GB1325107A - Polyester filaments and their production - Google Patents
Polyester filaments and their productionInfo
- Publication number
- GB1325107A GB1325107A GB3748471A GB3748471A GB1325107A GB 1325107 A GB1325107 A GB 1325107A GB 3748471 A GB3748471 A GB 3748471A GB 3748471 A GB3748471 A GB 3748471A GB 1325107 A GB1325107 A GB 1325107A
- Authority
- GB
- United Kingdom
- Prior art keywords
- filament
- heat
- expressed
- heated
- polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
- D02J1/229—Relaxing
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Artificial Filaments (AREA)
Abstract
1325107 Polyester filaments TEIJIN Ltd 10 Aug 1971 37484/71 Heading B5B A heat-resistant polyester filament is (i) composed of an aromatic polyester in which at least 90 mole per cent of the structural units are ethylene-2,6-naphth.alate units, (ii) has a melting point T m at a constant length of at least 287‹ C. (iii) has a density d of at least 1À370 g/cm<SP>3</SP>, (iv) is insoluble at 160‹C. in a mixed solvent containing 6 parts by weight of phenol and 4 parts by weight of o-dichlorobenzene and (v) meets the requirements expressed by the following formulae where L is a value indicating the crystal size of the aromatic polyester of the filament in the direction almost vertical to the filament axis, said L value being expressed by the equation :- in which B is a (010) diffraction peak width in radian units when the diffraction intensity is (It + Iam)/2 (where It is a diffraction intensity at (010) peak position and Iam is a meridional X-ray diffraction intensity at Bragg's reflection angle 2# = 15À6 degrees), # has the same value as in the above equation for the reflection angle, b is 0À00204 radian, K is 0À94 and # is 1À542; #n denotes the absolute value of the birefringence of the filament determined by the retardation technique using α-bromonaphthalene as a dipping liquid and a Berek compensator; and T m and d are as defined above. Preferably, such a filament has a heat-shrinkage at 255‹ C. for 5 sees. of not more than 5% and a thermal deformation temperature exceeding 260‹ C., a melting point at constant length of at least 288‹ C. is insoluble in 6 : 4 by weight mixture of phenol and o-dichlorobenzene at 170‹ C., has a Young's modulus of more than 1500 Kg/mm<SP>2</SP> at 25‹ C., a denier of 50 or less and a hydrolysis resistance of more than 75%, expressed in terms of the per cent tenacity retention obtained when a sample filament is heated under no tension at 180‹C. and at a relative humidity of 100% for 1 hour. The filament is made by heat-treatment of a melt-spun filament composed of a polyester containing at least 90 mole per cent of ethylene- 2,6-naphthalate units and which has a birefrigence of at least 0À27, wherein the filament generally after preliminary stretching e.g., at 120‹-165‹ C. at a draw ratio of 4 : 1, or at 150‹C. at a draw ratio of 5À8 followed by stretching at 200‹ C. at a draw ratio of 1À25, is heated first at 160‹ to 250‹ C., then at 250‹ to 290‹ C., the time t in hours for which the filament is maintained at any particular temperature T (in ‹C) in the range of 250 to 290‹ C. being such that the sum of all the values E expressed by the equation is at least 1, preferably at least 1À5. Desirably, the filament is heated at 160 to 250‹ C. for 0À5 to 40 sees. In examples, first stage heating is effected for 10 seconds and second stage heating for periods of from 5 mins. to 4 hours. The filament may be heated at at least two different temperatures within the range of 160-250‹ C. and/or within the range of 250- 290‹C. Suitably the filament has a denier of at most 50, a birefringence of at least 0À3 and intrinsic viscosity of 0À35 to 1À0, especially 0À55 to 1À0, determined in a 1% by weight solution of ochlorophenol at 35‹ C., using 120 mg. polymer in 100 ml. of solvent. During the heat-treatment the length of the filament should not change by more than Œ15%, preferably Œ10% and especially Œ5%. In Examples, the first-stage heat-treatment is effected at constant length and the second stage either at constant length, or conditions allowing up to 4À5% shrinkage or up to 4À5% elongation.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19712139854 DE2139854C3 (en) | 1971-08-09 | Process for the production of thread from polyethylene-2,6-naphthalate |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1325107A true GB1325107A (en) | 1973-08-01 |
Family
ID=5816249
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3748471A Expired GB1325107A (en) | 1971-08-09 | 1971-08-10 | Polyester filaments and their production |
Country Status (3)
Country | Link |
---|---|
FR (1) | FR2149631A5 (en) |
GB (1) | GB1325107A (en) |
NL (1) | NL7111005A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5397527A (en) * | 1991-12-30 | 1995-03-14 | Alliedsignal Inc. | High modulus polyester yarn for tire cords and composites |
US5618480A (en) * | 1993-06-22 | 1997-04-08 | Akzo Nobel N.V. | Process of making multifilament yarn, monofilament or film of polyethylene naphthalate |
US6015616A (en) * | 1990-05-11 | 2000-01-18 | Arteva North America S.A.R.L. | Drawn polyester yarn having a high tenacity, a high modulus and a low shrinkage |
US8017795B2 (en) | 2005-04-21 | 2011-09-13 | Ndsu Research Foundation | Radiation curable polymer films having improved laser ablation properties and radiation curable sensitizers therefor |
-
1971
- 1971-08-10 NL NL7111005A patent/NL7111005A/xx unknown
- 1971-08-10 GB GB3748471A patent/GB1325107A/en not_active Expired
- 1971-08-17 FR FR7129960A patent/FR2149631A5/fr not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6015616A (en) * | 1990-05-11 | 2000-01-18 | Arteva North America S.A.R.L. | Drawn polyester yarn having a high tenacity, a high modulus and a low shrinkage |
US5397527A (en) * | 1991-12-30 | 1995-03-14 | Alliedsignal Inc. | High modulus polyester yarn for tire cords and composites |
US5618480A (en) * | 1993-06-22 | 1997-04-08 | Akzo Nobel N.V. | Process of making multifilament yarn, monofilament or film of polyethylene naphthalate |
US8017795B2 (en) | 2005-04-21 | 2011-09-13 | Ndsu Research Foundation | Radiation curable polymer films having improved laser ablation properties and radiation curable sensitizers therefor |
Also Published As
Publication number | Publication date |
---|---|
DE2139854A1 (en) | 1973-02-22 |
FR2149631A5 (en) | 1973-03-30 |
DE2139854B2 (en) | 1977-01-27 |
NL7111005A (en) | 1973-02-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |