GB1374300A - Process for producing allylcarboxylates - Google Patents
Process for producing allylcarboxylatesInfo
- Publication number
- GB1374300A GB1374300A GB6085071A GB6085071A GB1374300A GB 1374300 A GB1374300 A GB 1374300A GB 6085071 A GB6085071 A GB 6085071A GB 6085071 A GB6085071 A GB 6085071A GB 1374300 A GB1374300 A GB 1374300A
- Authority
- GB
- United Kingdom
- Prior art keywords
- lead
- compound
- carboxylate
- acetate
- carrier material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
- B01J27/232—Carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1374300 Carboxylation catalysts TOYO SODA MFG CO Ltd 30 Dec 1971 [30 Dec 1970] 60850/71 Heading B1E [Also in Division C2] Catalyst for use in the preparation of allyl carboxylate from propylene, molecular oxygen and carboxylic acid comprises carrier material upon which is supported (a) elemental palladium, (b) a compound of lead and (c) either an alkali metal carboxylate and/or an alkaline earth metal carboxylate or an alkali metal compound and/or an alkaline earth metal compound convertible to an alkali metal carboxylate and/or an alkaline earth metal carboxylate by reaction with the carboxylic acid reactant. The carrier material may comprise alumina, silica gel, silica-alumina, aluminium, phosphate, activated carbon, silicon carbide, pumice and/or diatomaceous earth. The elemental palladium may have been obtained by reducing palladium chloride, nitrate and/or acetate in situ on the carrier material. The compound of lead may be selected from oxides, chloride, nitrate and acetate of lead. The carboxylate, which may be derived from a carboxylic acid having from 1 to 4 carbon atoms, may be an acetate, propionate or butyrate of lithium, sodium, potassium or magnesium; alternatively, the catalyst may comprise, as the compound convertible to carboxylate, a carbonate or borate such as sodium carbonate, potassium carbonate or sodium borate. The catalyst may contain, per 100 parts by weight of carrier material, from 0.01 to 10.0 parts by weight of palladium, from 0.01 to 20.0 parts by weight of a compound of lead, calculated as elemental lead, and from 0.01 to 30.0 parts by weight of alkali metal/ alkaline earth metal carboxylate. As exemplified, catalyst is prepared from activated alumina, palladium chloride, lead nitrate and either potassium acetate (Example 1) or sodium tetraborate (Example 3) or from activated carbon, palladium chloride, lead (II) acetate and magnesium acetate (Example 2) by a procedure wherein the carrier material is composited with palladium chloride from aqueous hydrochloric acid (Examples 1 and 2) or ammonia (Example 3) solution, subjected to reduction with aqueous hydrazine hydrate/ caustic soda solution (Examples 1 and 2) or hydrogen (Example 3) and thereafter composited with the lead compound and with the alkali metal/alkaline earth metal compound.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12677570A JPS505685B1 (en) | 1970-12-30 | 1970-12-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1374300A true GB1374300A (en) | 1974-11-20 |
Family
ID=14943611
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB6085071A Expired GB1374300A (en) | 1970-12-30 | 1971-12-30 | Process for producing allylcarboxylates |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPS505685B1 (en) |
DE (1) | DE2165738C3 (en) |
FR (1) | FR2120147B1 (en) |
GB (1) | GB1374300A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010080090A1 (en) * | 2008-12-18 | 2010-07-15 | Lyondell Chemical Technology, L.P. | Direct epoxidation process using improved catalyst |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1521560A (en) * | 1975-11-13 | 1978-08-16 | Columbia Ribbon Carbon Mfg | Production of imaged master sheets |
JPS5951850B2 (en) * | 1980-03-19 | 1984-12-17 | 東亜燃料工業株式会社 | Catalyst for diacyloxylation of conjugated dienes |
JPH0729980B2 (en) * | 1988-09-29 | 1995-04-05 | 昭和電工株式会社 | Method for producing allyl acetate |
-
1970
- 1970-12-30 JP JP12677570A patent/JPS505685B1/ja active Pending
-
1971
- 1971-12-30 DE DE19712165738 patent/DE2165738C3/en not_active Expired
- 1971-12-30 GB GB6085071A patent/GB1374300A/en not_active Expired
- 1971-12-30 FR FR7147558A patent/FR2120147B1/fr not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010080090A1 (en) * | 2008-12-18 | 2010-07-15 | Lyondell Chemical Technology, L.P. | Direct epoxidation process using improved catalyst |
US7767835B2 (en) | 2008-12-18 | 2010-08-03 | Lyondell Chemical Technology, L.P. | Direct epoxidation process using improved catalyst |
Also Published As
Publication number | Publication date |
---|---|
JPS505685B1 (en) | 1975-03-06 |
DE2165738C3 (en) | 1979-03-29 |
FR2120147B1 (en) | 1973-06-08 |
DE2165738B2 (en) | 1973-05-10 |
DE2165738A1 (en) | 1972-07-27 |
FR2120147A1 (en) | 1972-08-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |