GB1223682A - Mineral separation - Google Patents
Mineral separationInfo
- Publication number
- GB1223682A GB1223682A GB8795/67A GB879567A GB1223682A GB 1223682 A GB1223682 A GB 1223682A GB 8795/67 A GB8795/67 A GB 8795/67A GB 879567 A GB879567 A GB 879567A GB 1223682 A GB1223682 A GB 1223682A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkali metal
- carbonates
- carbonate
- iii
- soluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000926 separation method Methods 0.000 title abstract 3
- 229910052500 inorganic mineral Inorganic materials 0.000 title 1
- 239000011707 mineral Substances 0.000 title 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 4
- 229910052684 Cerium Inorganic materials 0.000 abstract 3
- 229910052776 Thorium Inorganic materials 0.000 abstract 3
- 229910000288 alkali metal carbonate Inorganic materials 0.000 abstract 3
- 150000008041 alkali metal carbonates Chemical class 0.000 abstract 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 3
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 229910052727 yttrium Inorganic materials 0.000 abstract 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 abstract 2
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 1
- -1 Thorium alkali metal Chemical class 0.000 abstract 1
- 229910052769 Ytterbium Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F15/00—Compounds of thorium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/30—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Cephalosporin Compounds (AREA)
Abstract
1,223,682. Separation of Thorium, Cerium, Ytterbium and Yttrium. W. J. REYNOLDS HOLDINGS Ltd. 15 Feb., 1968 [23 Feb., 1967], No. 8795/67. Heading C1A. The separation of Th from Ce<SP>IV</SP> or Yb<SP>III</SP> from Y is effected by the preparation of their alkali metal double carbonates and crystallization thereof in alkali metal carbonate solution. To separate Thorium it is preferable that the starting material contains water-soluble Th compounds and light rare earths (i.e. elements with atomic nos. 57-63 inclusive) and only a minor proportion of Y. This can be achieved by the method as in Specification 1,223,683. Any Cerium present is oxidized to the Ce<SP>IV</SP> state. The water-solubles from the process are converted to carbonates and the soluble carbonates dissolved in alkali metal carbonate solution, insoluble carbonates removed and solution treated to reduce Ce<SP>IV</SP> to Ce<SP>III</SP> which is removed. Thorium alkali metal double carbonate is crystallized out. Cerium is separated by oxidizing the pptd Ce<SP>III</SP> carbonate and then forming double carbonate as with Th. Yttrium is separated from materials containing water-soluble Y compounds, preferably with very low Yb content so that reduction to Yb<SP>II</SP> is unnecessary. The alkali metal carbonate solution is used at concas, greater than 10%. The double carbonate may be converted to oxalate or nitrate and then to the oxide.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8795/67A GB1223682A (en) | 1967-02-23 | 1967-02-23 | Mineral separation |
| FR1555149D FR1555149A (en) | 1967-02-23 | 1968-02-22 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8795/67A GB1223682A (en) | 1967-02-23 | 1967-02-23 | Mineral separation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1223682A true GB1223682A (en) | 1971-03-03 |
Family
ID=9859401
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8795/67A Expired GB1223682A (en) | 1967-02-23 | 1967-02-23 | Mineral separation |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR1555149A (en) |
| GB (1) | GB1223682A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0324276A2 (en) * | 1987-12-23 | 1989-07-19 | Pirelli Cabos S/A | Synthesis of superconductors from xenotyme |
-
1967
- 1967-02-23 GB GB8795/67A patent/GB1223682A/en not_active Expired
-
1968
- 1968-02-22 FR FR1555149D patent/FR1555149A/fr not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0324276A2 (en) * | 1987-12-23 | 1989-07-19 | Pirelli Cabos S/A | Synthesis of superconductors from xenotyme |
| EP0324276A3 (en) * | 1987-12-23 | 1991-04-10 | Pirelli Cabos S/A | Synthesis of superconductors from xenotyme |
| EP0464965A2 (en) * | 1987-12-23 | 1992-01-08 | Pirelli Cabos S/A | Synthesis of superconductors from xenotyme |
| EP0464965A3 (en) * | 1987-12-23 | 1992-07-15 | Pirelli S/A Companhia Industrial Brasileira | Synthesis of superconductors from xenotyme |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1555149A (en) | 1969-01-24 |
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