GB1379257A - Hydroisomerisation process using leached mordenite catalyst - Google Patents

Hydroisomerisation process using leached mordenite catalyst

Info

Publication number
GB1379257A
GB1379257A GB5328271A GB5328271A GB1379257A GB 1379257 A GB1379257 A GB 1379257A GB 5328271 A GB5328271 A GB 5328271A GB 5328271 A GB5328271 A GB 5328271A GB 1379257 A GB1379257 A GB 1379257A
Authority
GB
United Kingdom
Prior art keywords
paraffins
nov
sio
per cent
mordenite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5328271A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sunoco Inc R&M
Sunoco Inc
Original Assignee
Sun Oil Co
Sun Oil Company of Pennsylvania
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sun Oil Co, Sun Oil Company of Pennsylvania filed Critical Sun Oil Co
Publication of GB1379257A publication Critical patent/GB1379257A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • B01J29/22—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/226—Catalytic processes not covered by C07C5/23 - C07C5/31 with metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C07C2529/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • C07C2529/22—Noble metals

Abstract

1379257 Isomerizing n-paraffins SUN OIL CO OF PENNSYLVANIA 17 Nov 1971 [17 Nov 1970 1 Oct 1971] 53282/71 Heading C5E The octane rating of gasoline streams comprising C 4 -C 10 n.paraffins and sulphur compounds and/or aromatic hydrocarbon impurities is increased by isomerization at 250-340‹ under 100-1000 p.s.i.g. H 2 , at 0À5-10 LHSV, with a catalyst comprising a solid hydrogenation component and an aluminosilicate zeolite which is at least 5% crystalline, the crystalline portion comprising hydrogenmordenite having a SiO 2 /Al 2 O 3 mole ratio in the range 15À9 to 50 and containing less than 1 wt. per cent alkali metal cations. The mordenite preferably with a SiO 2 /Al 2 O 3 ratio of 16-21 is obtained by leaching H-mordenite with HCl (e.g. 5-12N) at 20-100‹ C. The hydrogenation component may be Pt, Pd, Rh, Re, Ru, Mo, Co or Ni or oxide or sulphide thereof present in amount 0À1-10 wt. per cent.
GB5328271A 1970-11-17 1971-11-17 Hydroisomerisation process using leached mordenite catalyst Expired GB1379257A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US9046370A 1970-11-17 1970-11-17
US18561571A 1971-10-01 1971-10-01

Publications (1)

Publication Number Publication Date
GB1379257A true GB1379257A (en) 1975-01-02

Family

ID=26782297

Family Applications (2)

Application Number Title Priority Date Filing Date
GB585774A Expired GB1379258A (en) 1970-11-17 1971-11-17 Pelleted catalyst composition
GB5328271A Expired GB1379257A (en) 1970-11-17 1971-11-17 Hydroisomerisation process using leached mordenite catalyst

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB585774A Expired GB1379258A (en) 1970-11-17 1971-11-17 Pelleted catalyst composition

Country Status (6)

Country Link
BE (1) BE775416A (en)
CA (1) CA998989A (en)
DE (1) DE2157140A1 (en)
GB (2) GB1379258A (en)
IT (1) IT943670B (en)
NL (1) NL7115854A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0046615A1 (en) * 1980-08-26 1982-03-03 Shell Internationale Researchmaatschappij B.V. Preparation of a catalyst for normal paraffin isomerization
FR2519335A1 (en) * 1982-01-04 1983-07-08 Azote & Prod Chim PRODUCTION OF HYDROCARBONS FROM METHANOL IN THE PRESENCE OF CATALYSTS OF THE ZEOLITHE TYPE
CN112934251A (en) * 2019-12-11 2021-06-11 中国科学院大连化学物理研究所 Bifunctional catalyst for catalyzing n-heptane hydroisomerization and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4128591A (en) * 1977-05-31 1978-12-05 Engelhard Minerals & Chemicals Corporation Alkyl aromatic isomerization

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0046615A1 (en) * 1980-08-26 1982-03-03 Shell Internationale Researchmaatschappij B.V. Preparation of a catalyst for normal paraffin isomerization
FR2519335A1 (en) * 1982-01-04 1983-07-08 Azote & Prod Chim PRODUCTION OF HYDROCARBONS FROM METHANOL IN THE PRESENCE OF CATALYSTS OF THE ZEOLITHE TYPE
EP0084748A1 (en) * 1982-01-04 1983-08-03 Societe Chimique De La Grande Paroisse, Azote Et Produits Chimiques Preparation of hydrocarbons from methanol in the presence of catalysts of the zeolite-type
US4447669A (en) * 1982-01-04 1984-05-08 Societe Chimique De La Grande Paroisse, Azote Et Produits Chimiques Production of hydrocarbons from methanol in the presence of zeolite catalysts
CN112934251A (en) * 2019-12-11 2021-06-11 中国科学院大连化学物理研究所 Bifunctional catalyst for catalyzing n-heptane hydroisomerization and preparation method thereof
CN112934251B (en) * 2019-12-11 2023-06-06 中国科学院大连化学物理研究所 Double-function catalyst for catalyzing hydroisomerization of n-heptane and preparation method thereof

Also Published As

Publication number Publication date
GB1379258A (en) 1975-01-02
DE2157140A1 (en) 1972-05-25
NL7115854A (en) 1972-05-19
IT943670B (en) 1973-04-10
BE775416A (en) 1972-05-17
CA998989A (en) 1976-10-26

Similar Documents

Publication Publication Date Title
US3759821A (en) Catalytic process for upgrading cracked gasolines
US3668113A (en) Hydrocatalytic process for normal paraffin wax and sulfur removal
USRE28398E (en) Marshall dann
GB1183397A (en) Improved Mordenite Catalyst Compositions
GB1333051A (en) Aluminosilicate zeolites and their use as shape selective catalysts
DE1645716C3 (en) Process for the preparation of a catalyst for the hydrogenative conversion of hydrocarbons
GB1251388A (en)
GB1039167A (en) Improved hydrocracking conversion catalyst and process
GB1133386A (en) Hydrocracking process for upgrading naphtha
GB1258292A (en)
GB1379257A (en) Hydroisomerisation process using leached mordenite catalyst
US3764516A (en) Isomerization of waxy lube streams and waxes using zeolite catalyst
GB1281265A (en) A catalytic composition for the conversion of petroleum hydrocarbons
GB1264545A (en)
US3625880A (en) Catalysts for the selective conversion of straight-chain hydrocarbons
GB1064032A (en) Conversion process
GB1286304A (en) Catalyst and process for converting hydrocarbons
US3474025A (en) Shape selective hydrocarbon conversion over activated offretite
GB1178594A (en) Hydrocarbon Conversion Catalysts
DE1236701B (en) Process for lowering the pour point of gas oils
DE1200991B (en) Process for the hydrogenative cracking of a hydrocarbon oil
GB1304773A (en)
DE1568123A1 (en) Process for the conversion of hydrocarbon compounds
GB1126918A (en) Selective conversion process
GB1270607A (en) Production of motor and jet fuels

Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee