GB1415194A - Preparation of copolymers containing silicon - Google Patents

Preparation of copolymers containing silicon

Info

Publication number
GB1415194A
GB1415194A GB1372972A GB1372972A GB1415194A GB 1415194 A GB1415194 A GB 1415194A GB 1372972 A GB1372972 A GB 1372972A GB 1372972 A GB1372972 A GB 1372972A GB 1415194 A GB1415194 A GB 1415194A
Authority
GB
United Kingdom
Prior art keywords
ethylene
radical
copolymerized
march
unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1372972A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Silicones UK Ltd
Original Assignee
Dow Corning Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Corning Ltd filed Critical Dow Corning Ltd
Priority to GB1372972A priority Critical patent/GB1415194A/en
Publication of GB1415194A publication Critical patent/GB1415194A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C08F230/085—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes

Abstract

1415194 Ethylene-unsaturated silane copolymerization process DOW CORNING Ltd 15 March 1973 [23 March 1972] 13729/72 Heading C3P Ethylene is copolymerized with a silane of formula RR<SP>1</SP> n Si(R<SP>11</SP>) 3-n in which R is a monovalent, terminally ethylenically unsaturated radical, R<SP>1</SP> is a saturated hydrocarbon radical, R<SP>11</SP> is an alkoxy or alkoxyalkoxy radical and n is 0 or 1, and optionally with other unsaturated monomer(s), in the presence of a Zeigler catalyst, i.e. a compound of a Group IVa, Va or VIa metal and an organometallic or hydride compound of a Group Ia, IIa, IIb or IIIb metal. The copolymers may be cross-linked by exposure to water in the presence of a siloxane condensation catalyst such as organic tin compounds. In the examples, ethylene is copolymerized with allyl triethoxysilane, vinyl trimethoxysilane, gamma-triethoxy silyl propyl methacrylate, 1-(trimethoxy silyl)-5-hexene, or allyl triethoxysilane and propylene in the presence of VCl 4 , T : Cl 4 or chromyl chloride together with (C 2 H 5 ) 2 AlCl, and the products crosslinked by immersion in a boiling emulsion of dibutyl tin dilaurate.
GB1372972A 1972-03-23 1972-03-23 Preparation of copolymers containing silicon Expired GB1415194A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1372972A GB1415194A (en) 1972-03-23 1972-03-23 Preparation of copolymers containing silicon

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1372972A GB1415194A (en) 1972-03-23 1972-03-23 Preparation of copolymers containing silicon

Publications (1)

Publication Number Publication Date
GB1415194A true GB1415194A (en) 1975-11-26

Family

ID=10028317

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1372972A Expired GB1415194A (en) 1972-03-23 1972-03-23 Preparation of copolymers containing silicon

Country Status (1)

Country Link
GB (1) GB1415194A (en)

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2926830A1 (en) * 1978-07-05 1980-01-17 Mitsubishi Petrochemical Co CROSSLINKABLE POLYETHYLENE PLASTICS
JPS559612A (en) * 1978-07-05 1980-01-23 Mitsubishi Petrochem Co Ltd Cross-linked polyethylene resin film
DE2944664A1 (en) * 1978-11-13 1980-05-22 Mitsubishi Petrochemical Co PRODUCTION OF ELECTRIC LADDERS SHEETED WITH A CROSSLINKED POLYETHYLENE
EP0019290A2 (en) * 1979-05-17 1980-11-26 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Curable composition
JPS568447A (en) * 1979-07-03 1981-01-28 Mitsubishi Petrochem Co Ltd Crosslinkable ethylene copolymer composition
JPS5611246A (en) * 1979-07-11 1981-02-04 Mitsubishi Petrochemical Co Resinnmetal complex
JPS5648944A (en) * 1979-09-17 1981-05-02 Mitsubishi Petrochemical Co Bridged polyethylene hollow molding vessel
JPS5688446A (en) * 1979-12-20 1981-07-17 Mitsubishi Petrochem Co Ltd Bridged polyethylene resin pipe
JPS5695940A (en) * 1979-12-28 1981-08-03 Mitsubishi Petrochem Co Ltd Ethylene polymer composition
EP0050248A2 (en) * 1980-10-03 1982-04-28 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Vinyl-type resin composition
US4413066A (en) 1978-07-05 1983-11-01 Mitsubishi Petrochemical Company, Ltd. Crosslinkable polyethylene resin compositions
WO1984000969A1 (en) * 1982-08-27 1984-03-15 Contact Lens Mfg Ltd Prostheses contact lenses and polymers therefor
EP0215402A1 (en) * 1985-09-09 1987-03-25 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Curable resin and process for preparing the same
WO1988008856A1 (en) * 1987-05-08 1988-11-17 Aristech Chemical Corporation Incorporation of functional groups in polymers
GB2205846A (en) * 1987-06-13 1988-12-21 Bp Chem Int Ltd Crosslinkable polymer
EP0321258A2 (en) * 1987-12-16 1989-06-21 MITSUI TOATSU CHEMICALS, Inc. Use of a copolymer alpha olefin alkenylsilane for bonding two layers or for coating an article
EP0430112A2 (en) * 1989-11-28 1991-06-05 MITSUI TOATSU CHEMICALS, Inc. Syndiotactic alpha-olefin-alkenylsilane copolymer and method for preparing same
US5162456A (en) * 1985-09-09 1992-11-10 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Curable resin and process for preparing the same
US5276108A (en) * 1985-09-09 1994-01-04 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Curable resin and process for preparing the same
EP0585967A1 (en) * 1987-12-16 1994-03-09 MITSUI TOATSU CHEMICALS, Inc. A process for preparing a silicon containing polymer
US5302669A (en) * 1985-09-09 1994-04-12 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Curable resin and process for preparing the same
US5686546A (en) * 1994-11-15 1997-11-11 At Plastics, Inc. Cross-linkable polymer composition containing a carboxylic acid precursor as a catalyst
WO2012099882A2 (en) * 2011-01-19 2012-07-26 Dow Corning Corporation Method for producing silyl-functionalized polyolefins and silyl-functionalized polyolefins with silyl monomer incorporation

Cited By (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2926830A1 (en) * 1978-07-05 1980-01-17 Mitsubishi Petrochemical Co CROSSLINKABLE POLYETHYLENE PLASTICS
JPS559611A (en) * 1978-07-05 1980-01-23 Mitsubishi Petrochem Co Ltd Cross-linkable polyethylene resin composition
JPS559612A (en) * 1978-07-05 1980-01-23 Mitsubishi Petrochem Co Ltd Cross-linked polyethylene resin film
FR2430432A1 (en) * 1978-07-05 1980-02-01 Mitsubishi Petrochemical Co CROSSLINKABLE POLYETHYLENE RESIN COMPOSITIONS
US4413066A (en) 1978-07-05 1983-11-01 Mitsubishi Petrochemical Company, Ltd. Crosslinkable polyethylene resin compositions
JPS6223778B2 (en) * 1978-07-05 1987-05-25 Mitsubishi Petrochemical Co
JPS6223777B2 (en) * 1978-07-05 1987-05-25 Mitsubishi Petrochemical Co
US4297310A (en) 1978-11-13 1981-10-27 Mitsubishi Petrochemical Co., Ltd. Process for producing electric conductors coated with crosslinked polyethylene resin
DE2944664A1 (en) * 1978-11-13 1980-05-22 Mitsubishi Petrochemical Co PRODUCTION OF ELECTRIC LADDERS SHEETED WITH A CROSSLINKED POLYETHYLENE
EP0019290A3 (en) * 1979-05-17 1981-01-07 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Curable composition
EP0019290A2 (en) * 1979-05-17 1980-11-26 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Curable composition
JPS568447A (en) * 1979-07-03 1981-01-28 Mitsubishi Petrochem Co Ltd Crosslinkable ethylene copolymer composition
JPS6223779B2 (en) * 1979-07-03 1987-05-25 Mitsubishi Petrochemical Co
JPS5611246A (en) * 1979-07-11 1981-02-04 Mitsubishi Petrochemical Co Resinnmetal complex
JPS6225098B2 (en) * 1979-07-11 1987-06-01 Mitsubishi Petrochemical Co
JPS5648944A (en) * 1979-09-17 1981-05-02 Mitsubishi Petrochemical Co Bridged polyethylene hollow molding vessel
JPS6226331B2 (en) * 1979-09-17 1987-06-08 Mitsubishi Petrochemical Co
JPS5688446A (en) * 1979-12-20 1981-07-17 Mitsubishi Petrochem Co Ltd Bridged polyethylene resin pipe
JPS6223977B2 (en) * 1979-12-20 1987-05-26 Mitsubishi Petrochemical Co
JPS5695940A (en) * 1979-12-28 1981-08-03 Mitsubishi Petrochem Co Ltd Ethylene polymer composition
JPS6223978B2 (en) * 1979-12-28 1987-05-26 Mitsubishi Petrochemical Co
EP0050248A3 (en) * 1980-10-03 1983-02-16 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Vinyl-type resin composition
EP0050248A2 (en) * 1980-10-03 1982-04-28 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Vinyl-type resin composition
WO1984000969A1 (en) * 1982-08-27 1984-03-15 Contact Lens Mfg Ltd Prostheses contact lenses and polymers therefor
US5459205A (en) * 1985-09-09 1995-10-17 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Curable resin and process for preparing the same
US5302669A (en) * 1985-09-09 1994-04-12 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Curable resin and process for preparing the same
EP0215402A1 (en) * 1985-09-09 1987-03-25 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Curable resin and process for preparing the same
US5162456A (en) * 1985-09-09 1992-11-10 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Curable resin and process for preparing the same
US5276108A (en) * 1985-09-09 1994-01-04 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Curable resin and process for preparing the same
WO1988008856A1 (en) * 1987-05-08 1988-11-17 Aristech Chemical Corporation Incorporation of functional groups in polymers
GB2205846A (en) * 1987-06-13 1988-12-21 Bp Chem Int Ltd Crosslinkable polymer
EP0321258A2 (en) * 1987-12-16 1989-06-21 MITSUI TOATSU CHEMICALS, Inc. Use of a copolymer alpha olefin alkenylsilane for bonding two layers or for coating an article
EP0321258A3 (en) * 1987-12-16 1991-01-23 MITSUI TOATSU CHEMICALS, Inc. Use of a copolymer alpha olefin alkenylsilane for bonding two layers or for coating an article
EP0585967A1 (en) * 1987-12-16 1994-03-09 MITSUI TOATSU CHEMICALS, Inc. A process for preparing a silicon containing polymer
EP0430112A2 (en) * 1989-11-28 1991-06-05 MITSUI TOATSU CHEMICALS, Inc. Syndiotactic alpha-olefin-alkenylsilane copolymer and method for preparing same
US5334684A (en) * 1989-11-28 1994-08-02 Mitsui Toatsu Chemicals, Incorporated α-olefin-alkenylsilane copolymer and method for preparing same
EP0430112A3 (en) * 1989-11-28 1992-01-08 Mitsui Toatsu Chemicals, Incorporated Alpha-olefin-alkenylsilane copolymer and method for preparing same
US5686546A (en) * 1994-11-15 1997-11-11 At Plastics, Inc. Cross-linkable polymer composition containing a carboxylic acid precursor as a catalyst
WO2012099882A2 (en) * 2011-01-19 2012-07-26 Dow Corning Corporation Method for producing silyl-functionalized polyolefins and silyl-functionalized polyolefins with silyl monomer incorporation
WO2012099882A3 (en) * 2011-01-19 2012-09-13 Dow Corning Corporation Method for producing silyl-functionalized polyolefins and silyl-functionalized polyolefins with silyl monomer incorporation
CN103443143A (en) * 2011-01-19 2013-12-11 道康宁公司 Method for producing silyl-unctionalized polyolefins and silyl-<wbr/>functionalized polyolefins with silyl monomer incorporation
US9388265B2 (en) 2011-01-19 2016-07-12 Dow Corning Corporation Method for producing silyl-functionalized polyolefins and silyl-functionalized polyolefins with silyl monomer incorporation
CN103443143B (en) * 2011-01-19 2017-08-04 道康宁公司 The method for producing silyl-functional polyolefin and combining the silyl-functional polyolefin of silyl group monomer

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee