GB1430072A - Polymerisation process - Google Patents
Polymerisation processInfo
- Publication number
- GB1430072A GB1430072A GB3280972A GB3280972A GB1430072A GB 1430072 A GB1430072 A GB 1430072A GB 3280972 A GB3280972 A GB 3280972A GB 3280972 A GB3280972 A GB 3280972A GB 1430072 A GB1430072 A GB 1430072A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylene
- catalyst
- rate
- constant
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 abstract 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 5
- 239000005977 Ethylene Substances 0.000 abstract 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 150000002430 hydrocarbons Chemical group 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Polymerisation Methods In General (AREA)
Abstract
1430072 Continuous polymerization of ethylene IMPERIAL CHEMICAL INDUSTRIES Ltd 4 July 1973 [13 July 1972] 32809/72 Addition to 1314828 Heading C3P Ethylene is polymerized continuously by contacting a catalyst with a mixture of hydrogen and ethylene in a reaction vessel, the ratio of ethylene to hydrogen in the vessel being kept constant at a value between 1 : 10 and 10 : 1, the total pressure being not greater than 40 kg./cm.<SP>2</SP>, the catalyst being introduced at such a rate as to keep the rate of polymerization constant, and the catalyst being the product of reacting particulate alumina or silica which has hydroxyl groups on the surface but is free of adsorbed water with a compound of formula MR m , where M is a Group IVa metal, vanadium or chromium, m is the valency of M and R is a hydrocarbon or substituted hydrocarbon group. Conveniently the ethylene may be introduced at a constant rate and the catalyst at such a rate as to keep the total pressure constant, continuously or in discrete portions. The melt flow index of the product may be selected by varying the proportion of hydrogen and/or the polymerization rate. The exemplified catalyst is zirconium tetrabenzyl on alumina; other suitable catalysts are as described in Specification 1,314,828.
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3280972A GB1430072A (en) | 1972-07-13 | 1972-07-13 | Polymerisation process |
FR7325653A FR2193039B2 (en) | 1972-07-13 | 1973-07-12 | |
BE133425A BE802280A (en) | 1972-07-13 | 1973-07-12 | POLYMERIZATION PROCESS |
DE19732335536 DE2335536A1 (en) | 1972-07-13 | 1973-07-12 | PROCESS FOR CONTINUOUS POLYMERIZATION OF AETHYLENE |
DK386673AA DK141101B (en) | 1972-07-13 | 1973-07-12 | Process for Continuous Polymerization of Ethylene. |
NL7309727A NL7309727A (en) | 1972-07-13 | 1973-07-12 | |
AU58056/73A AU467696B2 (en) | 1972-07-13 | 1973-07-13 | Polymerisation process |
LU68012A LU68012A1 (en) | 1972-07-13 | 1973-07-13 | |
ZA00734749A ZA734749B (en) | 1972-07-13 | 1973-07-13 | Polymerisation process |
JP48078549A JPS4953272A (en) | 1972-07-13 | 1973-07-13 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3280972A GB1430072A (en) | 1972-07-13 | 1972-07-13 | Polymerisation process |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1430072A true GB1430072A (en) | 1976-03-31 |
Family
ID=10344319
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3280972A Expired GB1430072A (en) | 1972-07-13 | 1972-07-13 | Polymerisation process |
Country Status (10)
Country | Link |
---|---|
JP (1) | JPS4953272A (en) |
AU (1) | AU467696B2 (en) |
BE (1) | BE802280A (en) |
DE (1) | DE2335536A1 (en) |
DK (1) | DK141101B (en) |
FR (1) | FR2193039B2 (en) |
GB (1) | GB1430072A (en) |
LU (1) | LU68012A1 (en) |
NL (1) | NL7309727A (en) |
ZA (1) | ZA734749B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3950269A (en) * | 1974-05-20 | 1976-04-13 | E. I. Du Pont De Nemours & Co. | Olefin polymerization catalyst system and process for polymerization of olefins |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE559774A (en) * | 1956-08-03 | |||
FR2058003A5 (en) * | 1969-08-13 | 1971-05-21 | Ici Ltd | Transitionmetal polymerization catalysts - for olefinic monomers |
-
1972
- 1972-07-13 GB GB3280972A patent/GB1430072A/en not_active Expired
-
1973
- 1973-07-12 DK DK386673AA patent/DK141101B/en unknown
- 1973-07-12 FR FR7325653A patent/FR2193039B2/fr not_active Expired
- 1973-07-12 NL NL7309727A patent/NL7309727A/xx not_active Application Discontinuation
- 1973-07-12 DE DE19732335536 patent/DE2335536A1/en active Pending
- 1973-07-12 BE BE133425A patent/BE802280A/en unknown
- 1973-07-13 LU LU68012A patent/LU68012A1/xx unknown
- 1973-07-13 JP JP48078549A patent/JPS4953272A/ja active Pending
- 1973-07-13 AU AU58056/73A patent/AU467696B2/en not_active Expired
- 1973-07-13 ZA ZA00734749A patent/ZA734749B/en unknown
Also Published As
Publication number | Publication date |
---|---|
DK141101C (en) | 1980-07-14 |
JPS4953272A (en) | 1974-05-23 |
BE802280A (en) | 1974-01-14 |
DK141101B (en) | 1980-01-14 |
LU68012A1 (en) | 1973-09-26 |
NL7309727A (en) | 1974-01-15 |
FR2193039A2 (en) | 1974-02-15 |
ZA734749B (en) | 1975-02-26 |
FR2193039B2 (en) | 1977-05-13 |
AU467696B2 (en) | 1975-12-11 |
AU5805673A (en) | 1975-01-16 |
DE2335536A1 (en) | 1974-04-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |