GB1375178A - - Google Patents
Info
- Publication number
- GB1375178A GB1375178A GB2846874A GB2846874A GB1375178A GB 1375178 A GB1375178 A GB 1375178A GB 2846874 A GB2846874 A GB 2846874A GB 2846874 A GB2846874 A GB 2846874A GB 1375178 A GB1375178 A GB 1375178A
- Authority
- GB
- United Kingdom
- Prior art keywords
- anhydride
- methacrylates
- radiation
- vinyl
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/06—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to oxygen-containing macromolecules
- C08F291/10—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to oxygen-containing macromolecules on to macromolecules containing epoxy radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
- C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
- C08G59/1461—Unsaturated monoacids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1375178 Coating/polymerising with high energy radiation O'BRIEN CORP 7 Oct 1971 28468/74 Divided out of 1375177 Heading B2E [Also in Division C3] A method of coating a substrate at ambient temperatures comprises applying a film of a liquid coating composition to said substrate, said composition comprising an ethylenically unsaturated polymerisable monomer solvent and a prepolymer which is the reaction product of an acrylate functional intermediate and an epoxide containing compound, said intermediate being the reaction product of an organic acid anhydride comprising endic anhydride (2,2,1-bicyclo-5- heptene-2,3- dicarboxylic anhydride) and/or a chlorinated derivative of endic anhydride and/or an alkylated derivative of endic anahydride and a hydroxy acrylate of the formula wherein R is H or methyl and Z is an optionally substituted alkylene radical containing up to 12 carbon atoms; and curing the film by subjecting it to the influence of high energy ionising radiation, preferably electron beam radiation. If desired, the radiation curing may be followed by a thermal curing step. Suitable polymerisable solvents include vinyl esters of synthetic tertiary carboxylic acids, alkyl acrylates and methacrylates, cyclohexyl acrylate, hydroxyalkyl acrylates and methacrylates, ethylene glycol butyl ether monoacrylate, vinyl pyrrolidone, vinyl toluene, hexachlorobutadiene, styrene, ethyl vinyl benzene, isopropyl styrene, α-methyl styrene, acrylic acid, vinyl acetate, and polyol polyacrylates and methacrylates. The compositions may also include additives such as pigments, dyes, fillers and abrasives, such as CaCO 3 , MgO, BaSO 4 , Al 2 O 3 , powdered slate, asbestos or silicon carbide, or wallnut shell flour. In Examples the prepolymer is prepared by reacting together chlorendic anhydride and 2- hydroxyethyl acrylate in the presence of a polymerisation inhibitor, and then reacting the product with an epoxy novolac resin. Exemplified substrates include ceiling tiles, ABS panels and beverage containers.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4677171A GB1375177A (en) | 1970-10-23 | 1971-10-07 | |
GB2846874A GB1375178A (en) | 1970-10-23 | 1971-10-07 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8364170A | 1970-10-23 | 1970-10-23 | |
GB2846874A GB1375178A (en) | 1970-10-23 | 1971-10-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1375178A true GB1375178A (en) | 1974-11-27 |
Family
ID=60201775
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4677171A Expired GB1375177A (en) | 1970-10-23 | 1971-10-07 | |
GB2846874A Expired GB1375178A (en) | 1970-10-23 | 1971-10-07 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4677171A Expired GB1375177A (en) | 1970-10-23 | 1971-10-07 |
Country Status (1)
Country | Link |
---|---|
GB (2) | GB1375177A (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4431782A (en) * | 1981-07-27 | 1984-02-14 | The Dow Chemical Company | Process for the preparation of radiation-curable, water-thinnable vinyl ester resins |
DE3332564A1 (en) * | 1983-09-09 | 1985-03-28 | Basf Ag, 6700 Ludwigshafen | MAGNETIC RECORDING CARRIERS |
DE3332504A1 (en) * | 1983-09-09 | 1985-03-28 | Basf Ag, 6700 Ludwigshafen | MAGNETIC RECORDING CARRIERS |
DE3332503A1 (en) * | 1983-09-09 | 1985-03-28 | Basf Ag, 6700 Ludwigshafen | MAGNETIC RECORDING CARRIERS |
DE3418482A1 (en) * | 1984-05-18 | 1985-11-21 | Basf Ag, 6700 Ludwigshafen | MAGNETIC RECORDING CARRIERS |
-
1971
- 1971-10-07 GB GB4677171A patent/GB1375177A/en not_active Expired
- 1971-10-07 GB GB2846874A patent/GB1375178A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB1375177A (en) | 1974-11-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
433D | Application made for revocation (sect. 33/1949) | ||
433G | Case decided by the comptroller ** application refused (sect. 33/1949) | ||
PCNP | Patent ceased through non-payment of renewal fee |