GB1453911A - Tricyclic hydrocarbons and production thereof - Google Patents

Tricyclic hydrocarbons and production thereof

Info

Publication number
GB1453911A
GB1453911A GB5579274A GB5579274A GB1453911A GB 1453911 A GB1453911 A GB 1453911A GB 5579274 A GB5579274 A GB 5579274A GB 5579274 A GB5579274 A GB 5579274A GB 1453911 A GB1453911 A GB 1453911A
Authority
GB
United Kingdom
Prior art keywords
trimethylcyclododecatriene
trimethyltricyclo
dodec
ene
dec
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5579274A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takasago International Corp
Original Assignee
Takasago Perfumery Industry Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP744207A external-priority patent/JPS5530491B2/ja
Priority claimed from JP10264674A external-priority patent/JPS5132548A/en
Application filed by Takasago Perfumery Industry Co filed Critical Takasago Perfumery Industry Co
Publication of GB1453911A publication Critical patent/GB1453911A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • C11B9/0042—Essential oils; Perfumes compounds containing condensed hydrocarbon rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
    • C07C13/605—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings with a bridged ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/613—Unsaturated compounds containing a keto groups being part of a ring polycyclic
    • C07C49/617—Unsaturated compounds containing a keto groups being part of a ring polycyclic a keto group being part of a condensed ring system
    • C07C49/643—Unsaturated compounds containing a keto groups being part of a ring polycyclic a keto group being part of a condensed ring system having three rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/31—Rearrangement of carbon atoms in the hydrocarbon skeleton changing the number of rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C07D303/06—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms in which the oxirane rings are condensed with a carbocyclic ring system having three or more relevant rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1453911 1,2,6 - Trimethyltricyclo[5,3,2,0<SP>2,7</SP>]- dodec-5-ene TAKASAGO PERFUMERY CO Ltd 24 Dec 1974 [27 Dec 1973 6 Sept 1974] 55792/74 Heading C5E 1,2,6 - Trimethyltricyclo[5,3,2,0<SP>2,7</SP>]dodec - 5- ene having the general Formula (I) is claimed per se. The cis decalin form may be prepared from 1,5,9-trimethylcyclododecatriene- 1,5,9 and the trans decalin form from 1,5,10- trimethylcyclododecatriene-1,5,9 by intramolecular ring closure in the presence of an acid catalyst, such as H 2 SO 4 , H 3 PO 4 , polyphosphoric benzene sulphonic or p-toluene sulphonic acids, a strong acid ion-exchange resin, BF 3 , SnCl 4 , AlCl 3 or TiCl 4 . The reaction may be carried out at 0-100‹ C. in the presence of a solvent such as formic acid, acetic acid, methanol, ethanol, CH 2 Cl 2 , CHCl 3 , CCl 4 , n-hexane, benzene and/or toluene. The starting materials may be prepared by trimerizing isoprene in the presence of Ni naphthenate, triphenylphosphite and Et 3 Al.
GB5579274A 1973-12-27 1974-12-24 Tricyclic hydrocarbons and production thereof Expired GB1453911A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP744207A JPS5530491B2 (en) 1973-12-27 1973-12-27
JP10264674A JPS5132548A (en) 1974-09-06 1974-09-06 3 kanseitankasuisonoseizohoho

Publications (1)

Publication Number Publication Date
GB1453911A true GB1453911A (en) 1976-10-27

Family

ID=26337938

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5579274A Expired GB1453911A (en) 1973-12-27 1974-12-24 Tricyclic hydrocarbons and production thereof

Country Status (5)

Country Link
DE (1) DE2461524C3 (en)
FR (1) FR2272058B1 (en)
GB (1) GB1453911A (en)
IT (1) IT1026178B (en)
NL (1) NL163762C (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL269168A (en) *
NL259358A (en) * 1959-12-22
US3185739A (en) * 1960-05-19 1965-05-25 Phillips Petroleum Co Conversion of cyclotriene compounds

Also Published As

Publication number Publication date
DE2461524C3 (en) 1982-03-11
FR2272058B1 (en) 1978-12-22
DE2461524A1 (en) 1975-08-21
NL163762C (en) 1980-10-15
NL7416922A (en) 1975-07-01
NL163762B (en) 1980-05-16
DE2461524B2 (en) 1981-01-29
FR2272058A1 (en) 1975-12-19
IT1026178B (en) 1978-09-20

Similar Documents

Publication Publication Date Title
Wailes et al. Hydrido complexes of zirconium: III. Reactions with acetylenes to give alkenylzirconium derivatives
DE2452461C3 (en) Process for the ring-opening polymerization of imide-type norbornene derivatives
Lasne et al. New synthetic developments of the [4π+ 2π] cycloreversion
DE2731263A1 (en) PROCESS FOR THE PRODUCTION OF A POLYMER OR MIXED POLYMER FROM A NORBORN DERIVATIVE AND A CATALYST FOR IT
Leonard et al. Spectral Properties of Medium-and Large-ring Carbocyclic Compounds: α-Bromoketones, Enol Acetates and Unsaturated Ketones
Inanaga Samarium Diiodide-A Versatile Reagent in Organic Synthesis
Paquette et al. Unsaturated heterocyclic systems. LV. Cycloaddition reactions of derivatives of 1H-azepine
GB1375587A (en)
IE40961L (en) Making polybicyclo [2.2.1] hept-2-ene
GB1453911A (en) Tricyclic hydrocarbons and production thereof
Crich et al. Some studies on 6, 7-unsaturated carbonyl radical cyclizations
Haaima et al. Iodovinylidene lactone synthesis. Free radical cyclisation of iodoacetylenic esters
JPS54122263A (en) Preparation of 1,4-dihydro-9,10-dihydroxyanthracene
GB1340524A (en) Ring-opening polymerization process
Doyle Cycloaddition reactions. Thermal addition of dimethyl acetylenedicarboxylate to 1-methoxyindene
DE69608941D1 (en) Process for the production of polybutadiene with a high cis content
GB1327542A (en) Process for producing polycyclic alkylphenols
US2496390A (en) Cyclic ether peroxide catalysts in the polymerization of conjugated diolefins
Kristinsson et al. Photochemistry of phenyloxirans; indene oxide. A convenient synthesis of isochromene
Flores et al. Mass spectra of photoaddition products from methyl‐substituted maleic anhydrides and thiophen derivatives
Aso et al. Studies on the polymerization of bifunctional monomers. XVII. Cyclopolymerization of malealdehyde and the structure of the polymer
ES476490A1 (en) Manufacture of furan compound
SU394392A1 (en) METHOD OF GETTING. PAUL IFENIL FHOB
áO'Neill Metathesis polymerization of 7-oxa-2, 3-bismethoxycarbonylbicyclo [2.2. 1] hepta-2, 5-diene: synthesis of novel conjugated polyenes
Hienuki et al. Synthesis and properties of p-C8-bridged hydroquinones and p-benzoquinones

Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee