GB1390408A - Cyclic process for the production of hydrogen peroxide - Google Patents
Cyclic process for the production of hydrogen peroxideInfo
- Publication number
- GB1390408A GB1390408A GB3165472A GB3165472A GB1390408A GB 1390408 A GB1390408 A GB 1390408A GB 3165472 A GB3165472 A GB 3165472A GB 3165472 A GB3165472 A GB 3165472A GB 1390408 A GB1390408 A GB 1390408A
- Authority
- GB
- United Kingdom
- Prior art keywords
- temp
- mixture
- hydrogen peroxide
- july
- tert
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1390408 Hydrogen peroxide by anthraquinone process SOLWAY & CIE 6 July 1972 [8 July 1971] 31654/72 Heading C1A A mixture of 2-tert. amyl and 2-sec. isoamyltetrahydroanthraquinones are used as intermediates in the anthraquinone process for producing H 2 O 2 . The mixture preferably contains 30-55% by wt. of the 2-tert. compound and 70-45% of the 2-sec. compound. The solvent may be a mixture of (a) C 6 -C 11 petroleum fractions, naphthalene, chlorinated hydrocarbons, alkyl benzenes or anisole with (b) aliphatic alcohols having at least 6 carbon atoms, e.g. heptanol, methylcyclohexanol, octan-2-ol, diisobutyl carbinol, or aliphatic esters of carboxylic or phosphoric acids. The quinone hydrogenation may be catalysed by Raney Ni, or Pd on hydroxyapatite, Re, Rh, Pt or Pd at a temp. of 45-70‹.C. to 90% conversion. The quinol oxidation may be carried out in air at a pressure of 3-5 kg.(cm.<SP>2</SP> in a co- or counter-current manner in a packed column at a temp. of 20-50‹ C. Anthraquinone by-products may be removed, prior to recycle after H 2 O 2 removal, by treatment with alkali metal or alkaline earth metalhydroxides, or alkaline alumina or aluminosilicates at temp. of 20-150‹ C.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE769675A BE769675A (en) | 1971-07-08 | 1971-07-08 | CYCLICAL PROCESS FOR THE MANUFACTURE OF HYDROGEN PEROXIDE. |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1390408A true GB1390408A (en) | 1975-04-09 |
Family
ID=3858377
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3165472A Expired GB1390408A (en) | 1971-07-08 | 1972-07-06 | Cyclic process for the production of hydrogen peroxide |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE769675A (en) |
FR (1) | FR2144725B1 (en) |
GB (1) | GB1390408A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4514376A (en) * | 1984-04-19 | 1985-04-30 | Fmc Corporation | Pregeneration of tetrahydroanthraquinones in a make-up solution to be added to a hydrogen peroxide working solution |
US4539196A (en) * | 1984-04-19 | 1985-09-03 | Fmc Corporation | Process for hydrogenating an alkylated anthraquinone |
US5399333A (en) * | 1992-12-25 | 1995-03-21 | Mitsubishi Chemical Gas Co., Ltd. | Process for producing hydrogen peroxide |
WO2023102759A1 (en) * | 2021-12-08 | 2023-06-15 | Solvay Sa | A composition comprising 2-amylenyl-anthraquinones, preparation method and its use thereof |
-
1971
- 1971-07-08 BE BE769675A patent/BE769675A/en not_active IP Right Cessation
-
1972
- 1972-06-30 FR FR7223923A patent/FR2144725B1/fr not_active Expired
- 1972-07-06 GB GB3165472A patent/GB1390408A/en not_active Expired
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4514376A (en) * | 1984-04-19 | 1985-04-30 | Fmc Corporation | Pregeneration of tetrahydroanthraquinones in a make-up solution to be added to a hydrogen peroxide working solution |
US4539196A (en) * | 1984-04-19 | 1985-09-03 | Fmc Corporation | Process for hydrogenating an alkylated anthraquinone |
EP0158864A2 (en) * | 1984-04-19 | 1985-10-23 | FMC Corporation | Process for hydrogenating an alkylated anthraquinone |
EP0158865A2 (en) * | 1984-04-19 | 1985-10-23 | FMC Corporation | Pregeneration of tetrahydroanthraquinone in a make-up solution to be added to a hydrogen peroxide working solution |
EP0158865A3 (en) * | 1984-04-19 | 1986-02-12 | Fmc Corporation | Pregeneration of tetrahydroanthraquinone in a make-up solution to be added to a hydrogen peroxide working solution |
EP0158864A3 (en) * | 1984-04-19 | 1986-02-19 | Fmc Corporation | Process for hydrogenating an alkylated anthraquinone |
US5399333A (en) * | 1992-12-25 | 1995-03-21 | Mitsubishi Chemical Gas Co., Ltd. | Process for producing hydrogen peroxide |
WO2023102759A1 (en) * | 2021-12-08 | 2023-06-15 | Solvay Sa | A composition comprising 2-amylenyl-anthraquinones, preparation method and its use thereof |
Also Published As
Publication number | Publication date |
---|---|
BE769675A (en) | 1972-01-10 |
FR2144725A1 (en) | 1973-02-16 |
FR2144725B1 (en) | 1978-03-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |