GB1419383A - Catalyst for electrophilic processes and method for preparing same - Google Patents

Catalyst for electrophilic processes and method for preparing same

Info

Publication number
GB1419383A
GB1419383A GB5192472A GB5192472A GB1419383A GB 1419383 A GB1419383 A GB 1419383A GB 5192472 A GB5192472 A GB 5192472A GB 5192472 A GB5192472 A GB 5192472A GB 1419383 A GB1419383 A GB 1419383A
Authority
GB
United Kingdom
Prior art keywords
alx
solution
solution containing
alcl
carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5192472A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
OTHERS
Original Assignee
OTHERS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by OTHERS filed Critical OTHERS
Priority to GB5192472A priority Critical patent/GB1419383A/en
Publication of GB1419383A publication Critical patent/GB1419383A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/861—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1419383 Alkyl aluminium halide complexes P G PAUTOV N B ARKHIPOV V E DOBROVINSKY V A NABILKINA E G TIMOFEEV Y N PROKOFIEV E G LAZARIANTS N V SCHERBAKOVA V D PETROVA A G TSVETKOVA J V LEBEDEV K S MINSKER N M RODIONOVA V M SOBOLEV G A STEPANOV G V EMELYANOVA A V VINOGRADOVA K Y KRAPIVINA E V KOLOSOVA L N VLADYKIN L I SLETOVA A P ORLOVA T N YATSYSHINA and V P BUGROV 10 Nov 1972 51924/72 Heading C2J [Also in Divisions B1 C3 and C5] Catalysts consisting of a solution containing R n AlX 3-n .ZH 2 and optionally R n AlX 3-n wherein R is alkyl, X is a halogen atom, Z is an oxygen or sulphur atom and n is 1 or 1À5 is prepared by forming a solution containing 0À2-100 g/l. of R n AlX 3-n in an anhydrous alkane, chloroalkane, saturated alicyclic hydrocarbon and/or aromatic hydrocarbon; adding to the solution H 2 Z in admixture with or in combination with a carrier which is insoluble in the solvent; the amount of H 2 Z added being such that the molar ratio of R n AlX 3-n : H 2 Z is 1 : 0À5 to 1 : 1À5 and the temperature being maintained at from - 100‹ to + 70‹ C.; and separating the insoluble carrier from the solution to give the catalyst solution. Examples describe the preparation of solutions containing C 2 H 5 AlCl 2 .OH 2 in benzene, or benzene and methyl chloride, and C 2 H 5 AlBr 2 .OH 2 in n-pentane and each containing excess organoaluminium halide using a hydrated metal sulphate as the carrier-water combination. In other examples a solution containing i-C 4 H 8 AlCl 2 .OH 2 and uncomplexed organoaluminium halide in cyclohexane is made by introducing the water through an atomizer and a solution containing (C 2 H 5 ) 1À5 AlCl 1À5 .OH 2 in isopentane is made using humidified nitrogen.
GB5192472A 1972-11-10 1972-11-10 Catalyst for electrophilic processes and method for preparing same Expired GB1419383A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB5192472A GB1419383A (en) 1972-11-10 1972-11-10 Catalyst for electrophilic processes and method for preparing same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5192472A GB1419383A (en) 1972-11-10 1972-11-10 Catalyst for electrophilic processes and method for preparing same

Publications (1)

Publication Number Publication Date
GB1419383A true GB1419383A (en) 1975-12-31

Family

ID=10461950

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5192472A Expired GB1419383A (en) 1972-11-10 1972-11-10 Catalyst for electrophilic processes and method for preparing same

Country Status (1)

Country Link
GB (1) GB1419383A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017140602A1 (en) * 2016-02-16 2017-08-24 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
EP3444283A1 (en) * 2017-08-17 2019-02-20 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017140602A1 (en) * 2016-02-16 2017-08-24 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
CN108602913A (en) * 2016-02-16 2018-09-28 巴斯夫欧洲公司 The method for preparing highly reactive isobutylene homo or copolymer
JP2019509374A (en) * 2016-02-16 2019-04-04 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Process for producing highly reactive isobutene homopolymers or copolymers
US10975180B2 (en) * 2016-02-16 2021-04-13 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
CN108602913B (en) * 2016-02-16 2022-07-08 巴斯夫欧洲公司 Method for producing highly reactive isobutene homo-or copolymers
EP3444283A1 (en) * 2017-08-17 2019-02-20 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
WO2019034477A1 (en) * 2017-08-17 2019-02-21 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
US11359034B2 (en) 2017-08-17 2022-06-14 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers

Similar Documents

Publication Publication Date Title
KR880011218A (en) Process for producing propylene-α-olefin block copolymer
ATE21253T1 (en) PROCESS FOR THE PREPARATION OF A CATALYST FOR THE POLYMERIZATION OF OLEFINS.
GB1086021A (en) Process for the production of aromatic polyketones
ATE73465T1 (en) CATALYST COMPOSITION FOR THE PRODUCTION OF ALPHA OLEFIN POLYMERS WITH RELATIVELY NARROW MOLECULAR WEIGHT DISTRIBUTION.
GB1513063A (en) Preparation of chlorinated alkylbenzenes
GB1419383A (en) Catalyst for electrophilic processes and method for preparing same
ES401491A1 (en) Catalysts for the polymerization of olefins
GB1287819A (en)
GB1478587A (en) Preparation of alpha-6-deoxy-5-hydroxytetracycline
ES8200705A1 (en) A process for producing a polymerisation catalyst and use of same for olefin polymerisation.
GB1261474A (en) Phenylacetic acid
GB1194068A (en) Process for Producing Organometallic Chelated Cobalt Complexes
GB1450926A (en) Chromium tris-diorgano-orthophosphates and their production and use
GB1508047A (en) Aluminium hydride oligomer derivatives and process for the preparation thereof
GB1381432A (en) Method for inhibiting the corrosion of metals
GB1472541A (en) Catalyst composition and use thereof in polymerisation of halide monomers
GB1251736A (en)
GB1282815A (en) Process for producing 5-(1'-alkenyl)-2-norbornene
GB1455406A (en) Aluminium compounds
GB1265631A (en)
GB1039565A (en) Improvements in or relating to the catalytic polymerization of olefins
GB1475825A (en) Process for the production of n,n-diallyl-dichloroacetamide
IE42754L (en) N,n'-substituted naphthalenacetamidines
GB1362959A (en) Phosphorus-containing unsaturated carboxylic acid derivatives
GB1430624A (en) 3-alkyl-2- 6-cafboxyhexyl cyclopentaanones and esters and salts thereof

Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee