GB1502527A - Cyclopropane derivatives - Google Patents

Cyclopropane derivatives

Info

Publication number
GB1502527A
GB1502527A GB1394176A GB1394176A GB1502527A GB 1502527 A GB1502527 A GB 1502527A GB 1394176 A GB1394176 A GB 1394176A GB 1394176 A GB1394176 A GB 1394176A GB 1502527 A GB1502527 A GB 1502527A
Authority
GB
United Kingdom
Prior art keywords
formula
cyclopropane
formyl
april
dimethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1394176A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Publication of GB1502527A publication Critical patent/GB1502527A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D317/30—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1502527 Cyclopropane derivatives ROUSSEL UCLAF 6 April 1976 [7 April 1975] 13941/76 Heading C2C The invention comprises a process for the preparation of compounds of the formula where R is C 1- C 6 alkyl, each R 1 is C 1 -C 4 alkyl or the two R 1 radicals together represent -(CH 2 ) n - in which n is 2 or 3 and X is O or S by reacting a compound of the formula in the presence of a strong base with a triphenyl isopropyl phosphonium halide. The invention further comprises methyl 2,2-dimethyl-3RS- formyl - cyclopropane - 1RS - carboxylate diethyl acetal and methyl 2,2-dimethyl-3RS- formyl-cyclopropane-1RS-carboxylate diethylene acetal. Compounds of Formula III may be hydrolysed under acidic conditions to yield a compound of the formula which may subsequently be saponified to yield the free acid.
GB1394176A 1975-04-07 1976-04-06 Cyclopropane derivatives Expired GB1502527A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE155169A BE827652A (en) 1975-04-07 1975-04-07 NEW PROCESS FOR THE PREPARATION OF LOWER ALCOYL ESTERS OF HEMICARONIC ALDEHYDE

Publications (1)

Publication Number Publication Date
GB1502527A true GB1502527A (en) 1978-03-01

Family

ID=3842757

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1394176A Expired GB1502527A (en) 1975-04-07 1976-04-06 Cyclopropane derivatives

Country Status (11)

Country Link
JP (2) JPS51127050A (en)
BE (1) BE827652A (en)
CA (1) CA1091250A (en)
CH (1) CH609027A5 (en)
DE (1) DE2615160A1 (en)
DK (1) DK134176A (en)
FR (1) FR2306970A1 (en)
GB (1) GB1502527A (en)
IE (1) IE43363B1 (en)
IT (1) IT1065993B (en)
NL (1) NL7603678A (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE827652A (en) * 1975-04-07 1975-10-07 NEW PROCESS FOR THE PREPARATION OF LOWER ALCOYL ESTERS OF HEMICARONIC ALDEHYDE
DE2923774A1 (en) * 1979-06-12 1980-12-18 Bayer Ag METHOD FOR PRODUCING 3,3-DIMETHYL-CYCLOPROPAN-1,2-DICARBONIC ACID ESTERS
DE2927133A1 (en) * 1979-07-05 1981-01-08 Bayer Ag METHOD FOR PRODUCING 2-FORMYL-3,3-DIMETHYL-CYCLOPROPAN1-CARBONIC ACID ESTERS
FR2490633A1 (en) * 1980-09-24 1982-03-26 Roussel Uclaf PROCESS FOR THE PREPARATION OF CYCLOPROPANE CARBOXYLIC ACID DERIVATIVES WITH ALDEHYDE FUNCTION
FR2624511B1 (en) * 1987-12-11 1990-09-21 Roussel Uclaf ENANTIOSELECTIVE PROCESS FOR PREPARING HEMICARONIC ALDEHYDE DERIVATIVES WITH TRANS OR CIS STRUCTURE

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE827652A (en) * 1975-04-07 1975-10-07 NEW PROCESS FOR THE PREPARATION OF LOWER ALCOYL ESTERS OF HEMICARONIC ALDEHYDE

Also Published As

Publication number Publication date
JPS51127050A (en) 1976-11-05
CH609027A5 (en) 1979-02-15
JPS5929058B2 (en) 1984-07-18
DE2615160A1 (en) 1976-10-21
CA1091250A (en) 1980-12-09
IT1065993B (en) 1985-03-04
JPS51127049A (en) 1976-11-05
IE43363L (en) 1976-10-07
IE43363B1 (en) 1981-02-11
FR2306970A1 (en) 1976-11-05
BE827652A (en) 1975-10-07
NL7603678A (en) 1976-10-11
DK134176A (en) 1976-10-08
FR2306970B1 (en) 1979-10-05

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee