GB1490859A - Polymerization of vinylidene monomers - Google Patents
Polymerization of vinylidene monomersInfo
- Publication number
- GB1490859A GB1490859A GB5458174A GB5458174A GB1490859A GB 1490859 A GB1490859 A GB 1490859A GB 5458174 A GB5458174 A GB 5458174A GB 5458174 A GB5458174 A GB 5458174A GB 1490859 A GB1490859 A GB 1490859A
- Authority
- GB
- United Kingdom
- Prior art keywords
- monomers
- monomer
- butyl
- parts
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1490859 Polymerizing in the presence of tetrahydrofuran B F GOODRICH CO 18 Dec 1974 54581/74 Heading C3P A process for the production of polymers by aqueous suspension or bulk polymerization of one or more vinylidene monomers, e.g. vinyl chloride containing a terminal vinyl or vinylidene group comprises polymerizing the monomer(s) in the presence of a free radical catalyst at 0-60‹ C. in the presence of 5 parts to 100 parts by weight, based on 100 parts by weight of monomer(s) of tetrahydrofuran, the polymerization being continued to a point no greater than 80% conversion of monomer or monomers to polymer. Preferably the mixture of monomers is vinyl chloride and vinyl acrylate or vinylidene chloride, and exemplified catalysts are sec.-butyl peroxydicarbonate, di(sec.-butyl)- peroxydicarbonate, and di(iso-butyl)peroxide. The T.H.F. partly acts as a molecular weight regulator.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5458174A GB1490859A (en) | 1974-12-18 | 1974-12-18 | Polymerization of vinylidene monomers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5458174A GB1490859A (en) | 1974-12-18 | 1974-12-18 | Polymerization of vinylidene monomers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1490859A true GB1490859A (en) | 1977-11-02 |
Family
ID=10471474
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5458174A Expired GB1490859A (en) | 1974-12-18 | 1974-12-18 | Polymerization of vinylidene monomers |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1490859A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0656374A2 (en) * | 1993-12-01 | 1995-06-07 | Röhm GmbH | Polymethacrylate moulding matter with elevated heat distortion resistance and elevated resistance against thermal degradation |
-
1974
- 1974-12-18 GB GB5458174A patent/GB1490859A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0656374A2 (en) * | 1993-12-01 | 1995-06-07 | Röhm GmbH | Polymethacrylate moulding matter with elevated heat distortion resistance and elevated resistance against thermal degradation |
EP0656374A3 (en) * | 1993-12-01 | 1995-06-28 | Roehm Gmbh | |
US5530080A (en) * | 1993-12-01 | 1996-06-25 | Roehm Gmbh Chemische Fabrik | Polymethacrylate molding compound with high heat deflection temperature and stability against thermal degradation |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |