GB1329126A - Acrylic fibre and a method for manufacturing the same - Google Patents
Acrylic fibre and a method for manufacturing the sameInfo
- Publication number
- GB1329126A GB1329126A GB5722970A GB5722970A GB1329126A GB 1329126 A GB1329126 A GB 1329126A GB 5722970 A GB5722970 A GB 5722970A GB 5722970 A GB5722970 A GB 5722970A GB 1329126 A GB1329126 A GB 1329126A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyethylene glycol
- monomers
- acrylonitrile
- ether
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-acryloylmorpholine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/42—Nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S260/00—Chemistry of carbon compounds
- Y10S260/21—Polymer chemically or physically modified to impart antistatic properties and methods of antistatic agent addition
Abstract
1329126 Acrylonitrile copolymer fibres MITSUBISHI RAYON CO Ltd 1 Dec 1970 [11 Dec 1969 31 March 1970] 57229/70 Heading C3P Fibres are formed from acrylonitrile copolymers comprising at least 50% by wt. of (a) acrylonitrile and less than 50% but not less than 1% of (b) a compound of the formula RCOR<SP>1</SP>NHCOCR<SP>11</SP>=CH 2 in which R and R<SP>11</SP> are H or C 1 -C 10 alkyl and R<SP>1</SP> is ethylene or alkyl-substituted ethylene containing no more than 15 carbons, (c) a monomer selected from hydroxyl-containing monomers, carboxyl monomers or their salts, sulphonic acid monomers or their salts, amide monomers, polyethylene glycol acrylates and methacrylates, vinyl pyrrolidone and other monomers with polyethylene glycol side chains and optionally (d) a fourth monomer. The fibres may also be formed from a mixture of such a copolymer with a different copolymer containing at least 85% acrylonitrile. In examples, monomer (c) is sodium vinylbenzene sulphonate, acrylic acid, sodium acrylate, hydroxyethyl acrylate, N-vinylpyrrolidone, polyethylene glycol C 18 alkyl ether monoacrylate, polyethylene glycol monononylphenol ether monomethacrylate, a di-polyethyleneglycol ether itaconate, polyethyleneglycol ether acrylamide, itaconic acid, methacrylic acid, and other polyethylene glycol ether acrylates or itaconates. In two examples vinyl acetate is present as a fourth monomer. The other copolymers used in the examples contain vinyl acetate, methyl acrylate and sodium vinylbenzene sulphonate, methyl acrylate, or vinyl acetate and methacrylic acid as comonomers. The copolymer or mixture of copolymers is dissolved in dimethyl formamide or acetamide or dimethyl sulphoxide and wet or dry spun.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9972869 | 1969-12-11 | ||
JP2655370 | 1970-03-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1329126A true GB1329126A (en) | 1973-09-05 |
Family
ID=26364357
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5722970A Expired GB1329126A (en) | 1969-12-11 | 1970-12-01 | Acrylic fibre and a method for manufacturing the same |
Country Status (5)
Country | Link |
---|---|
US (1) | US3718716A (en) |
DE (1) | DE2061213A1 (en) |
FR (1) | FR2073674A5 (en) |
GB (1) | GB1329126A (en) |
NL (1) | NL7017676A (en) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3975337A (en) * | 1972-04-20 | 1976-08-17 | Bayer Aktiengesellschaft | Process for the production of acrylic fibers processible into yarns with improved textile properties and low boiling-induced shrinkage values |
DE2730643A1 (en) * | 1977-07-07 | 1979-01-25 | Bayer Ag | FIBER AND FAED MIXTURES CONTAINING SOOT MODIFIED, HIGH-SHRINKAGE POLY (MOD) ACRYLIC BIFILAR FIBERS OR FIBERS |
DE3536262A1 (en) * | 1985-10-11 | 1987-04-16 | Basf Ag | STORAGE STABILITY, ORGANIC SOLVENT SOLVED OR DISPERSED CROSSLINKABLE COMPOSITIONS, THEIR PRODUCTION AND USE |
US6713646B2 (en) | 2002-04-12 | 2004-03-30 | Biosphere Medical | Degradable crosslinkers, and degradable crosslinked hydrogels comprising them |
US7838699B2 (en) * | 2002-05-08 | 2010-11-23 | Biosphere Medical | Embolization using degradable crosslinked hydrogels |
US6884905B2 (en) * | 2002-07-23 | 2005-04-26 | Biosphere Medical | Degradable carbamate-containing bis(acryloyl) crosslinkers, and degradable crosslinked hydrogels comprising them |
CN101910207B (en) | 2007-11-19 | 2013-04-24 | 巴斯夫欧洲公司 | Use of highly-branched polymers for producing polymer dispersions with improved freeze/thaw stability |
US8399554B2 (en) | 2007-11-19 | 2013-03-19 | Basf Se | Use of highly branched polymers in polymer dispersions for gloss colours |
AU2009227048B2 (en) | 2008-03-20 | 2014-07-17 | Basf Se | Polymer dispersions containing phosphorous polymers and emulsifiers |
EP2370516B1 (en) | 2008-12-01 | 2015-07-01 | Basf Se | Aqueous binder composition comprising oligomers |
PT2456836E (en) | 2009-07-22 | 2015-07-30 | Basf Se | Water based dispersions, fire rersistant binders for plasters and covering layers obtained therewith |
AU2010294679B2 (en) | 2009-09-15 | 2014-09-18 | Basf Se | Aqueous dispersions containing antimicrobials in a hybrid network |
PT2513154E (en) | 2009-12-16 | 2015-05-05 | Basf Se | Use of aqueous hybrid binding agents for gloss paints |
US8785557B2 (en) | 2009-12-16 | 2014-07-22 | Basf Se | Use of aqueous hybrid binders for gloss paints |
WO2011101395A1 (en) | 2010-02-18 | 2011-08-25 | Basf Se | Polymer dispersion comprising a highly branched polycarbonate with unsaturated fatty acid groups |
CN102453252B (en) * | 2010-10-20 | 2014-07-09 | 中国石油化工股份有限公司 | Acrylamide macromonomer and comb type copolymer and preparation method and application thereof |
WO2012084737A1 (en) | 2010-12-21 | 2012-06-28 | Basf Se | Multistage polymer dispersions, method for producing same, and use thereof |
US8754151B2 (en) | 2010-12-21 | 2014-06-17 | Basf Se | Multistage polymer dispersions, processes for preparing them, and use thereof |
WO2013015210A1 (en) * | 2011-07-22 | 2013-01-31 | 三菱レイヨン株式会社 | Polyacrylonitrile-based copolymer, polyacrylonitrile-based precursor fiber for carbon fiber, carbon fiber bundles, process for producing flameproofed fiber bundles, and process for producing carbon fiber bundles |
EP2636714A1 (en) | 2012-03-09 | 2013-09-11 | Basf Se | Multistage preparation of aqueous adhesive dispersions for producing self-adhesive items |
RU2674410C2 (en) | 2012-06-05 | 2018-12-07 | Басф Се | Use of multi-stage polymer dispersions to coat metal sheets |
JP2015522678A (en) | 2012-07-06 | 2015-08-06 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | Use of aqueous composite binders and alkyds for coatings |
EP3365309B1 (en) | 2015-10-20 | 2019-09-25 | Basf Se | Coating compositions for coating fibre cement board |
WO2017125277A1 (en) | 2016-01-18 | 2017-07-27 | Basf Se | Use of a single-component laminating adhesive for composite film lamination |
EP3202795B1 (en) | 2016-02-08 | 2018-08-08 | Basf Se | Use of an adhesive dispersion for glossy film lamination |
KR20180126517A (en) | 2016-03-18 | 2018-11-27 | 바스프 에스이 | A finely divided aqueous multistage polymer dispersion, a method for producing the same, and uses thereof as a binder |
WO2019201696A1 (en) | 2018-04-20 | 2019-10-24 | Basf Se | Adhesive composition having a gel content based on cross-linking via keto groups or aldehyde groups |
EP3924185B1 (en) | 2019-02-15 | 2023-01-25 | Covestro Intellectual Property GmbH & Co. KG | New systems for the priming and the adhesion of floor coverings |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE502706A (en) * | 1950-04-26 | |||
US2719138A (en) * | 1952-01-17 | 1955-09-27 | Eastman Kodak Co | Polymerization of acrylonitrile in presence of n-acyl acrylamide and n-acyl methacrylamide polymers |
US3277056A (en) * | 1963-11-27 | 1966-10-04 | Lubrizol Corp | N-3-oxohydrocarbon-substituted acrylamides and polymers thereof |
US3366613A (en) * | 1964-08-17 | 1968-01-30 | Rohm & Haas | Monomers and polymers of n-(acryloxyalkyl)acylamides and methods of making them |
US3341455A (en) * | 1966-05-31 | 1967-09-12 | Lubrizol Corp | Lubricants containing copolymeric nitrogen compounds |
GB1133410A (en) * | 1966-09-22 | 1968-11-13 | Lubrizol Corp | Method for removal of dissolved impurities from water |
US3607835A (en) * | 1967-12-20 | 1971-09-21 | Sir Soc Italiana Resine Spa | Acrylonitrile copolymers and method of preparing them |
-
1970
- 1970-12-01 GB GB5722970A patent/GB1329126A/en not_active Expired
- 1970-12-03 NL NL7017676A patent/NL7017676A/xx unknown
- 1970-12-11 DE DE19702061213 patent/DE2061213A1/en active Pending
- 1970-12-11 FR FR7044842A patent/FR2073674A5/fr not_active Expired
- 1970-12-11 US US00097330A patent/US3718716A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE2061213A1 (en) | 1971-06-24 |
US3718716A (en) | 1973-02-27 |
NL7017676A (en) | 1971-06-15 |
FR2073674A5 (en) | 1971-10-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PE20 | Patent expired after termination of 20 years |