manner which is substantially more reliable than the hitherto known processes and which requires the usual amount of time. This process is particularly suitable for obtaining bright and very bright shades.
The following Examples serve to illustrate the invention. The levelling action of the dyes was tested by treating polyester material dyed with the migrating disperse dyes as defined herein with undyed polyester material under HT conditions. In this test, the dyes migrate in a more or less pronounced manner from the dyed to the undyed material.
Example 1
700 g of polyester texturised yarn in muff form are dyed in a HT circulatingliquor dyeing machine under HT conditions in the conventional manner in a liquor ratio of 1:10 with the following dyes:
0.69 g of the yellow dye of the formula
1.10 g of the blue dye CI Disperse Blue 26 (methylated mixture Do = 4.8 of diaminoanthrarufine and diamino- K = 315
chrysazine) t/2= 22
The dyeing was aftertreated in the usual manner (dyeing 1).
A further dyeing (dyeing 2) is carried out on 700 g of texturised yarn in muff form as described above using the same dyes, but in smaller amounts, viz.:
0.29 g of the yellow dye
0.29 g of the red dye and
0.475 g of the blue dye mixture.
The material is also subjected to an aftertreatment in the same manner. Both
dyeings 1 and 2, which differ in their colour strength by about 40%, are treated in a ffr circulating-liquor dyeing machine in a liquor ratio of 1:10 with a blank aqueous
liquor containing 28 g of the disodium salt of di(6 - sulphonaphthyl - 2)methane, 28
g of the ammonium sulphate and 7 ml of 80% aqueous formic acid. The blank
dyebath is heated from 95" to 1300C in the course of 10 minutes and allowed to
circulate from the outside to the inside of the circulating pump direction for 75
minutes. The liquor is cooled to 800 C, and the goods are rinsed and finished in the
usual manner.
Two polyester muffs (wound packages) dyed in a level olive green shade are
obtained. Yarn was taken alternatively from the outside, centre and inner layer of
the two muffs and used to form a knitted piece which exhibited a completely level
shade.
It is thus evident that dyeing 1 and dyeing 2, which differ from each other by
about 40% in colour strength before the treatment, are rectified by the migration
and give hand-knitting yarns which are dyed in completely level shades.
Example 2
The procedure described in Example I is repeated, except that dyeings 1 and 2
are treated for 35 minutes at 1350C instead of for 75 minutes at 130 C. An equally
complete colour rectification of the originally differing dyeings is achieved.
Example 3
1400 g of texturised polyester in the form of a wound package are treated in a
HT circulating-liquor dyeing machine in a liquor ratio of 1:15 with an aqueous
liquor containing 21 g of the disodium salt of di(6 - sulphonaphthyl - 2)methane, 42
g of ammonium sulphate and 10.5 ml of 80% aqueous formic acid at a temperature
of 70"C. In the tank for liquor preparation, the mixture of the following dyes:
1.96 g of the yellow dye of the formula given in Example 1,
1.96 g of the red dye of the formula given in Example 1,
3.15 g of the blue dye of the formula given in Example 1,
is drawn in water to the liquor circulation and the liquor is allowed to circulate for 5
minutes at 700C. The liquor is heated to 1300C in the course of 20 minutes and at a
rate of about 3 circulations per mintue and kept at this temperature for 60 minutes.
The dyebath is then cooled to 800C and the goods are rinsed and aftertreated in the
usual manner.
A knitted piece obtained by knitting separately the outside, centre, and inner
layers of the resulting olive green polyester texturised yarn (muff) is dyed in a
completely level shade and the individual layers can virtually no longer be
distinguished.
Example 4
The procedure of Example 3 is repeated, heating with a capacity of 3"C per sninute but in this case to a bath temperature of 135"C and keeping this unperåture for 30 minutes. A texturised yarn dyed in a level olive green shade is siso obtained. On knitting separately the outside, centre, and inner layers of the
muff to a knittal piece,- no differences in colour strength can be observed.
Example 5 wrisonixanwle using non-migrating dyes.
Zcocehlrc ofampIe 3 is repeated, using a mixture of the following dyes: 0.2 g of the yellow die mixture of the formulae
Do = 2
K = 128 t/2= 65 0.2 g of the red dye of the formula
Do = 2.4 K = 191 t/2= 53 0.27 g of the blue dye mixture of the formulae
Do = 2,9
K = 700 t/2= > 60
Polyester texturised yarn dyed in an eggshell shade is obtained.
On knitting separately the outside, centre, and inner layers of the polyester texturised yarn to a knitted piece, darker and lighter differences in colour are observed which point to unlevelness in the muff and which cannot be substantially improved even by a prolonged treatment at 1300C for a total of 120 minutes. The unlevelness is caused by the poorly migrating dyes, especially by the blue one.
Example 6
(Comparison Example)
700 g of texturised polyester yarn in muff form are dyed in a HT circulatingliquor machine under HT conditions in the usual manner in a liquor ratio of 1:10 with the following dyes:
0.7 g of the yellow dye of the formula
K C2000 Do = 4 2 t/2 < 60 1 g of the red dye of the formula
K 500 Do = 5.0 t/2 < 60 min 1.6 g of the blue dye of the formula
K 2020 Do= 4,8 t/2 < 60 min The dyeing is aftertreated in the usual manner.An undyed polyester muff (700 g) and the above muff, which is dyed in a light grey shade, are treated together in a circulating-liquor machine in a liquor ratio of 1:10 with a blank liquor containing 28 g of di(6 - sulphonaphthyl - 2)methane, 28 g of ammonium sulphate and 7 ml of 80% aqueous formic acid. The liquor is heated to 950-l300C in the course of 10 minutes and allowed to circulate tor 60 minutes from outside to the inside of the circulating pump direction, then cooled to 80"C. The goods are rinsed and aftertreated in the usual manner.
After the treatment in the blank liquor, the depth of shade of the originally dyed polyester muff has only been insignificantly brightened. The undyed muff has only a very slight light grey colouration after the treatment.
On processing the inner, centre and outer layers of the muff separately to a knitting in stocking form, the individual layers have a completely unlevel colouration which differs in shade from layer to layer. It is evident that the dye of the previously dyed muff migrated unlevelly and only in small amounts to the white, undyed muff.
By repeating the above procedure, but using instead the trichromatic system of Example 1, then, after knitting the individual layers of the muff, a knitted piece is obtained which has no deviations in shade. In addition, the undyed muff has the same depth of shade as the dyed muff. This means that a complete rectification of the dyeings on both muffs is obtained by a trichromatic dyeing using migrating dyes.
WHAT WE CLAIM IS:
1. A process for the level dyeing of polyester or cellulose triacetate material which comprises treating the material with an aqueous dye liquor which contains at least two migrating disperse dyes which have a diffusion coefficient Do at 1 300C of 2 to 10x10-'0 cm2/sec, a distribution coefficient K at 1300C of 20 to 500 I/kg and a migration half-life t/2 of less than 50 minutes, as well as, optionally, further ingredients by the aqueous exhaust method at a temperature above 100"C.
2. A process according to Claim 1 wherein the aqueous liquor contains three said migrating disperse dyes.
3. A process according to Claim 1 wherein the aqueous dye liquor contains a trichromatic system of migrating disperse dyes.
4. A process according to any one of Claims 1 to 3 wherein the dye liquor is heated without control to the dyeing temperature.
5. A process according to any one of Claims 1 to 4 wherein the aqueous liquor contains one or more acids, salts and/or dispersants as further ingredients.
6. A process according to any one of Claims I to 4 wherein the aqueous liquor contains a carrier.
7. A process according to any one of Claims 1 to 6 which is carried out at a temperature from 110 to 1400C under pressure.
8. A process according to any one of Claims 1 to 7 wherein at least one of the disperse dyes has a diffusion coefficient Do at 1300C of 2.5 to 10x 10-l cm2/sec, a distribution coefficient K at 1300C of 60 to 350 I/kg, and a migration half-life t/2 of less than 30 minutes.
9. A process according to any one of Claims I to 8 wherein the dye liquor contains two or more of the following migrating disperse dyes:
Do = 6.0
K = 193 t/2 = 17
Do = 3.7
K = 152
t/2 = 35
**WARNING** end of DESC field may overlap start of CLMS **.
Claims (14)
1. A process for the level dyeing of polyester or cellulose triacetate material which comprises treating the material with an aqueous dye liquor which contains at least two migrating disperse dyes which have a diffusion coefficient Do at 1 300C of 2 to 10x10-'0 cm2/sec, a distribution coefficient K at 1300C of 20 to 500 I/kg and a migration half-life t/2 of less than 50 minutes, as well as, optionally, further ingredients by the aqueous exhaust method at a temperature above 100"C.
2. A process according to Claim 1 wherein the aqueous liquor contains three said migrating disperse dyes.
3. A process according to Claim 1 wherein the aqueous dye liquor contains a trichromatic system of migrating disperse dyes.
4. A process according to any one of Claims 1 to 3 wherein the dye liquor is heated without control to the dyeing temperature.
5. A process according to any one of Claims 1 to 4 wherein the aqueous liquor contains one or more acids, salts and/or dispersants as further ingredients.
6. A process according to any one of Claims I to 4 wherein the aqueous liquor contains a carrier.
7. A process according to any one of Claims 1 to 6 which is carried out at a temperature from 110 to 1400C under pressure.
8. A process according to any one of Claims 1 to 7 wherein at least one of the disperse dyes has a diffusion coefficient Do at 1300C of 2.5 to 10x 10-l cm2/sec, a distribution coefficient K at 1300C of 60 to 350 I/kg, and a migration half-life t/2 of less than 30 minutes.
9. A process according to any one of Claims I to 8 wherein the dye liquor contains two or more of the following migrating disperse dyes:
Do = 6.0
K = 193 t/2 = 17
Do = 3.7
K = 152
t/2 = 35
Do = 5.0
K = 81 t/2 = 25
CI Disperse Blue 26 Do=4.8
(methylated mixture of K=315
diaminoanthrarufine and t/2=22
diaminochrysazine)
and CI Disperse Blue 95 Do=4.8
(mixture of diaminoanthra- K=315
rufine and diaminocrysazine, t/2w22 treated with formaldehyde)
10. A process according to Claim 9 wherein the dye liquor contains two or
more of the first three dyes specified in Claim 9.
11. A process according to Claim 1 substantially as described in any one of the
foregoing Examples 1 to 4.
12. Polyester or cellulose triacetate material whenever dyed by a process as
claimed in any one of Claims 1 to 11.
13. An aqeuous dye liquor which contains at least two migrating disperse dyes as defined in Claim I and, optionally, further ingredients.
14. A liquor according to Claim 13 which has one or more of the features of
Claims 2, 3, 5, 6 and 8 to 10.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH1647276 | 1976-12-30 | ||
CH638677A CH614827GA3 (en) | 1977-05-24 | 1977-05-24 | Process for level dyeing of polyester and cellulose triacetate materials |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1596179A true GB1596179A (en) | 1981-08-19 |
Family
ID=25699494
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5379277A Expired GB1596179A (en) | 1976-12-30 | 1977-12-23 | Process for the level dyeing of plyester or cellulose triacetate material |
Country Status (7)
Country | Link |
---|---|
JP (1) | JPS6012475B2 (en) |
BR (1) | BR7708765A (en) |
DE (1) | DE2758417A1 (en) |
ES (1) | ES465547A1 (en) |
FR (1) | FR2376245A1 (en) |
GB (1) | GB1596179A (en) |
MX (1) | MX146069A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4432770A (en) * | 1981-11-21 | 1984-02-21 | Sandoz Ltd. | Rapid dyeing of polyester fibers with a mixture of disperse dyes |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3109954A1 (en) * | 1981-03-14 | 1982-09-23 | Bayer Ag, 5090 Leverkusen | METHOD FOR COLORING HYDROPHOBIC FIBER MATERIAL |
JPS591783A (en) * | 1982-06-23 | 1984-01-07 | 東レ株式会社 | Dyeing of plolyurethane containing fiber sheet |
JPS5951950A (en) * | 1982-09-17 | 1984-03-26 | Mitsubishi Chem Ind Ltd | Blended dye composition having ultrahigh light fastness |
JPH03121865U (en) * | 1990-03-23 | 1991-12-12 |
-
1977
- 1977-12-23 GB GB5379277A patent/GB1596179A/en not_active Expired
- 1977-12-28 DE DE19772758417 patent/DE2758417A1/en not_active Ceased
- 1977-12-28 FR FR7739524A patent/FR2376245A1/en active Granted
- 1977-12-29 ES ES465547A patent/ES465547A1/en not_active Expired
- 1977-12-29 JP JP52158637A patent/JPS6012475B2/en not_active Expired
- 1977-12-29 BR BR7708765A patent/BR7708765A/en unknown
-
1978
- 1978-01-02 MX MX17188278A patent/MX146069A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4432770A (en) * | 1981-11-21 | 1984-02-21 | Sandoz Ltd. | Rapid dyeing of polyester fibers with a mixture of disperse dyes |
Also Published As
Publication number | Publication date |
---|---|
DE2758417A1 (en) | 1978-11-30 |
MX146069A (en) | 1982-05-11 |
FR2376245A1 (en) | 1978-07-28 |
FR2376245B1 (en) | 1980-10-10 |
ES465547A1 (en) | 1980-12-16 |
JPS5386883A (en) | 1978-07-31 |
BR7708765A (en) | 1978-09-05 |
JPS6012475B2 (en) | 1985-04-01 |
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