GB1480530A - Homogeneous highly filled polyolefin compositions - Google Patents

Homogeneous highly filled polyolefin compositions

Info

Publication number
GB1480530A
GB1480530A GB5396874A GB5396874A GB1480530A GB 1480530 A GB1480530 A GB 1480530A GB 5396874 A GB5396874 A GB 5396874A GB 5396874 A GB5396874 A GB 5396874A GB 1480530 A GB1480530 A GB 1480530A
Authority
GB
United Kingdom
Prior art keywords
filler
weight
oxide
transition metal
dec
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5396874A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/449,987 external-priority patent/US3950303A/en
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB1480530A publication Critical patent/GB1480530A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1480530 Polyolefin/filler composites E I DU PONT DE NEMOURS & CO 13 Dec 1974 [14 Dec 1973 (3) 11 March 1974 2 Dec 1974] 53968/74 Heading C3P A polyolefin composite comprises (i) 10-70% by weight of a polyolefin selected from polyethylene, or a copolymer of ethylene containing up to 15% by weight of units derived from at least one 1-alkane of 3 to 10 carbon atoms, having an inherent viscosity (defined) of at least 2À5, (ii) 30-90% by weight of a finely-divided inorganic filler (an inorganic compound which does not contain carbon except as the carbonate) having a neutral-to-acidic surface and a weight average equivalent spherical particle diameter of 0À1-50 Á, and having interacted at its surface (bonded directly or indirectly, preferably through an organoaluminium compound as a monomolecular layer of the filler which contains active polymerization sites such that the transition metal cannot be washed off) sufficient catalytically active transition metal (Group IVa, Va and VIa of the Periodic Table) to provide 0À000001-1À7 millimole of transition metal per gram of filler; wherein said olefin is polymerized on to the surface of said filler, and said composite has a 10-second micronization homogenity (defined) of at least 50% and a micronization homogenity index (defined) of at least 20. The filler may be selected from aluminium silicate clay (kaolinite, attapulgite, fuller's earth, bentonite), alumina hydrates (Al 2 O 3 1À5-3 H 2 O), silicas, water-insoluble silicates, water-insoluble calcium phosphates, titania, zinc oxide, iron oxide and antimony oxide which may have a surface area of 0À01- 100 m.<SP>2</SP>/g., and the filler may also comprise 0-30% by weight of a pigmentary oxide (e.g. titania, zinc, oxide, antimony oxide) free of catalytically active transition metal compound. The composites may be used to form articles; e.g. by subjection, optionally in a mould, to a temperature of 105-250‹ C. and pressures of 10-100,000 p.s.i.g.
GB5396874A 1973-12-14 1974-12-13 Homogeneous highly filled polyolefin compositions Expired GB1480530A (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US42482173A 1973-12-14 1973-12-14
US42482073A 1973-12-14 1973-12-14
US42482273A 1973-12-14 1973-12-14
US44429574A 1974-02-21 1974-02-21
US05/449,987 US3950303A (en) 1974-03-11 1974-03-11 Polyolefin/chromium modified mineral compositions and process for their preparation
US52900674A 1974-12-02 1974-12-02

Publications (1)

Publication Number Publication Date
GB1480530A true GB1480530A (en) 1977-07-20

Family

ID=27559970

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5396874A Expired GB1480530A (en) 1973-12-14 1974-12-13 Homogeneous highly filled polyolefin compositions

Country Status (1)

Country Link
GB (1) GB1480530A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4473672A (en) * 1981-04-09 1984-09-25 Imperial Chemical Industries Plc Polymer composition, production and use
US4564647A (en) * 1983-11-14 1986-01-14 Idemitsu Kosan Company Limited Process for the production of polyethylene compositions
EP0328753A2 (en) * 1988-02-16 1989-08-23 Felix Schoeller jr. Papierfabrik GmbH & Co. KG Process for the preparation of a pigment-resin concentrate
EP0881232A1 (en) * 1997-05-27 1998-12-02 Tosoh Corporation Catalyst for olefin polymerization and process for production of olefin polymer
WO2001066652A1 (en) * 2000-03-10 2001-09-13 Depco-Trh Pty Ltd Particulate titanium dioxide coated product and method of forming titanium dioxide coated particles

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4473672A (en) * 1981-04-09 1984-09-25 Imperial Chemical Industries Plc Polymer composition, production and use
US4564647A (en) * 1983-11-14 1986-01-14 Idemitsu Kosan Company Limited Process for the production of polyethylene compositions
EP0328753A2 (en) * 1988-02-16 1989-08-23 Felix Schoeller jr. Papierfabrik GmbH & Co. KG Process for the preparation of a pigment-resin concentrate
EP0328753A3 (en) * 1988-02-16 1991-09-25 Felix Schoeller jr. Papierfabrik GmbH & Co. KG Process for the preparation of a pigment-resin concentrate
EP0881232A1 (en) * 1997-05-27 1998-12-02 Tosoh Corporation Catalyst for olefin polymerization and process for production of olefin polymer
US6034187A (en) * 1997-05-27 2000-03-07 Tosoh Corporation Catalyst for olefin polymerization and process for production of olefin polymer
WO2001066652A1 (en) * 2000-03-10 2001-09-13 Depco-Trh Pty Ltd Particulate titanium dioxide coated product and method of forming titanium dioxide coated particles
US7285328B2 (en) 2000-03-10 2007-10-23 Depco-Trh Pty Ltd Particulate titanium dioxide coated product and method of forming titanium dioxide coated particles

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19931213