GB1522629A - Process for the preparation of catalysts - Google Patents

Process for the preparation of catalysts

Info

Publication number
GB1522629A
GB1522629A GB38013/75A GB3801375A GB1522629A GB 1522629 A GB1522629 A GB 1522629A GB 38013/75 A GB38013/75 A GB 38013/75A GB 3801375 A GB3801375 A GB 3801375A GB 1522629 A GB1522629 A GB 1522629A
Authority
GB
United Kingdom
Prior art keywords
diameter
catalysts
sept
pores
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB38013/75A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1522629A publication Critical patent/GB1522629A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0063—Granulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1522629 Hydrotreatment catalysts SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 16 Sept 1975 [18 Sept 1974] 38013/75 Heading B1E [Also in Division C5] Catalysts have a quotient pd>15, where p is the specific average pore diameter in nm and d is the specific average particle diameter in mm; at least 50% of the total pore volume in pores of diameter >100nm; at least 0.2 ml/g of pore volume in pores of diameter >50nm; and a specific surface area >150 m<SP>2</SP>/g, the catalyst comprising a hydrogenation component and having been prepared by the nodulizing technique from a starting material with a specific surface area >200 m<SP>2</SP>/g. The catalyst can be used in the demetallisation and upgrading of hydrocarbon oils.
GB38013/75A 1974-09-18 1975-09-16 Process for the preparation of catalysts Expired GB1522629A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7412337A NL7412337A (en) 1974-09-18 1974-09-18 PROCEDURE FOR THE PREPARATION OF NEW CATALYSTS.

Publications (1)

Publication Number Publication Date
GB1522629A true GB1522629A (en) 1978-08-23

Family

ID=19822123

Family Applications (1)

Application Number Title Priority Date Filing Date
GB38013/75A Expired GB1522629A (en) 1974-09-18 1975-09-16 Process for the preparation of catalysts

Country Status (13)

Country Link
JP (1) JPS604738B2 (en)
AU (1) AU498758B2 (en)
BE (1) BE833204A (en)
CA (1) CA1072530A (en)
DE (1) DE2541306A1 (en)
FR (1) FR2285177A1 (en)
GB (1) GB1522629A (en)
IT (1) IT1042594B (en)
NL (1) NL7412337A (en)
NO (1) NO146847C (en)
SE (1) SE420418B (en)
SU (1) SU645595A3 (en)
ZA (1) ZA755889B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2151499A (en) * 1983-12-19 1985-07-24 Intevep Sa Demetallization of heavy crudes
EP0683218A2 (en) 1994-05-19 1995-11-22 Shell Internationale Researchmaatschappij B.V. Process for the conversion of a residual hydrocarbon oil
WO2010084112A1 (en) 2009-01-20 2010-07-29 Shell Internationale Research Maatschappij B.V. Process for the hydro-demetallization of hydrocarbon feedstocks

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2486094B1 (en) * 1980-07-02 1985-03-22 Catalyse Soc Prod Francais
DE3045221A1 (en) * 1980-12-01 1982-06-03 Joh. A. Benckiser Gmbh, 6700 Ludwigshafen ABRASION-RESISTANT GRANULES BASED ON ALKALIAL ALUMINUM SILICATE WITH A GOOD DISPERSING CAPACITY IN AQUEOUS FOLLOW
AU547464B2 (en) * 1981-06-17 1985-10-24 Amoco Corporation Catalyst for hydrotreating hydrocarbon feed
FR2511389A1 (en) * 1981-08-11 1983-02-18 Inst Francais Du Petrole PROCESS FOR THE CATALYTIC HYDROCONVERSION OF LIQUID PHASE HEAVY HYDROCARBONS AND THE PRESENCE OF A DISPERSE CATALYST AND CHARCOAL PARTICLES
GB8701740D0 (en) * 1987-01-27 1987-03-04 Shell Int Research Catalytic conversion of hydrocarbon oils
RU2506997C1 (en) * 2012-08-27 2014-02-20 Федеральное государственное бюджетное учреждение науки Институт проблем переработки углеводородов Сибирского отделения Российской академии наук Catalyst of recycling heavy oil fractions
CN107983414B (en) * 2016-10-26 2021-01-08 中国石油化工股份有限公司 Hydrogenation catalyst

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1408759A (en) * 1971-12-07 1975-10-01 Shell Int Research Catalytic hydrodesulphurisation process
NL175732C (en) * 1972-07-07 Shell Int Research PROCEDURE FOR THE CATALYTIC DEMETALLIZATION OF RESIDUAL HYDROCARBON OILS AND THE FURTHER CATALYTIC CONVERSION OF THE OIL OBTAINED THEREIN.

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2151499A (en) * 1983-12-19 1985-07-24 Intevep Sa Demetallization of heavy crudes
GB2174015A (en) * 1983-12-19 1986-10-29 Intevep Sa Demetallization of heavy crudes
GB2191957A (en) * 1983-12-19 1987-12-31 Intevep Sa Demetallization of heavy crudes
EP0683218A2 (en) 1994-05-19 1995-11-22 Shell Internationale Researchmaatschappij B.V. Process for the conversion of a residual hydrocarbon oil
WO2010084112A1 (en) 2009-01-20 2010-07-29 Shell Internationale Research Maatschappij B.V. Process for the hydro-demetallization of hydrocarbon feedstocks

Also Published As

Publication number Publication date
AU498758B2 (en) 1979-03-22
JPS604738B2 (en) 1985-02-06
SE420418B (en) 1981-10-05
IT1042594B (en) 1980-01-30
FR2285177A1 (en) 1976-04-16
NO146847C (en) 1982-12-22
NL7412337A (en) 1976-03-22
CA1072530A (en) 1980-02-26
SE7510363L (en) 1976-03-19
FR2285177B1 (en) 1981-08-07
DE2541306C2 (en) 1987-07-23
BE833204A (en) 1976-03-09
NO753148L (en) 1976-03-19
NO146847B (en) 1982-09-13
AU8487375A (en) 1977-03-24
JPS5155791A (en) 1976-05-17
SU645595A3 (en) 1979-01-30
DE2541306A1 (en) 1976-04-08
ZA755889B (en) 1976-08-25

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19940916