GB1339981A - Curable copolymers - Google Patents

Curable copolymers

Info

Publication number
GB1339981A
GB1339981A GB2352771A GB2352771A GB1339981A GB 1339981 A GB1339981 A GB 1339981A GB 2352771 A GB2352771 A GB 2352771A GB 2352771 A GB2352771 A GB 2352771A GB 1339981 A GB1339981 A GB 1339981A
Authority
GB
United Kingdom
Prior art keywords
acrylate
halide
isobutylene
ethyl
boron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2352771A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP1891370A external-priority patent/JPS4938026B1/ja
Priority claimed from JP1891570A external-priority patent/JPS4936822B1/ja
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Publication of GB1339981A publication Critical patent/GB1339981A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1339981 Acrylic ester copolymers SUMITOMO CHEMICAL CO Ltd 19 April 1971 [4 March 1970 (2)] 23527/71 Heading C3P Curable halogen-containing copolymers comprising units of at least one olefin, at least one hydrocarbyl acrylic ester and at least one halogen-substituted olefin, styrene, hydrocarbon-substituted styrene, bridged cyclic unsaturated hydrocarbon, diolefin, unsaturated alcohol ester, acrylonitrile, acrylic acid, acrylic ester, acryloyl halide or acrylamide, are prepared by copolymerizing the monomers in the presence of a metal halide. The polymers may be derived from isobutylene, propylene, ethylene, butene-1, 2-methylbutene-1, hexene-1, butene-2, 4-methylpentene-1 and octadecene-1; methyl, ethyl, propyl, butyl, amyl, hexyl, 2- ethylhexyl, octadecyl, allyl, crotyl, cinnamyl, o-tolyl, benzyl, norbornenylmethyl and cyclohexyl acrylates; and halogen-substituted acrylonitriles, acrylamides, unsaturated esters and acid halides. The metal halide may be an aluminium halide, alkyl aluminium halide, boron trihalide, alkyl boron halide, zinc halide, tin tetrahalide or alkyl tin halide, and polymerization may be initiated by radical polymerization catalysts, oxygen, organometallic compounds or actinic radiation. The copolymers may be cured by heating with basic compounds, e.g. aliphatic polyamines and heterocyclic compounds containing at least two nitrogen atoms. Examples describe the copolymerization of isobutylene, ethyl acrylate and (1) 2- chlorethyl acrylate, (2) vinyl chloracetate and (3) methallyl chloride in the presence of ethyl boron dichloride; (4) propylene, amyl acrylate and 3-chloropropyl acrylate in the presence of ethyl aluminium sesquichloride ; (5) isobutylene, n-butyl acrylate and 2-chlorethyl acrylate or vinyl chloracetate in the presence of zinc chloride and triethyl boron; and (6) isobutylene, chlorallyl acrylate and 2-ethylhexyl acrylate in the presence of zinc chloride and azodiisobutyronitrue; the products being cured with (1) hexamethylene diamine carbamate or (2 and 4) triethylene tetramine and sulphur.
GB2352771A 1970-03-04 1971-04-19 Curable copolymers Expired GB1339981A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP1891370A JPS4938026B1 (en) 1970-03-04 1970-03-04
JP1891570A JPS4936822B1 (en) 1970-03-04 1970-03-04

Publications (1)

Publication Number Publication Date
GB1339981A true GB1339981A (en) 1973-12-05

Family

ID=26355656

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2352771A Expired GB1339981A (en) 1970-03-04 1971-04-19 Curable copolymers

Country Status (6)

Country Link
BE (1) BE763733A (en)
CA (1) CA1011040A (en)
DE (1) DE2110190A1 (en)
FR (1) FR2084123A5 (en)
GB (1) GB1339981A (en)
NL (1) NL7102854A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003070826A2 (en) * 2002-02-15 2003-08-28 Ppg Industries Ohio, Inc. Powder coating compositions having improved mar and acid resistance
WO2003070795A1 (en) * 2002-02-15 2003-08-28 Ppg Industries Ohio, Inc. Copolymers comprising isobutylene type and acrylate type monomers
US7132477B2 (en) 2002-02-15 2006-11-07 Ppg Industries Ohio, Inc. Powder coating compositions
US7183355B2 (en) 2002-02-15 2007-02-27 Ppg Industries, Ohio, Inc. Waterborne thermosetting compositions containing alternating copolymers of isobutylene type monomers
US7619040B2 (en) 2002-02-15 2009-11-17 Ppg Industries Ohio, Inc. Compositions containing copolymers of olefinic monomers

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5010826A (en) * 1973-06-02 1975-02-04

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003070826A2 (en) * 2002-02-15 2003-08-28 Ppg Industries Ohio, Inc. Powder coating compositions having improved mar and acid resistance
WO2003070795A1 (en) * 2002-02-15 2003-08-28 Ppg Industries Ohio, Inc. Copolymers comprising isobutylene type and acrylate type monomers
WO2003070781A1 (en) * 2002-02-15 2003-08-28 Ppg Industries Ohio, Inc. Thermosetting compositions containing alternating copolymers of isobutylene type monomers
WO2003070826A3 (en) * 2002-02-15 2003-11-13 Ppg Ind Ohio Inc Powder coating compositions having improved mar and acid resistance
US6784248B2 (en) 2002-02-15 2004-08-31 Ppg Industries Ohio, Inc. Thermosetting compositions containing alternating copolymers of isobutylene type monomers
AU2003210715B2 (en) * 2002-02-15 2006-04-06 Ppg Industries Ohio, Inc. Thermosetting compositions containing alternating copolymers of isobutylene type monomers
US7122600B2 (en) 2002-02-15 2006-10-17 Ppg Industries Ohio, Inc. Powder coating compositions having improved mar and acid resistance
US7125931B2 (en) 2002-02-15 2006-10-24 Ppg Industries Ohio, Inc. Thermosetting compositions containing alternating copolymers of isobutylene type monomers
US7132477B2 (en) 2002-02-15 2006-11-07 Ppg Industries Ohio, Inc. Powder coating compositions
US7132476B2 (en) 2002-02-15 2006-11-07 Ppg Industries Ohio, Inc. Thermosetting compositions containing alternating copolymers of isobutylene type monomers
CN1300185C (en) * 2002-02-15 2007-02-14 Ppg工业俄亥俄公司 Thermosetting compositions containing alternating copolymers of isobutylene type monomers
US7183355B2 (en) 2002-02-15 2007-02-27 Ppg Industries, Ohio, Inc. Waterborne thermosetting compositions containing alternating copolymers of isobutylene type monomers
US7619040B2 (en) 2002-02-15 2009-11-17 Ppg Industries Ohio, Inc. Compositions containing copolymers of olefinic monomers

Also Published As

Publication number Publication date
DE2110190A1 (en) 1971-09-16
FR2084123A5 (en) 1971-12-17
BE763733A (en) 1971-09-03
NL7102854A (en) 1971-09-07
CA1011040A (en) 1977-05-24

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee