GB1490494A - Process for the production of low molecular weight hydrocarbons - Google Patents
Process for the production of low molecular weight hydrocarbonsInfo
- Publication number
- GB1490494A GB1490494A GB15992/76A GB1599276A GB1490494A GB 1490494 A GB1490494 A GB 1490494A GB 15992/76 A GB15992/76 A GB 15992/76A GB 1599276 A GB1599276 A GB 1599276A GB 1490494 A GB1490494 A GB 1490494A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reactor
- catalyst
- gas
- per
- catalytic hydrogenation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229930195733 hydrocarbon Natural products 0.000 title abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 8
- 238000009903 catalytic hydrogenation reaction Methods 0.000 abstract 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 2
- BXVSAYBZSGIURM-UHFFFAOYSA-N 2-phenoxy-4h-1,3,2$l^{5}-benzodioxaphosphinine 2-oxide Chemical compound O1CC2=CC=CC=C2OP1(=O)OC1=CC=CC=C1 BXVSAYBZSGIURM-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000005751 Copper oxide Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910000431 copper oxide Inorganic materials 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/657—Pore diameter larger than 1000 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1490494 C 2 -C 4 olefins by hydrogenation of carbon monoxide RUHRCHEMIE AG 20 April 1976 [29 April 1975] 15992/76 Heading C5E A process for the production of a hydrocarbon mixture containing at least 50% by weight of one or more C 2 to C 4 hydrocarbons and at least 50% by weight of one or more olefins the percentage being used on the total content of hydrocarbons having at least 2 carbon atoms, comprises catalytic hydrogenation of carbon monoxide in a fixed-bed reactor under superatmospheric total pressure and at elevated temperatures, as follows: the catalytic hydrogenation is carried out using one or more catalysts arranged in at least 2 and not more than 10 layers: the catalytic hydrogenation is carried out in a reactor having a length of from 0À5 to 4À5 meters: the pressure in the reactor is from 5 to 30 bars: the temperature measured on the catalyst is from 250 to 370 C: the space velocity of fresh gas through the reactor is adjusted to from 1,000 to 10,000 std. cu.m.per cu.m. of catalyst per hour and: the rate of supply of recycle gas to the reactor is adjusted to from 5 times to 25 times the rate of supply of fresh gas to the reactor: the total gas loading to the reactor is from 7,500 to 50,000std.cu.m.per cu.m. of catalyst per hour and the catalyst is arranged in such a manner that the linear gas flow velocity through the reactor ranges between 1 and 10 m./second, based on normal conditions, and the residence time of the gas in the reactor ranges between 0À05 and 1 second, based of normal conditions, and the or each catalyst has an internal surface area of 5 to 150 sq.m. per gram of catalyst. A preferred catalyst comprises iron oxide, copper oxide, zinc oxide and K 2 CO 3 .
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19752518982 DE2518982C3 (en) | 1975-04-29 | Process for the production of hydrocarbon mixtures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1490494A true GB1490494A (en) | 1977-11-02 |
Family
ID=5945273
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB15992/76A Expired GB1490494A (en) | 1975-04-29 | 1976-04-20 | Process for the production of low molecular weight hydrocarbons |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS51131808A (en) |
| AU (1) | AU498400B2 (en) |
| BE (1) | BE840969A (en) |
| CA (1) | CA1053265A (en) |
| DD (1) | DD123881A5 (en) |
| FR (1) | FR2309497A1 (en) |
| GB (1) | GB1490494A (en) |
| NL (1) | NL162622C (en) |
| ZA (1) | ZA762412B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7012103B2 (en) | 2003-03-24 | 2006-03-14 | Conocophillips Company | Commercial fischer-tropsch reactor |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4206134A (en) * | 1979-03-12 | 1980-06-03 | Exxon Research & Engineering Co. | Ruthenium supported on manganese oxide as hydrocarbon synthesis catalysts in CO/H2 reactions |
| US4402869A (en) | 1979-03-12 | 1983-09-06 | Exxon Research And Engineering Co. | Group VIII metals on manganese-containing oxide supports which exhibit strong metal support interactions |
| EP0101913A3 (en) * | 1982-08-03 | 1986-07-30 | BASF Aktiengesellschaft | Dehydrogenation catalyst |
| GB0501731D0 (en) * | 2005-01-31 | 2005-03-02 | Accentus Plc | Catalytic reactor |
-
1975
- 1975-08-13 NL NL7509662.A patent/NL162622C/en not_active IP Right Cessation
-
1976
- 1976-04-19 JP JP51044400A patent/JPS51131808A/en active Granted
- 1976-04-20 GB GB15992/76A patent/GB1490494A/en not_active Expired
- 1976-04-21 BE BE166342A patent/BE840969A/en unknown
- 1976-04-22 CA CA250,791A patent/CA1053265A/en not_active Expired
- 1976-04-22 DD DD192465A patent/DD123881A5/xx unknown
- 1976-04-22 ZA ZA762412A patent/ZA762412B/en unknown
- 1976-04-22 AU AU13224/76A patent/AU498400B2/en not_active Expired
- 1976-04-22 FR FR7611927A patent/FR2309497A1/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7012103B2 (en) | 2003-03-24 | 2006-03-14 | Conocophillips Company | Commercial fischer-tropsch reactor |
Also Published As
| Publication number | Publication date |
|---|---|
| AU1322476A (en) | 1977-10-27 |
| JPS51131808A (en) | 1976-11-16 |
| JPS5443481B2 (en) | 1979-12-20 |
| FR2309497B1 (en) | 1981-02-13 |
| BE840969A (en) | 1976-10-21 |
| CA1053265A (en) | 1979-04-24 |
| DE2518982B2 (en) | 1977-03-03 |
| NL162622B (en) | 1980-01-15 |
| NL162622C (en) | 1980-06-16 |
| DE2518982A1 (en) | 1976-11-11 |
| FR2309497A1 (en) | 1976-11-26 |
| NL7509662A (en) | 1976-11-02 |
| ZA762412B (en) | 1977-04-27 |
| AU498400B2 (en) | 1979-03-08 |
| DD123881A5 (en) | 1977-01-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |