GB1293940A - Preparation of polyurethane composiitons - Google Patents

Preparation of polyurethane composiitons

Info

Publication number
GB1293940A
GB1293940A GB5450269A GB5450269A GB1293940A GB 1293940 A GB1293940 A GB 1293940A GB 5450269 A GB5450269 A GB 5450269A GB 5450269 A GB5450269 A GB 5450269A GB 1293940 A GB1293940 A GB 1293940A
Authority
GB
United Kingdom
Prior art keywords
polyurethane
glycol
moiety
denotes
polyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5450269A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Asahi Kasei Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP43081274A external-priority patent/JPS4812878B1/ja
Priority claimed from JP44020399A external-priority patent/JPS4813356B1/ja
Application filed by Asahi Chemical Industry Co Ltd, Asahi Kasei Kogyo KK filed Critical Asahi Chemical Industry Co Ltd
Publication of GB1293940A publication Critical patent/GB1293940A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
    • C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
    • C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
    • C08G18/0866—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4808—Mixtures of two or more polyetherdiols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

1293940 Polyurethane prepolymer dispersions ASAHI KASEI KOGYO KK 6 Nov 1969 [8 Nov 1968 19 March 1969] 54502/69 Heading C3R A polyurethane composition is prepared by dispersing in water an isocyanate groupcontaining polyurethane prepolymer based on a stoichiometric excess of an organic isocyanate and a polyol comprising a polyethylene ether moiety of a molecular weight of between 600 and 2500 and which is a percentage by weight of the polyol of at least 7À2-9 log P/100 (P being the molecular weight of the moiety), the said dispersion being effected in the presence of a sulphosuccinate-type anionic surface-active agent (S), a nonionic surface-active agent (N) having an H.L.B. value of from 6 to 16, and a compound (T) represented by the formula X-[-O-(CH 2 ) m -SO 3 Y] n , wherein X denotes an n-valent organic radical having a molecular weight of from 500 to 5000, Y denotes an alkali metal, m denotes 2, 3 or 4 and n denotes 1, 2, 3 or 4, the amount of S, N and T present being such that the percentages by weight of S, N and T, relative to the total weight of S, N and T, each percentage being plotted as one triangular co-ordinate, will not fall outside the area ABCDEA shown in Fig. 2. The H.L.B. value is stated to be one fifth of the weight per cent of the hydrophilic moiety of the surface-active agent. The dispersion may be carried out in the additional presence of a water-soluble compound containing at least 2 primary or secondary amino groups per molecule, e.g. hydrazine, aliphatic or aromatic polyamines and heterocyclic amines. The requisite polyol may be a compound containing a suitable polyethylene ether moiety or a mixture of compounds in which at least one component provides the said moiety. In examples polyurethane prepolymers suitable for dispersion are prepared from 4,4<SP>1</SP>-diphenylmethane-, 2,4-tolylene- and 1,6-hexamethylene diisocyanates, and from mixtures of polycaprolactone glycol (1200 or 1250) and polyethylene glycol (1000), polytetramethylene ether glycol (1380 or 2000) and polyethylene glycol (1200 or 1500), and polyethylene adipate (1250 or 1500) and polyethylene glycol (1000 or 1500), and from a copolymer (M.W. 2500) of epsiloncaprolactone and polyethylene glycol (800). The resulting polyurethane dispersions may be cast as films on to glass plates, aggregated to granular polyurethane by addition of sodium chloride and the resulting powder compression moulded into sheets or melted and extruded through nozzles to form filaments. Uses.-For admixture with addition polymer emulsions, for preparation of films, filaments and synthetic leathers, for coating fabrics, knits, leathers, papers, woods, and metals, for adhesives and wrinkle-resisting finishes, for blenders of concrete and mortar, for plasticizers and for blending agents for polymers. Compounds referred to as T (above) are specifically prepared by reacting polycaprolactone glycol (1200) with propanesultone and sodium hydroxide, or by reacting polytetramethylene ether glycol with propanesultone and sodium hydroxide.
GB5450269A 1968-11-08 1969-11-06 Preparation of polyurethane composiitons Expired GB1293940A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP43081274A JPS4812878B1 (en) 1968-11-08 1968-11-08
JP44020399A JPS4813356B1 (en) 1969-03-19 1969-03-19

Publications (1)

Publication Number Publication Date
GB1293940A true GB1293940A (en) 1972-10-25

Family

ID=26357343

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5450269A Expired GB1293940A (en) 1968-11-08 1969-11-06 Preparation of polyurethane composiitons

Country Status (2)

Country Link
DE (1) DE1956189C2 (en)
GB (1) GB1293940A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1600464A1 (en) * 2003-02-25 2005-11-30 Sanyo Chemical Industries, Ltd. Aqueous polyurethane resin dispersion and sheet material obtained from the same
WO2007136991A1 (en) * 2006-05-16 2007-11-29 Dow Global Technologies Inc. Aqueous non-ionic hydrophilic polyurethane dispersions, and a continuous process of making the same
EP2660373A2 (en) * 2010-12-29 2013-11-06 Hyosung Corporation Polyurethane fiber having superior adhesive force between filaments in multi-filament elastic fiber and method for manufacturing same

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9412043D0 (en) * 1994-06-16 1994-08-03 Powell Anthony Liquid dispensers
DE19805130A1 (en) * 1998-02-09 1999-08-12 Bayer Ag Antistatic polyurethane and elastane fibers

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3213049A (en) * 1961-06-19 1965-10-19 Mobay Chemical Corp Method of forming an aqueous dispersion of polyurethane

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1600464A1 (en) * 2003-02-25 2005-11-30 Sanyo Chemical Industries, Ltd. Aqueous polyurethane resin dispersion and sheet material obtained from the same
EP1600464A4 (en) * 2003-02-25 2007-04-04 Sanyo Chemical Ind Ltd Aqueous polyurethane resin dispersion and sheet material obtained from the same
US7271216B2 (en) 2003-02-25 2007-09-18 Sanyo Chemical Industries, Ltd. Polyurethane resin aqueous dispersion and sheet material obtained from the same
WO2007136991A1 (en) * 2006-05-16 2007-11-29 Dow Global Technologies Inc. Aqueous non-ionic hydrophilic polyurethane dispersions, and a continuous process of making the same
AU2007253912B2 (en) * 2006-05-16 2013-12-19 Dow Global Technologies Llc Aqueous non-ionic hydrophilic polyurethane dispersions, and a continuous process of making the same
EP2660373A2 (en) * 2010-12-29 2013-11-06 Hyosung Corporation Polyurethane fiber having superior adhesive force between filaments in multi-filament elastic fiber and method for manufacturing same
EP2660373A4 (en) * 2010-12-29 2015-01-14 Hyosung Corp Polyurethane fiber having superior adhesive force between filaments in multi-filament elastic fiber and method for manufacturing same

Also Published As

Publication number Publication date
DE1956189C2 (en) 1982-04-29
DE1956189A1 (en) 1970-06-04

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee