GB1390408A - Cyclic process for the production of hydrogen peroxide - Google Patents

Cyclic process for the production of hydrogen peroxide

Info

Publication number
GB1390408A
GB1390408A GB3165472A GB3165472A GB1390408A GB 1390408 A GB1390408 A GB 1390408A GB 3165472 A GB3165472 A GB 3165472A GB 3165472 A GB3165472 A GB 3165472A GB 1390408 A GB1390408 A GB 1390408A
Authority
GB
United Kingdom
Prior art keywords
temp
mixture
hydrogen peroxide
july
tert
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3165472A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay SA
Original Assignee
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay SA filed Critical Solvay SA
Publication of GB1390408A publication Critical patent/GB1390408A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/022—Preparation from organic compounds
    • C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1390408 Hydrogen peroxide by anthraquinone process SOLWAY & CIE 6 July 1972 [8 July 1971] 31654/72 Heading C1A A mixture of 2-tert. amyl and 2-sec. isoamyltetrahydroanthraquinones are used as intermediates in the anthraquinone process for producing H 2 O 2 . The mixture preferably contains 30-55% by wt. of the 2-tert. compound and 70-45% of the 2-sec. compound. The solvent may be a mixture of (a) C 6 -C 11 petroleum fractions, naphthalene, chlorinated hydrocarbons, alkyl benzenes or anisole with (b) aliphatic alcohols having at least 6 carbon atoms, e.g. heptanol, methylcyclohexanol, octan-2-ol, diisobutyl carbinol, or aliphatic esters of carboxylic or phosphoric acids. The quinone hydrogenation may be catalysed by Raney Ni, or Pd on hydroxyapatite, Re, Rh, Pt or Pd at a temp. of 45-70‹.C. to 90% conversion. The quinol oxidation may be carried out in air at a pressure of 3-5 kg.(cm.<SP>2</SP> in a co- or counter-current manner in a packed column at a temp. of 20-50‹ C. Anthraquinone by-products may be removed, prior to recycle after H 2 O 2 removal, by treatment with alkali metal or alkaline earth metalhydroxides, or alkaline alumina or aluminosilicates at temp. of 20-150‹ C.
GB3165472A 1971-07-08 1972-07-06 Cyclic process for the production of hydrogen peroxide Expired GB1390408A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE769675A BE769675A (en) 1971-07-08 1971-07-08 CYCLICAL PROCESS FOR THE MANUFACTURE OF HYDROGEN PEROXIDE.

Publications (1)

Publication Number Publication Date
GB1390408A true GB1390408A (en) 1975-04-09

Family

ID=3858377

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3165472A Expired GB1390408A (en) 1971-07-08 1972-07-06 Cyclic process for the production of hydrogen peroxide

Country Status (3)

Country Link
BE (1) BE769675A (en)
FR (1) FR2144725B1 (en)
GB (1) GB1390408A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4514376A (en) * 1984-04-19 1985-04-30 Fmc Corporation Pregeneration of tetrahydroanthraquinones in a make-up solution to be added to a hydrogen peroxide working solution
US4539196A (en) * 1984-04-19 1985-09-03 Fmc Corporation Process for hydrogenating an alkylated anthraquinone
US5399333A (en) * 1992-12-25 1995-03-21 Mitsubishi Chemical Gas Co., Ltd. Process for producing hydrogen peroxide
WO2023102759A1 (en) * 2021-12-08 2023-06-15 Solvay Sa A composition comprising 2-amylenyl-anthraquinones, preparation method and its use thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4514376A (en) * 1984-04-19 1985-04-30 Fmc Corporation Pregeneration of tetrahydroanthraquinones in a make-up solution to be added to a hydrogen peroxide working solution
US4539196A (en) * 1984-04-19 1985-09-03 Fmc Corporation Process for hydrogenating an alkylated anthraquinone
EP0158864A2 (en) * 1984-04-19 1985-10-23 FMC Corporation Process for hydrogenating an alkylated anthraquinone
EP0158865A2 (en) * 1984-04-19 1985-10-23 FMC Corporation Pregeneration of tetrahydroanthraquinone in a make-up solution to be added to a hydrogen peroxide working solution
EP0158865A3 (en) * 1984-04-19 1986-02-12 Fmc Corporation Pregeneration of tetrahydroanthraquinone in a make-up solution to be added to a hydrogen peroxide working solution
EP0158864A3 (en) * 1984-04-19 1986-02-19 Fmc Corporation Process for hydrogenating an alkylated anthraquinone
US5399333A (en) * 1992-12-25 1995-03-21 Mitsubishi Chemical Gas Co., Ltd. Process for producing hydrogen peroxide
WO2023102759A1 (en) * 2021-12-08 2023-06-15 Solvay Sa A composition comprising 2-amylenyl-anthraquinones, preparation method and its use thereof

Also Published As

Publication number Publication date
BE769675A (en) 1972-01-10
FR2144725A1 (en) 1973-02-16
FR2144725B1 (en) 1978-03-03

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee