GB1287396A - Olefin polymerization and a catalyst therefor - Google Patents

Olefin polymerization and a catalyst therefor

Info

Publication number
GB1287396A
GB1287396A GB22661/70A GB2266170A GB1287396A GB 1287396 A GB1287396 A GB 1287396A GB 22661/70 A GB22661/70 A GB 22661/70A GB 2266170 A GB2266170 A GB 2266170A GB 1287396 A GB1287396 A GB 1287396A
Authority
GB
United Kingdom
Prior art keywords
ethylene
reaction product
oic
ticl
isopropanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22661/70A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB1287396A publication Critical patent/GB1287396A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1287396 Polymerization of olefins FARBWERKE HOECHST AG 11 May 1970 [10 May 1969] 22661/70 Heading C3P [Also in Division C2] Ethylene is polymerized, optionally with up to 10% by weight of another alpha-olefin of the formula R-CH = CH 2 wherein R is C 1-13 hydrocarbon, in solution, in suspension or in the gaseous phase, at a temperature of 20-160‹ C. and pressure of up to 20 atmospheres, in the presence of a catalyst comprising (A) the reaction product of a halogen-free magnesium compound containing 0À2-2À0 mols. of hydroxy groups per gram-atom of magnesium with an alcohol, a titanium tetraalcoholate and titanium chloride, and (B) an organoaluminium compound. In the examples:-(a) ethylene is polymerized using (A) the reaction product of Mg(OH) 2 , TiCl 4 , Ti(OiC 3 H 7 ) 4 and isopropanol or isobutanol; and (B) Al(C 2 H 5 ) 3 ; and (b) a copolymer of ethylene and butene-1 is prepared using (A) the reaction product of TiCl 4 , Ti(OiC 3 H 7 ) 4 , isopropanol and the product obtained by treating MgCl 2 .6H 2 O with aqueous NaOH and Na 2 CO 3 and (B) Al(iC 4 Ha) 3 .
GB22661/70A 1969-05-10 1970-05-11 Olefin polymerization and a catalyst therefor Expired GB1287396A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19691924049 DE1924049A1 (en) 1969-05-10 1969-05-10 Process for the polymerization of olefins

Publications (1)

Publication Number Publication Date
GB1287396A true GB1287396A (en) 1972-08-31

Family

ID=5733914

Family Applications (1)

Application Number Title Priority Date Filing Date
GB22661/70A Expired GB1287396A (en) 1969-05-10 1970-05-11 Olefin polymerization and a catalyst therefor

Country Status (9)

Country Link
AT (1) AT302647B (en)
BE (1) BE750239A (en)
CA (1) CA919347A (en)
DE (1) DE1924049A1 (en)
DK (1) DK124136B (en)
FR (1) FR2047568A5 (en)
GB (1) GB1287396A (en)
NL (1) NL7006539A (en)
ZA (1) ZA702245B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2632730A1 (en) * 1975-07-30 1977-02-10 Bp Chem Int Ltd A ZIEGLER CATALYST MOUNTED ON A CARRIER AND THE PROCESS FOR THE PRODUCTION AND USE OF THE SAME
US4665140A (en) * 1982-11-24 1987-05-12 Cities Service Oil & Gas Corp. Process for polymerizing a monomer charge

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2632730A1 (en) * 1975-07-30 1977-02-10 Bp Chem Int Ltd A ZIEGLER CATALYST MOUNTED ON A CARRIER AND THE PROCESS FOR THE PRODUCTION AND USE OF THE SAME
US4256865A (en) 1975-07-30 1981-03-17 Bp Chemicals Limited Polymerization catalyst
USRE30970E (en) 1975-07-30 1982-06-15 Bp Chemicals Limited Polymerization catalyst
US4665140A (en) * 1982-11-24 1987-05-12 Cities Service Oil & Gas Corp. Process for polymerizing a monomer charge

Also Published As

Publication number Publication date
DK124136B (en) 1972-09-18
ZA702245B (en) 1971-03-31
BE750239A (en) 1970-11-12
FR2047568A5 (en) 1971-03-12
CA919347A (en) 1973-01-16
DE1924049A1 (en) 1970-11-12
AT302647B (en) 1972-10-25
NL7006539A (en) 1970-11-12

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees