GB1462857A - Anodes for mercury-cathode electrolytic cells - Google Patents

Anodes for mercury-cathode electrolytic cells

Info

Publication number
GB1462857A
GB1462857A GB2333473A GB2333473A GB1462857A GB 1462857 A GB1462857 A GB 1462857A GB 2333473 A GB2333473 A GB 2333473A GB 2333473 A GB2333473 A GB 2333473A GB 1462857 A GB1462857 A GB 1462857A
Authority
GB
United Kingdom
Prior art keywords
coating
polymer
oxide
anode
particulate material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2333473A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB2333473A priority Critical patent/GB1462857A/en
Priority to US465558A priority patent/US3922226A/en
Priority to ZA00742932A priority patent/ZA742932B/en
Publication of GB1462857A publication Critical patent/GB1462857A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C25B11/095—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one of the compounds being organic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Abstract

1462857 Mercury cathode cell anode IMPERIAL CHEMICAL INDUSTRIES Ltd 26 April 1974 [16 May 1973] 23334/73 Heading C7B [Also in Division B2] An anode for a mercury cathode electrolytic cell comprises a support member of titanium or a suitable titanium alloy provided with an anodicallyconducting oxide coating and a porous outer layer of a chlorine-resistant organic polymer (particularly polyvinylidene fluoride or PTFE) and is prepared by firstly coating the anode with the oxidic coating and then either (a) applying to the oxide coating a mixture of the polymer and a solid particulate material, bonding the polymer to the oxide coating by drying, heating to melt the polymer and cooling, and subsequently removing the particulate material from the coating by dissolving in water or acid or by reaction in the electrolytic cell after the anode is put into service; or (b) coating the oxidic coating with a discontinuous layer of solid particulate material, coating with the polymer so as to fill the spaces between the particles, bonding the polymer to the oxide by heating to melt the polymer followed by cooling, and removing the particulate material as before. The oxidic coating may comprise an oxide of a platinum group metal together with an oxide of Ti, Ta, Zr, Nb or W, especially a mixture of RnO 2 and TiO 2 applied as a solution of RuCl 3 and tetrabutyl ortho-titanate followed by heating, and may be applied as a homogeneous mixture or by depositing alternate layers of the two oxides. The polymer may be applied by meltspraying, or by spraying or brushing as an emulsion followed by evaporation of the liquid vehicle. The particulate material may comprise potassium chloride crystals (provided by dipping the oxidecoated anode into saturated aqueous KCl solution followed by drying), starch, cellulose or calcium carbonate.
GB2333473A 1973-05-16 1973-05-16 Anodes for mercury-cathode electrolytic cells Expired GB1462857A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB2333473A GB1462857A (en) 1973-05-16 1973-05-16 Anodes for mercury-cathode electrolytic cells
US465558A US3922226A (en) 1973-05-16 1974-04-30 Anodes for mercury-cathode electrolytic cells
ZA00742932A ZA742932B (en) 1973-05-16 1974-05-08 Improvements in anodes for mercury-cathode electrolytic cells

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2333473A GB1462857A (en) 1973-05-16 1973-05-16 Anodes for mercury-cathode electrolytic cells

Publications (1)

Publication Number Publication Date
GB1462857A true GB1462857A (en) 1977-01-26

Family

ID=10193947

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2333473A Expired GB1462857A (en) 1973-05-16 1973-05-16 Anodes for mercury-cathode electrolytic cells

Country Status (3)

Country Link
US (1) US3922226A (en)
GB (1) GB1462857A (en)
ZA (1) ZA742932B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2149565A (en) * 1983-11-02 1985-06-12 Raychem Ltd Protected metal components

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4315062A (en) * 1978-01-16 1982-02-09 Duracell International Inc. Method for the manufacture of a polystyrene separator and cell
US4472257A (en) * 1980-04-29 1984-09-18 Sklyarov Alexandr T Electrode for electrochemical processes and process for producing same
US4263112A (en) * 1980-06-20 1981-04-21 Frosch Robert A Cell and method for electrolysis of water and anode therefor
CA1190185A (en) * 1980-08-18 1985-07-09 Michael Katz Electrode with outer coating and protective intermediate conductive polymer coating on a conductive base
JPS6022070B2 (en) * 1981-09-22 1985-05-30 ペルメレツク電極株式会社 Cathode for acidic solution electrolysis and its manufacturing method
US4554172A (en) * 1984-07-05 1985-11-19 Olin Corporation Method of repairing electrode surfaces
CN116496110A (en) * 2023-04-10 2023-07-28 广西强强碳素股份有限公司 Method for improving stability of prebaked anode

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3346421A (en) * 1963-12-30 1967-10-10 Exxon Research Engineering Co Transition metal electrode
US3451856A (en) * 1965-01-28 1969-06-24 Union Oil Co Tetrafluoroethylene-coated catalytic nonporous metallic fuel cell anode and process of making same
US3671317A (en) * 1970-02-10 1972-06-20 United Aircraft Corp Method of making fuel cell electrodes
US3681136A (en) * 1970-03-02 1972-08-01 Intern Biophysics Corp Metal-metal salt electrodes and process
US3711385A (en) * 1970-09-25 1973-01-16 Chemnor Corp Electrode having platinum metal oxide coating thereon,and method of use thereof
US3798063A (en) * 1971-11-29 1974-03-19 Diamond Shamrock Corp FINELY DIVIDED RuO{11 {11 PLASTIC MATRIX ELECTRODE

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2149565A (en) * 1983-11-02 1985-06-12 Raychem Ltd Protected metal components
US4615961A (en) * 1983-11-02 1986-10-07 Raychem Corporation Protected metal components

Also Published As

Publication number Publication date
ZA742932B (en) 1975-12-31
US3922226A (en) 1975-11-25

Similar Documents

Publication Publication Date Title
US3882002A (en) Anode for electrolytic processes
FI57132C (en) ELEKTROD AVSEDD FOER ANVAENDNING VID ELEKTROKEMISKA PROCESSER
US4331528A (en) Coated metal electrode with improved barrier layer
CN102465312A (en) Electrode for electrolytic chlorine production
US4163084A (en) Electrochemically stable cathode
Lyons et al. Mechanism of oxygen reactions at porous oxide electrodes. Part 1.—Oxygen evolution at RuO 2 and Ru x Sn 1–x O 2 electrodes in alkaline solution under vigorous electrolysis conditions
US2901522A (en) Oxidation cells
GB1462857A (en) Anodes for mercury-cathode electrolytic cells
US3986942A (en) Electrolytic process and apparatus
CN101338437A (en) Method for preparing graded multicomponent metal mixing oxide anode
YOKOI et al. Mechanism of the Electrodeposition and Dissolution of Copper in an Acid Copper Sulfate Bath IV. Acceleration Mechanism in the Presence of Cl-Ions
FI68090B (en) BELAGD METALLELEKTROD MED FOERBAETTRAT SPAERRSKIKT
US4470894A (en) Nickel electrodes for water electrolyzers
GB1531323A (en) Electrolytic diaphragm cells
GB1303865A (en)
Mandelcorn et al. The Effects of Halides on Copper Deposition in the Presence of Gelatin
Cox et al. Voltammetry in the absence of a solution phase with solids prepared by a sol-gel process as the electrolytes: facilitation of an electrocatalytic anodic process in the presence of ammonia
CA1249547A (en) Treatment of cathodes for use in electrolytic cell
JPS595674B2 (en) electrode structure
US4273624A (en) Thin platinum films on tin oxide substrates
US3837879A (en) Removing of worn coating from metal electrodes
GB1354897A (en) Electrodes for electrochemical processes
US4981573A (en) Process for the production of alkali dichromates and chromic acid employing an anode of valve metal activated by electrodepositing noble metals from melts
SU537125A1 (en) Electrode for electrolysis of an alkali aqueous solution and method for its manufacture
GB1358926A (en) Electrodes for electrochemical processes

Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee