GB1357735A - Catalytic hydroformylation and hydrogenation of gaseous olefinically unsaturated compounds - Google Patents

Catalytic hydroformylation and hydrogenation of gaseous olefinically unsaturated compounds

Info

Publication number
GB1357735A
GB1357735A GB2782470A GB2782470A GB1357735A GB 1357735 A GB1357735 A GB 1357735A GB 2782470 A GB2782470 A GB 2782470A GB 2782470 A GB2782470 A GB 2782470A GB 1357735 A GB1357735 A GB 1357735A
Authority
GB
United Kingdom
Prior art keywords
hydroformylation
hydrogenation
gaseous
unsaturated compounds
olefinically unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2782470A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Priority to GB2782470A priority Critical patent/GB1357735A/en
Publication of GB1357735A publication Critical patent/GB1357735A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1357735 Hydroformylation and hydrogenation reactions JOHNSON MATTHEY & CO Ltd 7 June 1971 [9 June 1970] 27824/70 Heading C2C Hydroformylation and hydrogenation are effected by reacting an olefinic compound in the form of a gas, hydrogen and carbon monoxide (for hydroformylation) in the presence of a hydridocarbonyl complex or rhodium including an arsenic- or antimony-containing donor ligand in the absence of an inert solvent but in the presence of an arsenic- or antimony-containing ligand in liquid form. An example prepares predominantly linear butyraldehyde by hydroformylation of propylene. Reference is also made to obtaining n-propanol in this reaction by turning off the carbon monoxide supply at a suitable stage.
GB2782470A 1970-06-09 1970-06-09 Catalytic hydroformylation and hydrogenation of gaseous olefinically unsaturated compounds Expired GB1357735A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2782470A GB1357735A (en) 1970-06-09 1970-06-09 Catalytic hydroformylation and hydrogenation of gaseous olefinically unsaturated compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2782470A GB1357735A (en) 1970-06-09 1970-06-09 Catalytic hydroformylation and hydrogenation of gaseous olefinically unsaturated compounds

Publications (1)

Publication Number Publication Date
GB1357735A true GB1357735A (en) 1974-06-26

Family

ID=10265897

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2782470A Expired GB1357735A (en) 1970-06-09 1970-06-09 Catalytic hydroformylation and hydrogenation of gaseous olefinically unsaturated compounds

Country Status (1)

Country Link
GB (1) GB1357735A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0014796A2 (en) * 1978-10-04 1980-09-03 Toa Nenryo Kogyo Kabushiki Kaisha Process for the production of aldehydes by hydroformylation in presence of rhodium compound
US4259530A (en) * 1979-04-06 1981-03-31 Toa Nenryo Kogyo Kabushiki Kaisha Process for the production of aldehydes by hydroformylation
US4288634A (en) * 1978-04-10 1981-09-08 Toa Nenryo Kogyo Kabushiki Kaisha Novel rhodium compounds and process for producing the same
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5817883A (en) * 1996-04-24 1998-10-06 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing hydroxyaldehydes
US5821389A (en) * 1996-04-24 1998-10-13 Union Carbide Chemicals & Technology Corporation Processes for producing hydroxyaldehydes
US5925754A (en) * 1997-04-15 1999-07-20 Union Carbide Chemicals & Plastics Technology Corporation Epsilon caprolactam compositions
US6172269B1 (en) 1996-04-24 2001-01-09 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing 1,6-hexanediols
US6187970B1 (en) 1996-04-24 2001-02-13 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing 1,6-hexanediols

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4288634A (en) * 1978-04-10 1981-09-08 Toa Nenryo Kogyo Kabushiki Kaisha Novel rhodium compounds and process for producing the same
EP0089697A3 (en) * 1978-10-04 1984-02-08 Toa Nenryo Kogyo K.K. Rhodium compounds and process for producing them
EP0014796A3 (en) * 1978-10-04 1982-02-10 Toa Nenryo Kogyo K.K. Process for the production of aldehydes by hydroformylation in presence of rhodium compound
US4397788A (en) * 1978-10-04 1983-08-09 Toa Nenryo Kogyo Kabushiki Kaisha Process for producing rhodium compounds
EP0089697A2 (en) * 1978-10-04 1983-09-28 Toa Nenryo Kogyo Kabushiki Kaisha Rhodium compounds and process for producing them
EP0014796A2 (en) * 1978-10-04 1980-09-03 Toa Nenryo Kogyo Kabushiki Kaisha Process for the production of aldehydes by hydroformylation in presence of rhodium compound
US4259530A (en) * 1979-04-06 1981-03-31 Toa Nenryo Kogyo Kabushiki Kaisha Process for the production of aldehydes by hydroformylation
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5817883A (en) * 1996-04-24 1998-10-06 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing hydroxyaldehydes
US5821389A (en) * 1996-04-24 1998-10-13 Union Carbide Chemicals & Technology Corporation Processes for producing hydroxyaldehydes
US6172269B1 (en) 1996-04-24 2001-01-09 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing 1,6-hexanediols
US6187970B1 (en) 1996-04-24 2001-02-13 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing 1,6-hexanediols
US5925754A (en) * 1997-04-15 1999-07-20 Union Carbide Chemicals & Plastics Technology Corporation Epsilon caprolactam compositions

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee