GB1451777A - Process for preparation of secondary aliphatic amines - Google Patents
Process for preparation of secondary aliphatic aminesInfo
- Publication number
- GB1451777A GB1451777A GB5289273A GB5289273A GB1451777A GB 1451777 A GB1451777 A GB 1451777A GB 5289273 A GB5289273 A GB 5289273A GB 5289273 A GB5289273 A GB 5289273A GB 1451777 A GB1451777 A GB 1451777A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogen
- reaction
- alcohol
- gas
- ammonia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1868—Stationary reactors having moving elements inside resulting in a loop-type movement
- B01J19/1881—Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00029—Batch processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
- B01J2219/00108—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
1451777 Secondary aliphatic amines HOECHST AG 14 Nov 1973 [14 Nov 1972] 52892/73 Heading C2C Secondary amines are made by reacting a C 7-24 aliphatic alcohol with ammonia in the presence of hydrogen and a hydrogenating- dehydrogenating catalyst at a temperature of 120-250‹ C. and a pressure of 0À5-6À0 atmospheres absolute, the ammonia and the hydrogen being passed through the alcohol at a combined gas rate of at least 50 litres per hour and per kilogram of alcohol and the water formed in the reaction being removed with the gas stream. The gas mixture may also include an inert gas (e.g. N 2 and/or CH 4 ). Reaction may be performed either by an "open" method or by a "closed" method in which the gases coming off from the alcohol are recycled. In the "closed" method, no outside source of hydrogen need be used, the hydrogen obtained by dehydrogenation of the reaction mixture sufficing. At the beginning of the reaction the gas flow may consist wholly or mainly of ammonia and at the end of the reaction the gas flow may consist wholly or mainly of hydrogen. Specified catalysts are cobalt and/or nickel with or without copper, and cobalt and chrome together with alkali metals or barium.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2255701A DE2255701C3 (en) | 1972-11-14 | 1972-11-14 | Process for the preparation of secondary aliphatic amines |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1451777A true GB1451777A (en) | 1976-10-06 |
Family
ID=5861667
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5289273A Expired GB1451777A (en) | 1972-11-14 | 1973-11-14 | Process for preparation of secondary aliphatic amines |
Country Status (22)
Country | Link |
---|---|
JP (1) | JPS5817739B2 (en) |
AR (1) | AR196568A1 (en) |
AT (1) | AT332363B (en) |
AU (1) | AU6242073A (en) |
BE (1) | BE807331A (en) |
BR (1) | BR7308900D0 (en) |
CA (1) | CA1000742A (en) |
CH (1) | CH590201A5 (en) |
DD (1) | DD108970A5 (en) |
DE (1) | DE2255701C3 (en) |
DK (1) | DK143333C (en) |
ES (1) | ES420361A1 (en) |
FI (1) | FI61684C (en) |
FR (1) | FR2206311B1 (en) |
GB (1) | GB1451777A (en) |
IT (1) | IT999342B (en) |
NL (1) | NL177109C (en) |
NO (1) | NO138284C (en) |
SE (1) | SE402761C (en) |
SU (1) | SU550975A3 (en) |
YU (1) | YU294473A (en) |
ZA (1) | ZA738685B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4207263A (en) * | 1976-10-09 | 1980-06-10 | Basf Aktiengesellschaft | Manufacture of secondary amines by alkylating ammonia with alcohols |
US4234727A (en) * | 1978-09-01 | 1980-11-18 | Basf Aktiengesellschaft | Preparation of amines |
EP1101526A2 (en) * | 1999-11-17 | 2001-05-23 | Praxair Technology, Inc. | Batch reactor with on-demand supply of reactive gas |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2645712C2 (en) * | 1976-10-09 | 1983-08-04 | Basf Ag, 6700 Ludwigshafen | Process for the preparation of secondary amines by reacting ammonia with primary or secondary mono- or polyhydric alcohols |
DE3246978A1 (en) * | 1982-12-18 | 1984-06-20 | Basf Ag, 6700 Ludwigshafen | METHOD FOR PRODUCING AMINES |
DE19935448B4 (en) * | 1999-07-28 | 2013-08-22 | Oxea Gmbh | Process for the preparation of secondary aliphatic amines from medium chain aldehydes |
JP6780664B2 (en) | 2017-12-05 | 2020-11-04 | 日本軽金属株式会社 | Aluminum alloy plate for battery lid for molding of integrated circular explosion-proof valve and its manufacturing method |
-
1972
- 1972-11-14 DE DE2255701A patent/DE2255701C3/en not_active Expired
-
1973
- 1973-11-08 ES ES420361A patent/ES420361A1/en not_active Expired
- 1973-11-09 CH CH1574173A patent/CH590201A5/xx not_active IP Right Cessation
- 1973-11-09 DD DD174560A patent/DD108970A5/xx unknown
- 1973-11-09 NL NLAANVRAGE7315381,A patent/NL177109C/en not_active IP Right Cessation
- 1973-11-12 AR AR250951A patent/AR196568A1/en active
- 1973-11-12 FI FI3477/73A patent/FI61684C/en active
- 1973-11-12 IT IT31209/73A patent/IT999342B/en active
- 1973-11-12 AT AT949073A patent/AT332363B/en not_active IP Right Cessation
- 1973-11-13 DK DK613073A patent/DK143333C/en not_active IP Right Cessation
- 1973-11-13 CA CA185,586A patent/CA1000742A/en not_active Expired
- 1973-11-13 ZA ZA738685A patent/ZA738685B/en unknown
- 1973-11-13 JP JP48126860A patent/JPS5817739B2/en not_active Expired
- 1973-11-13 BR BR8900/73A patent/BR7308900D0/en unknown
- 1973-11-13 AU AU62420/73A patent/AU6242073A/en not_active Expired
- 1973-11-13 SU SU1971536A patent/SU550975A3/en active
- 1973-11-13 SE SE7315345A patent/SE402761C/en unknown
- 1973-11-14 GB GB5289273A patent/GB1451777A/en not_active Expired
- 1973-11-14 FR FR7340416A patent/FR2206311B1/fr not_active Expired
- 1973-11-14 NO NO4376/73A patent/NO138284C/en unknown
- 1973-11-14 YU YU02944/73A patent/YU294473A/en unknown
- 1973-11-14 BE BE137759A patent/BE807331A/en not_active IP Right Cessation
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4207263A (en) * | 1976-10-09 | 1980-06-10 | Basf Aktiengesellschaft | Manufacture of secondary amines by alkylating ammonia with alcohols |
US4234727A (en) * | 1978-09-01 | 1980-11-18 | Basf Aktiengesellschaft | Preparation of amines |
EP1101526A2 (en) * | 1999-11-17 | 2001-05-23 | Praxair Technology, Inc. | Batch reactor with on-demand supply of reactive gas |
EP1101526A3 (en) * | 1999-11-17 | 2001-10-10 | Praxair Technology, Inc. | Batch reactor with on-demand supply of reactive gas |
Also Published As
Publication number | Publication date |
---|---|
JPS504007A (en) | 1975-01-16 |
DE2255701C3 (en) | 1981-06-19 |
FR2206311B1 (en) | 1980-02-15 |
NL7315381A (en) | 1974-05-16 |
NO138284B (en) | 1978-05-02 |
DK143333B (en) | 1981-08-10 |
AR196568A1 (en) | 1974-02-06 |
ES420361A1 (en) | 1976-04-16 |
IT999342B (en) | 1976-02-20 |
JPS5817739B2 (en) | 1983-04-09 |
CA1000742A (en) | 1976-11-30 |
NL177109C (en) | 1985-08-01 |
FR2206311A1 (en) | 1974-06-07 |
AU6242073A (en) | 1975-05-15 |
BR7308900D0 (en) | 1974-08-22 |
NO138284C (en) | 1978-08-09 |
SE402761B (en) | 1978-07-17 |
DK143333C (en) | 1981-12-14 |
DD108970A5 (en) | 1974-10-12 |
ATA949073A (en) | 1976-01-15 |
SU550975A3 (en) | 1977-03-15 |
SE402761C (en) | 1979-11-19 |
BE807331A (en) | 1974-05-14 |
DE2255701A1 (en) | 1974-05-30 |
YU294473A (en) | 1982-06-30 |
ZA738685B (en) | 1974-09-25 |
CH590201A5 (en) | 1977-07-29 |
DE2255701B2 (en) | 1976-05-13 |
FI61684B (en) | 1982-05-31 |
FI61684C (en) | 1982-09-10 |
NL177109B (en) | 1985-03-01 |
AT332363B (en) | 1976-09-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |
Effective date: 19931113 |