GB1472881A - Process for foaming ionic polymers and the products thereof - Google Patents
Process for foaming ionic polymers and the products thereofInfo
- Publication number
- GB1472881A GB1472881A GB1230874A GB1230874A GB1472881A GB 1472881 A GB1472881 A GB 1472881A GB 1230874 A GB1230874 A GB 1230874A GB 1230874 A GB1230874 A GB 1230874A GB 1472881 A GB1472881 A GB 1472881A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymer
- foamed
- less
- ionic
- plasticizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/06—Recovery or working-up of waste materials of polymers without chemical reactions
- C08J11/08—Recovery or working-up of waste materials of polymers without chemical reactions using selective solvents for polymer components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
1472881 Foamed plasticized sulphonated polymers EXXON RESEARCH & ENG CO 20 March 1974 [29 March 1973] 12308/74 Heading C3C A foamed polymer having a uniform cell structure is made by mixing at a temperature of at least 40‹ C. and a pressure of more than 6 p.s.i. above atmospheric a foaming agent comprising a compound having a solubility parameter of less than 7À9 and more than 4À5 an ionic polymer having 0À2-20 mole per cent of sulphonic acid groups neutralized to a degree of at least 90% with a neutralizing agent which is ammonia, a C 1-30 amine, a basic compound whose cation is a metal of Groups Ia, IIa, Ib or IIb of the Mendeleeff Periodic Table of Elements, lead, tin, antimony or aluminium, and a non- volatile polar compound having a dipole moment of at least 0À9 debyes, of b.p. greater than 150‹ C. at atmospheric pressure and which is a preferential plasticizer for the pendant ionic groups of the polymer (i.e. having no effect on the non-ionic portion of the polymer), whereby the plasticizer is incorporated into the polymer which is then foamed. The foamed polymer has a density of less than 10 lb/foot<SP>3</SP>, an average cell volume of less than 0À3 x 10<SP>-3</SP> cm.<SP>3</SP>, and less than 5% of the foamed volume is occupied by cells of volumes greater than 0À5 x 10<SP>-2</SP> cm.<SP>3</SP> In the examples sulphonated polystyrenes, which were 100% neutralized and had sodium or barium as the cation, were mixed with the above polar compound, viz. phenethanol, pentaerythritol, 3,4-dimethyl benzoic acid or decanol, moulded into a pad and immersed in dichlorodifluoromethane, isopentane, butane, pentane or 1,1,2 - trichlorotrifluoro - ethane under elevated temperature and pressure, and then the impregnated polymer was foamed by heating in silicone oil or by exposure to microwave radiation. The ionic polymer may also be a sulphonated styrene/ t-butyl styrene copolymer and an adipate, citrate, glycolate, laurate, oleate, palmitate, phthalate, phosphate or sebacate may also be used as a chain-plasticizer.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US34597273A | 1973-03-29 | 1973-03-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1472881A true GB1472881A (en) | 1977-05-11 |
Family
ID=23357364
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1230874A Expired GB1472881A (en) | 1973-03-29 | 1974-03-20 | Process for foaming ionic polymers and the products thereof |
Country Status (9)
Country | Link |
---|---|
JP (1) | JPS5753375B2 (en) |
BE (1) | BE812986A (en) |
BR (1) | BR7402537D0 (en) |
CA (1) | CA1042150A (en) |
DE (1) | DE2414186A1 (en) |
FR (1) | FR2223407B1 (en) |
GB (1) | GB1472881A (en) |
IT (1) | IT1018644B (en) |
NL (1) | NL7404328A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010087848A1 (en) * | 2009-01-30 | 2010-08-05 | University Of Tennessee Research Foundation | Method for expansion and molding of polymeric foam |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60130046A (en) * | 1983-12-16 | 1985-07-11 | Stanley Electric Co Ltd | Fluorescent lamp |
US4529740A (en) * | 1984-02-06 | 1985-07-16 | W. R. Grace & Co. | Foamable hot melt polymer compositions |
JPS60146787U (en) * | 1984-03-12 | 1985-09-28 | プラチナ萬年筆株式会社 | Writing instrument with drug storage case |
JPS61248350A (en) * | 1985-04-24 | 1986-11-05 | Kimoto Sain:Kk | Discharge display device |
JPS62194089U (en) * | 1986-06-02 | 1987-12-10 |
-
1974
- 1974-03-14 CA CA195,028A patent/CA1042150A/en not_active Expired
- 1974-03-20 GB GB1230874A patent/GB1472881A/en not_active Expired
- 1974-03-23 DE DE2414186A patent/DE2414186A1/en not_active Withdrawn
- 1974-03-28 FR FR7410781A patent/FR2223407B1/fr not_active Expired
- 1974-03-28 BE BE142584A patent/BE812986A/en not_active IP Right Cessation
- 1974-03-29 BR BR253774A patent/BR7402537D0/en unknown
- 1974-03-29 NL NL7404328A patent/NL7404328A/xx unknown
- 1974-03-29 JP JP3657274A patent/JPS5753375B2/ja not_active Expired
- 1974-04-02 IT IT4992274A patent/IT1018644B/en active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010087848A1 (en) * | 2009-01-30 | 2010-08-05 | University Of Tennessee Research Foundation | Method for expansion and molding of polymeric foam |
Also Published As
Publication number | Publication date |
---|---|
NL7404328A (en) | 1974-10-01 |
DE2414186A1 (en) | 1974-10-10 |
FR2223407A1 (en) | 1974-10-25 |
BE812986A (en) | 1974-09-30 |
BR7402537D0 (en) | 1974-11-19 |
FR2223407B1 (en) | 1978-01-06 |
JPS5753375B2 (en) | 1982-11-12 |
IT1018644B (en) | 1977-10-20 |
JPS508862A (en) | 1975-01-29 |
CA1042150A (en) | 1978-11-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |