GB1261199A - Recovery of sulphur dioxide from waste gases - Google Patents
Recovery of sulphur dioxide from waste gasesInfo
- Publication number
- GB1261199A GB1261199A GB5321868A GB5321868A GB1261199A GB 1261199 A GB1261199 A GB 1261199A GB 5321868 A GB5321868 A GB 5321868A GB 5321868 A GB5321868 A GB 5321868A GB 1261199 A GB1261199 A GB 1261199A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphite
- bisulphite
- solution
- separated
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F3/00—Compounds of beryllium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
- C01B17/60—Isolation of sulfur dioxide from gases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Treating Waste Gases (AREA)
Abstract
1,261,199. Recovering sulphur dioxide; sodium, lithium and beryllium, bisulphite and sulphite. WELLMAN POWER GAS Inc. 11 Nov., 1968 [9 Nov., 1967], No. 53218/68. Heading C1A. Sulphur dioxide is separated from a gas containing it, e.g. flue gas, by contacting the gas in a reaction zone, with an aqueous solution of sodium, lithium or beryllium sulphite at a temp., e.g. below 230‹ F., sufficient to react the SO 2 with the solution to give a bisulphite and below the temp. at which the bisulphite decomposes to the sulphite, so as to form an aqueous solution containing unreacted sulphite and the corresponding bisulphite, from which solution the sulphite content is removed by crystallization or, for example, by selective extraction, the bisulphite content of the solution being decomposed, simultaneously with or subsequent to the removal of the sulphite, under conditions of temp., pressure, and residence time such that gaseous SO 2 , water and the corresponding sulphite are produced, when the SO 2 so produced is separated and the sulphite so formed together with that initially separated is recycled to the SO 2 reaction step. Sodium sulphite is the preferred sulphite. In one embodiment, the sulphite/bisulphite solution produced in the first step is treated so that simultaneously it decomposes into SO 2 H 2 O and the corresponding sulphite, the water evaporates, and the sulphite crystallizes from the solution. The decomposition of the bisulphite is preferably performed at a temp. up to 300‹ F., e.g. at 230-300‹ F., under superatmospheric pressure. The crystallized sulphite may be separated from its mother liquor, dissolved in water and recycled to the SO 2 absorbing step. The mother liquor is decomposed to give SO 2 which is separated. The waste gas may contain 0À001 to 5 mole per cent sulphur dioxide and the absorbing liquor may contain 25 to 35% by wt. of dissolved solid, above 55% by weight of which is sulphite. The solution produced by the absorbing step may have a dissolved solids content of 25 to 35 wt. per cent and bisulphite constitutes 50-70% by wt. of its solids content. The Specification describes a particular form of gas/liquid contacting apparatus (Fig. 3, not shown).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US68183367A | 1967-11-09 | 1967-11-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1261199A true GB1261199A (en) | 1972-01-26 |
Family
ID=24737030
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5321868A Expired GB1261199A (en) | 1967-11-09 | 1968-11-11 | Recovery of sulphur dioxide from waste gases |
Country Status (7)
Country | Link |
---|---|
BE (1) | BE723630A (en) |
CA (1) | CA930140A (en) |
CH (1) | CH508410A (en) |
DE (1) | DE1807926C3 (en) |
FR (1) | FR1603249A (en) |
GB (1) | GB1261199A (en) |
NL (1) | NL158143B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NO342799B1 (en) * | 2017-03-24 | 2018-08-06 | Rsss As | Sequential washing tower for exhaust gases |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1557295A (en) * | 1977-07-19 | 1979-12-05 | Davy Powergas Ltd | Removal of sulphur dioxide from gas |
-
1968
- 1968-11-08 CH CH1669268A patent/CH508410A/en not_active IP Right Cessation
- 1968-11-08 CA CA034756A patent/CA930140A/en not_active Expired
- 1968-11-08 BE BE723630D patent/BE723630A/xx not_active IP Right Cessation
- 1968-11-08 NL NL6815982A patent/NL158143B/en not_active IP Right Cessation
- 1968-11-08 FR FR1603249D patent/FR1603249A/fr not_active Expired
- 1968-11-08 DE DE19681807926 patent/DE1807926C3/en not_active Expired
- 1968-11-11 GB GB5321868A patent/GB1261199A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NO342799B1 (en) * | 2017-03-24 | 2018-08-06 | Rsss As | Sequential washing tower for exhaust gases |
NO20170481A1 (en) * | 2017-03-24 | 2018-08-06 | Rsss As | Sequential washing tower for exhaust gases |
Also Published As
Publication number | Publication date |
---|---|
BE723630A (en) | 1969-05-08 |
NL158143B (en) | 1978-10-16 |
NL6815982A (en) | 1969-05-13 |
CA930140A (en) | 1973-07-17 |
DE1807926B2 (en) | 1980-02-28 |
FR1603249A (en) | 1971-03-22 |
DE1807926A1 (en) | 1969-06-26 |
DE1807926C3 (en) | 1980-10-16 |
CH508410A (en) | 1971-06-15 |
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