GB1343456A - Process for the removal of sulphur trioxide from gases - Google Patents

Process for the removal of sulphur trioxide from gases

Info

Publication number
GB1343456A
GB1343456A GB1074671*[A GB1074671A GB1343456A GB 1343456 A GB1343456 A GB 1343456A GB 1074671 A GB1074671 A GB 1074671A GB 1343456 A GB1343456 A GB 1343456A
Authority
GB
United Kingdom
Prior art keywords
gases
oxide
plates
absorption
glass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1074671*[A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1343456A publication Critical patent/GB1343456A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/508Sulfur oxides by treating the gases with solids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/48Sulfur dioxide; Sulfurous acid
    • C01B17/50Preparation of sulfur dioxide
    • C01B17/60Isolation of sulfur dioxide from gases

Abstract

1343456 Removing SO 3 from gases; Al 2 O 3 plates; alumina ceramics SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ NV 22 April 1971 [24 April 1970] 10746/71 Headings C1A and C1J SO 3 is removed from gases by contacting the gases with a solid inorganic oxide which reacts chemically with SO 3 , and the oxide is then regenerated with H 2 S. The oxide may be #, α, or γ-Al 2 O 3 , or MgO, and may contain up to 10% alkali metal or alkaline earth metal oxide. The absorption may be carried out at 250-625‹ C. and the regeneration at within 50‹ C. of this temperature, e.g. 200-550‹ C. SO 2 -containing gases, e.g. kue gases and Claus off-gases, are first oxidized to SOt using a catalyst, e.g. of K 2 O and V 2 O 5 on SiO 2 . The oxidation may be effected in an apparatus comprising parallel gas channels with gauze walls, separated by catalyst zones. The absorption apparatus may comprise a plurality of parallel plates of the oxide with gas channels between them. After absorption the gases may be contacted with Cu and/or Cu oxide on an Al 2 O 3 support to remove residual SO 3 . The gases from the regeneration (SO 2 H 2 S and S vapour) may be fed to a Claus plant. γ-Al 2 O 3 plates may be made by calcining Al 2 O 3 or hydrated Al 2 O 3 at above 780‹ C., e.g. 800-1100‹ C., mixing with a binding agent, with or without water, powdered glass, and a pore-forming agent, compressing, optionally drying at 200‹ C. or below, and heating at above 780‹ C. The binding agent may be kaolioite, attapulgite, bentonite, halloysite, or montmorillonite and may be used in amounts of 0À1-0À5 pts. per pt. Al 2 O 3 . The glass may be soda-lime, lead or borosilicate glass, and may be present in amounts of up 10% in the plates. The poreforming agent may be polypropylene, polypivalolactone, flour, wood chips, paraffin wax, sugar, persalts, or peroxides.
GB1074671*[A 1970-04-24 1971-04-22 Process for the removal of sulphur trioxide from gases Expired GB1343456A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7005974A NL7005974A (en) 1970-04-24 1970-04-24

Publications (1)

Publication Number Publication Date
GB1343456A true GB1343456A (en) 1974-01-10

Family

ID=19809941

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1074671*[A Expired GB1343456A (en) 1970-04-24 1971-04-22 Process for the removal of sulphur trioxide from gases

Country Status (9)

Country Link
BE (1) BE765827A (en)
CA (1) CA949288A (en)
CH (1) CH560553A5 (en)
DE (1) DE2119716A1 (en)
ES (1) ES390447A1 (en)
FR (1) FR2090554A5 (en)
GB (1) GB1343456A (en)
NL (1) NL7005974A (en)
ZA (1) ZA712622B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2838093A1 (en) * 1977-08-31 1979-03-08 Mitsubishi Heavy Ind Ltd METHOD AND DEVICE FOR TREATMENT OF EXHAUST GAS

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2435281A1 (en) * 1978-09-08 1980-04-04 Poelman Sofiltra INSTALLATION FOR FILTERING A CONTAMINATED FLUID USING A PNEUMATICALLY RENEWABLE GRANULAR MATERIAL
FR2426645A1 (en) * 1979-07-23 1979-12-21 Gulf Canada Ltd Elimination of sulphur and sulphur cpds. from gases - by treatment with aq. suspension of catalytic material partic. active carbon
DE3122349A1 (en) * 1981-06-05 1982-12-23 Böhmeke, Albin, Prof. Dr., 5410 Höhr-Grenzhausen METHOD FOR ELIMINATING POLLUTANTS FROM EXHAUST GAS
FR2587236B1 (en) * 1985-09-13 1987-11-13 Inst Francais Du Petrole PROCESS FOR THE REMOVAL OF SULFUR OXIDES FROM A GAS BY MEANS OF AN ABSORPTION MASS REGENERABLE BY REACTION WITH HYDROGEN SULFIDE
CN114272709A (en) * 2021-11-10 2022-04-05 浙江华兴玻璃有限公司 Novel integrated process for denitration, desulfurization and dust removal of ceramic tube and matched device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2838093A1 (en) * 1977-08-31 1979-03-08 Mitsubishi Heavy Ind Ltd METHOD AND DEVICE FOR TREATMENT OF EXHAUST GAS

Also Published As

Publication number Publication date
NL7005974A (en) 1971-10-26
FR2090554A5 (en) 1972-01-14
ZA712622B (en) 1972-01-26
CH560553A5 (en) 1975-04-15
DE2119716A1 (en) 1971-11-11
CA949288A (en) 1974-06-18
BE765827A (en) 1971-10-18
ES390447A1 (en) 1973-06-01

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees