GB1438479A - Ketals of a-oximinocyclohexanones and processes for their pre paration - Google Patents
Ketals of a-oximinocyclohexanones and processes for their pre parationInfo
- Publication number
- GB1438479A GB1438479A GB1015975A GB1015975A GB1438479A GB 1438479 A GB1438479 A GB 1438479A GB 1015975 A GB1015975 A GB 1015975A GB 1015975 A GB1015975 A GB 1015975A GB 1438479 A GB1438479 A GB 1438479A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- compounds
- alkyl
- reacting
- inert solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 7
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 3
- 239000012442 inert solvent Substances 0.000 abstract 3
- -1 steroid oximes Chemical class 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000002243 cyclohexanonyl group Chemical class *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 abstract 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexyloxide Natural products O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 1
- 239000000539 dimer Substances 0.000 abstract 1
- 150000002009 diols Chemical class 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000003367 polycyclic group Chemical group 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07J—STEROIDS
- C07J41/00—Normal steroids containing one or more nitrogen atoms not belonging to a hetero ring
- C07J41/0005—Normal steroids containing one or more nitrogen atoms not belonging to a hetero ring the nitrogen atom being directly linked to the cyclopenta(a)hydro phenanthrene skeleton
- C07J41/0016—Oximes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/72—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 spiro-condensed with carbocyclic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Steroid Compounds (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
Abstract
1438479 Ketals; steroid oximes ALLIED CHEMICAL CORP 11 March 1975 [15 April 1974] 10159/75 Headings C2C and C2U The invention comprises compounds of the formula where R<SP>1</SP> is H, C 1 -C 4 alkyl or phenyl, or R<SP>1</SP> together with the 6-membered ring forms a polycyclic structure, X is a group of the formula where R<SP>2</SP> and R<SP>3</SP> are C 1 -C 10 alkyl, cyclohexyl or cyclohexyl substituted by C 1 -C 4 alkyl and R<SP>4</SP> and R<SP>5</SP> are H or C 1 -C 10 alkyl or R<SP>4</SP> and R<SP>5</SP> together with C<SP>a</SP> and C<SP>b</SP> form a cyclohexyl group. The invention further comprises dimers of the formula where X is a group of Formula II and R<SP>1</SP>, R<SP>2</SP> and R<SP>3</SP> are as defined above. Compounds of Formula IV may be prepared by reacting compounds of the formulµ and R<SP>3</SP>ONO in an inert solvent. Compounds of Formula I may be prepared by isomerizing compounds of Formula II or by reacting a compound of Formula V with a nitroxyl halide, a base and an alcohol of the formula R<SP>3</SP>OH in an inert solvent, or by reacting an R<SP>1</SP> substituted cyclohexanone with a nitroxyl halide, an acid and a diol of the formula in the presence of an inert solvent having a dielectric constant of at least 12 and subsequently neutralizing the resulting acid salt intermediate. Compounds prepared include 3,3-dimethoxy- 2-oximocholestane.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US46083674A | 1974-04-15 | 1974-04-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1438479A true GB1438479A (en) | 1976-06-09 |
Family
ID=23830265
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1015975A Expired GB1438479A (en) | 1974-04-15 | 1975-03-11 | Ketals of a-oximinocyclohexanones and processes for their pre paration |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPS5111737A (en) |
DE (1) | DE2515238A1 (en) |
FR (1) | FR2267322B3 (en) |
GB (1) | GB1438479A (en) |
IT (1) | IT1027472B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112638861A (en) * | 2018-12-19 | 2021-04-09 | 弗门尼舍有限公司 | Process for preparing cis-alpha, beta-substituted cyclopentanones |
-
1975
- 1975-02-06 IT IT6730275A patent/IT1027472B/en active
- 1975-03-11 GB GB1015975A patent/GB1438479A/en not_active Expired
- 1975-03-26 JP JP3566375A patent/JPS5111737A/en active Pending
- 1975-04-08 FR FR7510924A patent/FR2267322B3/fr not_active Expired
- 1975-04-08 DE DE19752515238 patent/DE2515238A1/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112638861A (en) * | 2018-12-19 | 2021-04-09 | 弗门尼舍有限公司 | Process for preparing cis-alpha, beta-substituted cyclopentanones |
Also Published As
Publication number | Publication date |
---|---|
FR2267322B3 (en) | 1977-12-16 |
DE2515238A1 (en) | 1975-10-30 |
FR2267322A1 (en) | 1975-11-07 |
JPS5111737A (en) | 1976-01-30 |
IT1027472B (en) | 1978-11-20 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |