GB1402845A - Age resisters and age resistant polymeric compositions - Google Patents

Age resisters and age resistant polymeric compositions

Info

Publication number
GB1402845A
GB1402845A GB967775A GB967775A GB1402845A GB 1402845 A GB1402845 A GB 1402845A GB 967775 A GB967775 A GB 967775A GB 967775 A GB967775 A GB 967775A GB 1402845 A GB1402845 A GB 1402845A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
radicals
hydrogen
polymers
alkyl radicals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB967775A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodyear Tire and Rubber Co
Original Assignee
Goodyear Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/153,449 external-priority patent/US3953411A/en
Priority claimed from US00153446A external-priority patent/US3817916A/en
Application filed by Goodyear Tire and Rubber Co filed Critical Goodyear Tire and Rubber Co
Publication of GB1402845A publication Critical patent/GB1402845A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/16—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/10—Esters
    • C08F22/12—Esters of phenols or saturated alcohols
    • C08F22/22—Esters containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups

Abstract

1402845 Age resistant polymers and polymer compositions GOODYEAR TIRE & RUBBER CO 15 June 1972 [15 June 1971] 9677/75 Divided out of 1402720 Heading C3P [Also in Division C2] New compounds of the general formula below are used to give age resistant properties to polymers, either by addition to pre-formed polymers or by using them as one of the monomers in a polymerization recipe containing at least 40 wt. per cent (based on total monomers) of a diene. The compounds are of formula wherein R is selected from alkyl radicals having 1 to 12 carbon atoms, cycloalkyl radicals having 5 to 12 carbon atoms, aralkyl radicals having 7 to 24 carbon atoms and aryl radicals having 6 to 24 carbon atoms, wherein R<SP>1</SP> and R<SP>2</SP> are selected from hydrogen and alkyl groups having 1 to 4 carbon atoms and wherein R<SP>3</SP> is selected from hydrogen, alkyl radicals having 1 to 12 carbon atoms, cycloalkyl radicals having from 5 to 12 carbon atoms, and aralkyl radicals having 7 to 24 carbon atoms, wherein R<SP>4</SP>, R<SP>5</SP>, R<SP>6</SP> , R<SP>7</SP> and R<SP>8</SP> are selected from hydrogen and alkyl radicals having from 1 to 4 carbon atoms, wherein R<SP>9</SP> is selected from hydrogen, alkyl radicals having from 1 to 4 carbon atoms, carboxymethyl radical and carbalkoxymethyl radicals, and wherein R<SP>10</SP> is selected from hydrogen, alkyl radicals having from 1 to 4 carbon atoms, phenyl and substituted phenyl radicals, alkyl radicals having 1 to 4 carbon atoms, alkoxy radicals having 1 or 2 carbon atoms, carboxyl radical and carbalkoxy radicals. Compositions.-Examples illustrate the stabilization of SBR and nitrile rubber with 3-N-(41- anilinophenyl)-amino-2-hydroxypropyl methacrylate (the reaction product of glycidyl methacrylate and p-aminodiphenylamine). Polymers.-Examples describe the production, by conventional emulsion polymerization techniques, of terpolymers of (i) butadiene as major component, (ii) styrene or acrylonitrile, and (iii) the reaction product of glycidyl methacrylate with either p-aminodiphenylamine or N-phenyl- N<SP>1</SP>-1,3-dimethylbutyl-p-phenylene diamine.
GB967775A 1971-06-15 1972-06-15 Age resisters and age resistant polymeric compositions Expired GB1402845A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/153,449 US3953411A (en) 1971-06-15 1971-06-15 Age resistant polymers of 4-(arylamino)aryl esters of α,β unsaturated carboxylic acids
US00153446A US3817916A (en) 1971-06-15 1971-06-15 Oxidation resistant polymeric compositions prepared from 3 - n-(4' - anilinophenyl)amino - 2-hydroxypropyl methacrylate

Publications (1)

Publication Number Publication Date
GB1402845A true GB1402845A (en) 1975-08-13

Family

ID=26850557

Family Applications (1)

Application Number Title Priority Date Filing Date
GB967775A Expired GB1402845A (en) 1971-06-15 1972-06-15 Age resisters and age resistant polymeric compositions

Country Status (9)

Country Link
JP (1) JPS5515488B2 (en)
AR (1) AR195670A1 (en)
AU (1) AU461115B2 (en)
BE (1) BE784694A (en)
CA (1) CA993147A (en)
DE (1) DE2225279A1 (en)
FR (1) FR2142370A5 (en)
GB (1) GB1402845A (en)
NL (1) NL173962C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113956538A (en) * 2020-07-20 2022-01-21 北京化工大学 Novel anti-aging agent and preparation method and application thereof

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5127278B2 (en) * 1972-06-30 1976-08-11
US4804028A (en) * 1986-03-05 1989-02-14 The Goodyear Tire & Rubber Company Non-staining vulcanized elastomeric composition and tires having sidewalls comprising said composition
US5049625A (en) * 1990-03-08 1991-09-17 The Goodyear Tire & Rubber Company Polymeric diphenyldiamines
CN109415454A (en) * 2016-07-06 2019-03-01 思美定株式会社 Solidification compound and product

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1457152A (en) * 1964-12-08 1966-07-08 Bayer Ag Process for the preparation of phenols containing unsaturated groups
GB1307409A (en) * 1969-06-23 1973-02-21 Goodyear Tire & Rubber Age resisters and age resistant polymeric compositions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113956538A (en) * 2020-07-20 2022-01-21 北京化工大学 Novel anti-aging agent and preparation method and application thereof

Also Published As

Publication number Publication date
JPS5515488B2 (en) 1980-04-24
AU4213472A (en) 1973-11-15
DE2225279C2 (en) 1987-12-23
BE784694A (en) 1972-10-02
NL7208202A (en) 1972-12-19
CA993147A (en) 1976-07-13
NL173962C (en) 1984-04-02
FR2142370A5 (en) 1973-01-26
AU461115B2 (en) 1975-05-15
AR195670A1 (en) 1973-10-31
DE2225279A1 (en) 1972-12-21
NL173962B (en) 1983-11-01
JPS4815988A (en) 1973-02-28

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years