GB1287396A - Olefin polymerization and a catalyst therefor - Google Patents
Olefin polymerization and a catalyst thereforInfo
- Publication number
- GB1287396A GB1287396A GB22661/70A GB2266170A GB1287396A GB 1287396 A GB1287396 A GB 1287396A GB 22661/70 A GB22661/70 A GB 22661/70A GB 2266170 A GB2266170 A GB 2266170A GB 1287396 A GB1287396 A GB 1287396A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylene
- reaction product
- oic
- ticl
- isopropanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1287396 Polymerization of olefins FARBWERKE HOECHST AG 11 May 1970 [10 May 1969] 22661/70 Heading C3P [Also in Division C2] Ethylene is polymerized, optionally with up to 10% by weight of another alpha-olefin of the formula R-CH = CH 2 wherein R is C 1-13 hydrocarbon, in solution, in suspension or in the gaseous phase, at a temperature of 20-160‹ C. and pressure of up to 20 atmospheres, in the presence of a catalyst comprising (A) the reaction product of a halogen-free magnesium compound containing 0À2-2À0 mols. of hydroxy groups per gram-atom of magnesium with an alcohol, a titanium tetraalcoholate and titanium chloride, and (B) an organoaluminium compound. In the examples:-(a) ethylene is polymerized using (A) the reaction product of Mg(OH) 2 , TiCl 4 , Ti(OiC 3 H 7 ) 4 and isopropanol or isobutanol; and (B) Al(C 2 H 5 ) 3 ; and (b) a copolymer of ethylene and butene-1 is prepared using (A) the reaction product of TiCl 4 , Ti(OiC 3 H 7 ) 4 , isopropanol and the product obtained by treating MgCl 2 .6H 2 O with aqueous NaOH and Na 2 CO 3 and (B) Al(iC 4 Ha) 3 .
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19691924049 DE1924049A1 (en) | 1969-05-10 | 1969-05-10 | Process for the polymerization of olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1287396A true GB1287396A (en) | 1972-08-31 |
Family
ID=5733914
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB22661/70A Expired GB1287396A (en) | 1969-05-10 | 1970-05-11 | Olefin polymerization and a catalyst therefor |
Country Status (9)
Country | Link |
---|---|
AT (1) | AT302647B (en) |
BE (1) | BE750239A (en) |
CA (1) | CA919347A (en) |
DE (1) | DE1924049A1 (en) |
DK (1) | DK124136B (en) |
FR (1) | FR2047568A5 (en) |
GB (1) | GB1287396A (en) |
NL (1) | NL7006539A (en) |
ZA (1) | ZA702245B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2632730A1 (en) * | 1975-07-30 | 1977-02-10 | Bp Chem Int Ltd | A ZIEGLER CATALYST MOUNTED ON A CARRIER AND THE PROCESS FOR THE PRODUCTION AND USE OF THE SAME |
US4665140A (en) * | 1982-11-24 | 1987-05-12 | Cities Service Oil & Gas Corp. | Process for polymerizing a monomer charge |
-
1969
- 1969-05-10 DE DE19691924049 patent/DE1924049A1/en active Pending
- 1969-08-29 DK DK465969AA patent/DK124136B/en unknown
-
1970
- 1970-04-03 ZA ZA702245A patent/ZA702245B/en unknown
- 1970-05-04 NL NL7006539A patent/NL7006539A/xx unknown
- 1970-05-08 AT AT418170A patent/AT302647B/en not_active IP Right Cessation
- 1970-05-08 CA CA082238A patent/CA919347A/en not_active Expired
- 1970-05-11 BE BE750239D patent/BE750239A/en unknown
- 1970-05-11 GB GB22661/70A patent/GB1287396A/en not_active Expired
- 1970-05-11 FR FR7016976A patent/FR2047568A5/fr not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2632730A1 (en) * | 1975-07-30 | 1977-02-10 | Bp Chem Int Ltd | A ZIEGLER CATALYST MOUNTED ON A CARRIER AND THE PROCESS FOR THE PRODUCTION AND USE OF THE SAME |
US4256865A (en) | 1975-07-30 | 1981-03-17 | Bp Chemicals Limited | Polymerization catalyst |
USRE30970E (en) | 1975-07-30 | 1982-06-15 | Bp Chemicals Limited | Polymerization catalyst |
US4665140A (en) * | 1982-11-24 | 1987-05-12 | Cities Service Oil & Gas Corp. | Process for polymerizing a monomer charge |
Also Published As
Publication number | Publication date |
---|---|
DK124136B (en) | 1972-09-18 |
ZA702245B (en) | 1971-03-31 |
BE750239A (en) | 1970-11-12 |
FR2047568A5 (en) | 1971-03-12 |
CA919347A (en) | 1973-01-16 |
DE1924049A1 (en) | 1970-11-12 |
AT302647B (en) | 1972-10-25 |
NL7006539A (en) | 1970-11-12 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PLNP | Patent lapsed through nonpayment of renewal fees |