GB1247351A - Electrolytic polymerization of aromatic compounds - Google Patents

Electrolytic polymerization of aromatic compounds

Info

Publication number
GB1247351A
GB1247351A GB56580/68A GB5658068A GB1247351A GB 1247351 A GB1247351 A GB 1247351A GB 56580/68 A GB56580/68 A GB 56580/68A GB 5658068 A GB5658068 A GB 5658068A GB 1247351 A GB1247351 A GB 1247351A
Authority
GB
United Kingdom
Prior art keywords
aromatic compounds
alcl
volts
electrolytic polymerization
maintaining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB56580/68A
Inventor
Norvell Edwin Wisdom Jr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1247351A publication Critical patent/GB1247351A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/10—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aromatic carbon atoms, e.g. polyphenylenes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

1,247,351. Electrolytic polymerization of aromatic compounds. ESSO RESEARCH & ENG. CO. 28 Nov., 1968 [11 Dec., 1967], No. 56580/68. Heading C5E. [Also in Division C7] To provide a more uniform process providing a high current efficiency the process of Specification 1,136,699 for preparing polymeric aromatic compounds is modified by including in the electrolysed solution comprising a C 6 to C 20 aromatic compound and a ternary complex R : HX: 2AlX 3 , where R is the same or another more basic C 6 to C 20 aromatic compound and X is Cl or Br, free AlCl 3 present at least in saturation amount and maintaining the anode potential (vs. a saturated Cu: CuCl 2 electrode) at 1À15 volts for 2 to 10 minutes initially and then reducing it to 1À05 to 1À10 volts for the remainder of the process. This voltage sequence may be effected by maintaining a current density of 8 to 9 mA/sq.cm. Solid AlCl 3 may be confined within a porous chamber to maintain the presence of free AlCl 3 , permitting continuous operation.
GB56580/68A 1967-12-11 1968-11-28 Electrolytic polymerization of aromatic compounds Expired GB1247351A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US68935067A 1967-12-11 1967-12-11

Publications (1)

Publication Number Publication Date
GB1247351A true GB1247351A (en) 1971-09-22

Family

ID=24768061

Family Applications (1)

Application Number Title Priority Date Filing Date
GB56580/68A Expired GB1247351A (en) 1967-12-11 1968-11-28 Electrolytic polymerization of aromatic compounds

Country Status (4)

Country Link
US (1) US3437570A (en)
DE (1) DE1813486A1 (en)
FR (1) FR1594352A (en)
GB (1) GB1247351A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3862841A (en) * 1966-10-20 1975-01-28 Xerox Corp Polymerization imaging by charge injection from a photoconductive layer
DE3034988A1 (en) * 1980-09-17 1982-04-29 Basf Ag, 6700 Ludwigshafen METHOD FOR THE PRODUCTION OF ELECTRICALLY CONDUCTIVE POLYAROMATS AND THEIR USE IN ELECTROTECHNICS AND FOR THE ANTISTATIC EQUIPMENT OF PLASTICS
DE4411024A1 (en) * 1994-03-30 1995-12-21 Hoechst Ag Process for the preparation of 4,4'-dimethyl-1,1'-binaphthyl
RU2518122C2 (en) 2008-02-08 2014-06-10 Лист Холдинг АГ Method and device for production of formed products

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3386899A (en) * 1963-11-29 1968-06-04 Hooker Chemical Corp Electrolytic production of aromatic condensation products
US3335075A (en) * 1964-08-10 1967-08-08 Gen Electric Electrolytic polymerization of phenol

Also Published As

Publication number Publication date
US3437570A (en) 1969-04-08
FR1594352A (en) 1970-06-01
DE1813486A1 (en) 1969-07-24

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees