GB1248656A - Process for the production of microporous sheet structures which are permeable to water vapour - Google Patents
Process for the production of microporous sheet structures which are permeable to water vapourInfo
- Publication number
- GB1248656A GB1248656A GB21932/69A GB2193269A GB1248656A GB 1248656 A GB1248656 A GB 1248656A GB 21932/69 A GB21932/69 A GB 21932/69A GB 2193269 A GB2193269 A GB 2193269A GB 1248656 A GB1248656 A GB 1248656A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solution
- weight
- solvent
- water
- woven
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
1,248,656. Microporous sheets. FARBENFABRIKEN BAYER A.G., and MOBAY CHEMICAL CO. 30 April, 1969 [30 April, 1968], No. 21932/69. Heading B5B. [Also in Divisions B2 and C3] In a process for producing microporous sheets which are permeable to water vapour: (a) 90 to 70 parts by weight of a high molecular weight polyurethane which is free from NCO groups and contains from 6 to 20% by weight of urethane groups and which is produced from precursors having an NCO/OH ratio during synthesis of from 0À99 to 1À15, said polyurethane having a tensile strength of at least 100 kp/cm.<SP>2</SP>, a Shore A hardness of 35 to 85 and a softening point of above 120‹ C., and (b) 10 to 30 parts by weight (solids basis) of a predominantly linear high molecular weight polyurethane which is free from NCO groups and contains 8 to 35% by weight of urethane groups and 0À5 to 2À0% by weight of quaternary ammonium groups, in the form of an aqueous dispersion or colloidal solution, dissolved in (c) 200 to 2000 parts by weight of a water soluble strongly polar solvent for (a), having a boiling point of above 100‹ C., shaping the solution to form a sheet, optionally gelling the solution, treating the solution with water or with a mixture of water and solvent (c) to remove solvent (c) from the solution, and subsequently drying the resulting microporous sheet. An additional low boiling solvent may be used together with solvent (c). Specified low-boiling solvents include acetone, methyl ethyl ketone, tetrahydrofuran, ethyl acetate, methylene dichloride and 1,2-dichloropropane, in proportions of up to 100% by weight of the strongly polar solvent. Preferably the amount of water contained in the solution of (a) and (b) in (c) is below 7% by weight, and at least 2À5% by weight based on the amount of (b) of an anionic synthetic tanning agent may be added to the solution of (a), (b) and (c) prior to gelling. Solvent (c) may be removed by using several mixtures of solvent (c) and water having decreasing solvent content and finally pure water, e.g. by passing the gel through successive baths of such solvents, the gel being squeezed between each bath, and the microporous sheet may be subsequently treated with a solution of a synthetic anionic tanning agent. Shaping is suitably effected by casting, using a porous substrate e.g. wood, split leather, cardboard, paper, woven or unwoven textile sheeting or brickwork, or a non-porous substrate e.g. metal, glass or strips of fabric coated with a synthetic resin e.g. polytetrafluoroethylene. The gelling step is preferably achieved by exposure to moving air at from 10 to 40‹ C. and relative humidity 60 to 99%, especially 80 to 98%, for between 1 and 30 min. depending on the thickness of the solution. Still air may be used to gel the solution but a period of some hours is then necessary. The solutions of the invention may be used to produce laminated materials by spreading on porous or non-porous substrates, e.g. woven and knitted fabrics, fleeces, felts, glass or metal. Films prepared on non-porous substrates may be transferred by the reversing process on to such substrates as wood, split leather, cardboard, paper, woven and non-woven fabrics, brickwork and metal.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1769277A DE1769277C3 (en) | 1968-04-30 | 1968-04-30 | Process for the production of microporous, water-vapor-permeable flat structures based on polyurethane |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1248656A true GB1248656A (en) | 1971-10-06 |
Family
ID=5700076
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB21932/69A Expired GB1248656A (en) | 1968-04-30 | 1969-04-30 | Process for the production of microporous sheet structures which are permeable to water vapour |
Country Status (12)
Country | Link |
---|---|
AT (1) | AT292321B (en) |
BE (1) | BE732387A (en) |
CH (1) | CH522700A (en) |
CS (1) | CS174113B2 (en) |
DE (1) | DE1769277C3 (en) |
ES (1) | ES446257A3 (en) |
FR (1) | FR2007314A1 (en) |
GB (1) | GB1248656A (en) |
NL (1) | NL6906597A (en) |
PL (1) | PL80137B1 (en) |
RO (1) | RO58319A (en) |
SE (1) | SE361050B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4728542A (en) * | 1985-06-19 | 1988-03-01 | Bayer Aktiengesellschaft | Ionically modified pur spreading pastes and their use |
US4743470A (en) * | 1985-03-02 | 1988-05-10 | Bayer Aktiengesellschaft | Spreading pastes containing polyurethane plastics and a process for the production of polyurethane coatings permeable to water vapor |
US5177141A (en) * | 1988-10-22 | 1993-01-05 | Bayer Aktiengesellschaft | Coating materials containing pur dispersions and solvents and their use for the preparation of water vapor permeable pur coatings |
CN113652872A (en) * | 2021-09-07 | 2021-11-16 | 中国科学院兰州化学物理研究所 | Emergency lubricating oil core material and preparation method thereof, oil-containing emergency lubricating oil core material and preparation method and application thereof |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5314601B2 (en) * | 1972-09-04 | 1978-05-18 | ||
DE2522019C2 (en) * | 1974-11-01 | 1983-03-10 | Chemie-Anlagenbau Bischofsheim GmbH, 4500 Osnabrück | Process for the production of finished and / or irreversibly embossed microporous flat structures |
DE2754603A1 (en) * | 1977-12-08 | 1979-06-13 | Bayer Ag | PROCESS FOR THE SOLVENT-FREE COATING OF SUBSTRATES |
-
1968
- 1968-04-30 DE DE1769277A patent/DE1769277C3/en not_active Expired
-
1969
- 1969-04-11 AT AT353369A patent/AT292321B/en not_active IP Right Cessation
- 1969-04-19 RO RO59779A patent/RO58319A/ro unknown
- 1969-04-28 CS CS3006A patent/CS174113B2/cs unknown
- 1969-04-29 PL PL1969133284A patent/PL80137B1/pl unknown
- 1969-04-29 CH CH662369A patent/CH522700A/en not_active IP Right Cessation
- 1969-04-29 SE SE06113/69*A patent/SE361050B/xx unknown
- 1969-04-29 NL NL6906597A patent/NL6906597A/xx unknown
- 1969-04-30 BE BE732387D patent/BE732387A/xx unknown
- 1969-04-30 FR FR6913818A patent/FR2007314A1/fr not_active Withdrawn
- 1969-04-30 GB GB21932/69A patent/GB1248656A/en not_active Expired
-
1976
- 1976-03-22 ES ES446257A patent/ES446257A3/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4743470A (en) * | 1985-03-02 | 1988-05-10 | Bayer Aktiengesellschaft | Spreading pastes containing polyurethane plastics and a process for the production of polyurethane coatings permeable to water vapor |
US4728542A (en) * | 1985-06-19 | 1988-03-01 | Bayer Aktiengesellschaft | Ionically modified pur spreading pastes and their use |
US5177141A (en) * | 1988-10-22 | 1993-01-05 | Bayer Aktiengesellschaft | Coating materials containing pur dispersions and solvents and their use for the preparation of water vapor permeable pur coatings |
CN113652872A (en) * | 2021-09-07 | 2021-11-16 | 中国科学院兰州化学物理研究所 | Emergency lubricating oil core material and preparation method thereof, oil-containing emergency lubricating oil core material and preparation method and application thereof |
CN113652872B (en) * | 2021-09-07 | 2022-04-29 | 中国科学院兰州化学物理研究所 | Emergency lubricating oil core material and preparation method thereof, oil-containing emergency lubricating oil core material and preparation method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
CH522700A (en) | 1972-06-30 |
DE1769277A1 (en) | 1971-11-18 |
BE732387A (en) | 1969-10-01 |
NL6906597A (en) | 1969-11-03 |
SE361050B (en) | 1973-10-15 |
AT292321B (en) | 1971-08-25 |
DE1769277C3 (en) | 1975-01-09 |
PL80137B1 (en) | 1975-08-30 |
ES446257A3 (en) | 1977-06-16 |
CS174113B2 (en) | 1977-03-31 |
RO58319A (en) | 1975-09-15 |
DE1769277B2 (en) | 1973-11-08 |
FR2007314A1 (en) | 1970-01-02 |
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