GB1537375A - Soluble copper phthalocyanine dyes and their use - Google Patents
Soluble copper phthalocyanine dyes and their useInfo
- Publication number
- GB1537375A GB1537375A GB571776A GB571776A GB1537375A GB 1537375 A GB1537375 A GB 1537375A GB 571776 A GB571776 A GB 571776A GB 571776 A GB571776 A GB 571776A GB 1537375 A GB1537375 A GB 1537375A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenyl
- copper phthalocyanine
- groups
- dyes
- feb
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/08—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Paints Or Removers (AREA)
Abstract
1537375 Copper phthalocyanines BASF AG 13 Feb 1976 [14 Feb 1975] 05717/76 Heading C4P The invention comprises copper phthalocyanine dyes having the general Formula (I) wherein m has a mean value of at least 3, the sum (n+m) is not more than 16, CuPc is a copper phthalocyanine radical devoid of hydroxy groups attached to the phenylene nucleus thereof, X is chlorine or bromine, R is phenyl optionally substituted by one or more substituents which do not confer solubility in water, the groups R may be the same or different and if n is more than one, the groups X may be the same or different. Preferred R groups are phenyl, methyl-phenyl, tbutylphenyl, i-propylphenyl, octylphenyl, dodecylphenyl, dimethylphenyl, diethylphenyl, trifluoromethylphenyl, methoxyphenyl, cyclohexylphenyl, diphenyl, bis-(phenylethyl)phenyl, 4-(α,α- dimethyl - p - hydroxybenzyl) phenyl, dimethyl-, aminophenyl, 2 - pyrrolidon - 1 - yl - phenyl, chlorophenyl and chloromethylphenyl. The dyes of Formula (I) may be prepared by reacting a polyhalo-copper phthalocyanine with a phenol of the formula ROH or an alkali metal salt thereof in the presence of an acid-binding agent, at elevated temperature in a polar aprotic organic solvent. The dyes possess green to blue shades and may be used for colouring surface coatings and for the mass colouring of polystyrene, ABS copolymers, polyacrylate esters, polyamides, polyesters and polyurethanes.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19752506153 DE2506153A1 (en) | 1975-02-14 | 1975-02-14 | SOLUBLE COPPER PHTHALOCYANINE DYES AND THEIR APPLICATION |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1537375A true GB1537375A (en) | 1978-12-29 |
Family
ID=5938845
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB571776A Expired GB1537375A (en) | 1975-02-14 | 1976-02-13 | Soluble copper phthalocyanine dyes and their use |
Country Status (6)
Country | Link |
---|---|
JP (1) | JPS51106125A (en) |
CH (1) | CH601440A5 (en) |
DE (1) | DE2506153A1 (en) |
FR (1) | FR2300788A1 (en) |
GB (1) | GB1537375A (en) |
IT (1) | IT1053848B (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5135972A (en) * | 1989-09-18 | 1992-08-04 | Milliken Research Corporation | Poly(oxyalkylene) modified phthalocyanine colorants |
US5292855A (en) * | 1993-02-18 | 1994-03-08 | Eastman Kodak Company | Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein |
US5397819A (en) * | 1991-11-08 | 1995-03-14 | Eastman Chemical Company | Thermoplastic materials containing near infrared fluorophores |
US5423432A (en) * | 1993-12-30 | 1995-06-13 | Eastman Chemical Company | Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein |
US5990197A (en) * | 1996-10-28 | 1999-11-23 | Eastman Chemical Company | Organic solvent based ink for invisible marking/identification |
US6138913A (en) * | 1997-11-05 | 2000-10-31 | Isotag Technology, Inc. | Security document and method using invisible coded markings |
US6197851B1 (en) | 1996-08-30 | 2001-03-06 | Eastman Chemical Company | Polyester compositions containing near infrared absorbing materials to improve reheat |
US6217794B1 (en) | 1998-06-01 | 2001-04-17 | Isotag Technology, Inc. | Fiber coating composition having an invisible marker and process for making same |
US6432715B1 (en) | 1998-02-24 | 2002-08-13 | Isotag Technology, Inc. | Method for marking items for identification |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61152769A (en) * | 1984-12-26 | 1986-07-11 | Tdk Corp | Phthalocyanine compound |
DE69230121T2 (en) * | 1991-07-15 | 2000-04-20 | Nippon Catalytic Chem Ind | New phthalocyanine compounds, their manufacturing processes and the near infrared absorbing materials they contain |
JP5089190B2 (en) * | 2006-02-15 | 2012-12-05 | キヤノン株式会社 | Water-based ink, ink set, ink jet recording method, ink cartridge, recording unit and ink jet recording apparatus |
-
1975
- 1975-02-14 DE DE19752506153 patent/DE2506153A1/en not_active Withdrawn
-
1976
- 1976-02-10 FR FR7603608A patent/FR2300788A1/en active Granted
- 1976-02-11 CH CH166776A patent/CH601440A5/xx not_active IP Right Cessation
- 1976-02-12 IT IT4807176A patent/IT1053848B/en active
- 1976-02-13 GB GB571776A patent/GB1537375A/en not_active Expired
- 1976-02-14 JP JP1443476A patent/JPS51106125A/en active Pending
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5135972A (en) * | 1989-09-18 | 1992-08-04 | Milliken Research Corporation | Poly(oxyalkylene) modified phthalocyanine colorants |
US5397819A (en) * | 1991-11-08 | 1995-03-14 | Eastman Chemical Company | Thermoplastic materials containing near infrared fluorophores |
US5461136A (en) * | 1991-11-08 | 1995-10-24 | Eastman Chemical Company | Method for tagging thermoplastic materials with near infrared fluorophores |
US5553714A (en) * | 1991-11-08 | 1996-09-10 | Eastman Chemical Company | Method for detecting and separating thermoplastic containers with near infrared fluorosphores |
US5703229A (en) * | 1991-11-08 | 1997-12-30 | Eastman Chemical Company | Method for tagging thermoplastic materials with near infrared fluorophores |
US5292855A (en) * | 1993-02-18 | 1994-03-08 | Eastman Kodak Company | Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein |
US5423432A (en) * | 1993-12-30 | 1995-06-13 | Eastman Chemical Company | Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein |
US6197851B1 (en) | 1996-08-30 | 2001-03-06 | Eastman Chemical Company | Polyester compositions containing near infrared absorbing materials to improve reheat |
US5990197A (en) * | 1996-10-28 | 1999-11-23 | Eastman Chemical Company | Organic solvent based ink for invisible marking/identification |
US6138913A (en) * | 1997-11-05 | 2000-10-31 | Isotag Technology, Inc. | Security document and method using invisible coded markings |
US6432715B1 (en) | 1998-02-24 | 2002-08-13 | Isotag Technology, Inc. | Method for marking items for identification |
US6217794B1 (en) | 1998-06-01 | 2001-04-17 | Isotag Technology, Inc. | Fiber coating composition having an invisible marker and process for making same |
Also Published As
Publication number | Publication date |
---|---|
FR2300788A1 (en) | 1976-09-10 |
FR2300788B1 (en) | 1980-04-18 |
JPS51106125A (en) | 1976-09-20 |
DE2506153A1 (en) | 1976-08-26 |
CH601440A5 (en) | 1978-07-14 |
IT1053848B (en) | 1981-10-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |