GB1220105A - Catalyst preparation - Google Patents

Catalyst preparation

Info

Publication number
GB1220105A
GB1220105A GB07620/68A GB1762068A GB1220105A GB 1220105 A GB1220105 A GB 1220105A GB 07620/68 A GB07620/68 A GB 07620/68A GB 1762068 A GB1762068 A GB 1762068A GB 1220105 A GB1220105 A GB 1220105A
Authority
GB
United Kingdom
Prior art keywords
silica
aqueous medium
urea
carrier material
medium containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB07620/68A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stamicarbon BV
Original Assignee
Stamicarbon BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stamicarbon BV filed Critical Stamicarbon BV
Publication of GB1220105A publication Critical patent/GB1220105A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/755Nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18Arsenic, antimony or bismuth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/26Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/28Molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/745Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/882Molybdenum and cobalt
    • B01J35/393
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/031Precipitation
    • B01J37/035Precipitation on carriers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063Titanium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica

Abstract

1,220,105. Inorganic oxides. STAMICARBON N.V. 11 April, 1968 [14 April, 1967; 31 Aug., 1967], No. 17620/68. Headings C1A and C1N. [Also in Divisions B1 C2 and C5] A supported metal-containing catalyst is prepared by a process which comprises pre- 'paring an aqueous medium comprising a soluble compound of a catalytic metal in solution and particulate carrier material in the solid phase e.g. alumina, titania or, silica, which compound forms a precipitate of catalytically-active material or precursor therefor on reaction with a hydroxyl ion, agitating the medium thereby to obtain a suspension of the carrier material, making available hydroxyl ions in the agitated suspension by an in situ generation of hydroxyl ions thereby to form a precipitate of catalytically-active material or precursor therefor, the rate at which the hydroxyl ions are made available being controlled at such a low rate that the precipitate is formed on the carrier material and not in the body of the aqueous medium and the agitation being controlled so that the concentration of hydroxyl ions is uniform throughout the aqueous medium thereby to provide a homogeneous distribution of precipitate in finely divided form on the carrier material, separating carrier material loaded with precipitate from the aqueous medium, and drying the separated carrier material loaded with precipitate to provide a catalyst which subsequently may be moulded to form artefacts having a predetermined shape and size. The artefacts may include thermostable filler material. The catalyst and/or the artefacts moulded therefrom may be calcined; alternatively or subsequently, the catalyst and/or the artefacts moulded therefrom may be heated under reducing conditions, for example in a stream of hydrogen. The catalytically-active material supported by the carrier material preferably has a particle size not greater than 50 Š; the weight ratio of catalytically-active material to carrier material may be between 0À1 to 1 and 3 to 1 and preferably is not more than 2 to 1. The hydroxyl ions may be made available by the provision in the aqueous medium of urea and/or nitrite ions, which nitrite ions may be provided by the use of a nitrite as the soluble compound of the catalytic metal; alternatively, such soluble compound may be a chloride, a nitrate or a sulphate. The carrier material, preferably has a specific surface area of about 150 m.<SP>2</SP>/g. The catalytic metal may be tin, lead, vanadium, antimony, bismuth, chromium, uranium, manganese, iron, cobalt or nickel and may be present in the form of elemental metal or an oxide thereof; the catalyst may contain two or more catalytic metals or oxides thereof which may be in the form of a salt, for example a vanadate, a molybdate or a tungstate. Catalysts referred to include silica-elemental nickel obtained by reduction, for example with hydrogen, of a silicanickel oxide catalyst precursor prepared from an aqueous medium containing silica, nickel nitrate, sodium nitrite and urea (Example 1) or silica, nickel nitrate and urea (Example 2) or silica, nickel nitrate and sodium nitrite (Example 10); silica-bismuth oxide prepared from an aqueous medium containing silica, bismuth nitrate and urea (Example 3); silica-cobalt molybdate prepared from an aqueous medium containing silica, cobalt nitrate, ammonium molybdate and urea (Example 4); silicachromium oxide prepared from an aqueous medium containing silica, chromium nitrate and urea (Example 5); silica-stannic oxide prepared from an aqueous medium containing silica, stannic chloride and urea (Example 6) silicaplatinum prepared from an aqueous medium containing silica chloroplatinic acid and urea (Example 7); titania-nickel oxide prepared from an aqueous medium containing titania, nickel nitrate and urea (Example 8); and silica-ferric oxide prepared from an aqueous medium containing silica, ferrous chloride and urea (Example 9). The silica used is a commerciallyavailable highly-porous silica obtained from silicon tetrachloride by flame hydrolysis.
GB07620/68A 1967-04-14 1968-04-11 Catalyst preparation Expired GB1220105A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL676705259A NL143139B (en) 1967-04-14 1967-04-14 PROCESS FOR PREPARING A CARRIER CATALYST BY TREATING A CARRIER WITH A SOLUTION OF A SALT OF A CATALYTIC ACTIVE ELEMENT.
NL676712004A NL145778B (en) 1967-04-14 1967-08-31 IMPROVEMENT OF A METHOD FOR PREPARING A CATALYST.

Publications (1)

Publication Number Publication Date
GB1220105A true GB1220105A (en) 1971-01-20

Family

ID=26644180

Family Applications (1)

Application Number Title Priority Date Filing Date
GB07620/68A Expired GB1220105A (en) 1967-04-14 1968-04-11 Catalyst preparation

Country Status (11)

Country Link
JP (1) JPS502398B1 (en)
AT (1) AT289040B (en)
BE (1) BE713656A (en)
CH (1) CH517522A (en)
DE (1) DE1767202C3 (en)
DK (1) DK124925B (en)
ES (1) ES352710A1 (en)
FR (1) FR1569895A (en)
GB (1) GB1220105A (en)
NL (2) NL143139B (en)
SE (1) SE345393B (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3853791A (en) * 1973-02-06 1974-12-10 American Cyanamid Co Oxide and molybdenum oxide on an alumina support and catalyst obtained
US4073750A (en) * 1976-05-20 1978-02-14 Exxon Research & Engineering Co. Method for preparing a highly dispersed supported nickel catalyst
US4077912A (en) * 1972-10-12 1978-03-07 Standard Oil Company Catalysts useful for exothermic reactions
US4113658A (en) * 1967-04-14 1978-09-12 Stamicarbon, N.V. Process for homogeneous deposition precipitation of metal compounds on support or carrier materials
EP0044117A2 (en) * 1980-07-16 1982-01-20 Dyson Refractories Limited Catalyst
EP0044118A2 (en) * 1980-07-16 1982-01-20 Dyson Refractories Limited A method of preparing a catalyst
US4478800A (en) * 1981-08-07 1984-10-23 Veg Gasinstituut N.V. Process for removal of sulfur compounds from gases
US4629612A (en) * 1982-07-30 1986-12-16 Veg-Gasinstituut N.V. Reaction mass, method for the manufacture thereof and use thereof
US4657888A (en) * 1983-12-31 1987-04-14 Veg-Gasinstituut N.V. Process for the production of a catalyst
US4725573A (en) * 1983-12-31 1988-02-16 Veg-Gasinstituut, N.V. Copper-nickel catalyst and process for its production
EP1101734A2 (en) * 1999-11-19 2001-05-23 Praxair Technology, Inc. Purification of argon
WO2005056164A1 (en) * 2003-12-05 2005-06-23 Jayalekshmy Ayyer A catalyst useful for h2s removal from gas stream preparation thereof and use thereof
CN1662300B (en) * 2002-06-21 2010-04-14 Isis创新有限公司 Catalyst
US9216402B2 (en) 2012-11-06 2015-12-22 H R D Corporation Reactor and catalyst for converting natural gas to organic compounds
US10626064B2 (en) 2018-05-30 2020-04-21 Exxonmobil Chemical Patents Inc. Processes to make neopentane using shell and tube reactors
CN112619659A (en) * 2020-12-18 2021-04-09 齐鲁工业大学 Nickel oxide nanosheet and bismuth molybdate nanofiber heterojunction photocatalytic material as well as preparation method and application thereof
US10994264B2 (en) 2018-05-30 2021-05-04 Exxonmobil Chemical Patents Inc. Catalysts and processes for making catalysts for producing neopentane

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1573174A (en) * 1968-04-10 1969-07-04
LU57716A1 (en) * 1968-12-30 1970-07-01
LU58391A1 (en) * 1969-04-09 1970-11-09
NL7703762A (en) * 1977-04-06 1978-10-10 Stamicarbon PROCEDURE FOR PREPARING CATALYST ON SUPPORT SYSTEMS.
HU177860B (en) * 1979-05-22 1982-01-28 Mta Koezponti Hivatala Method for producing carrier metal catalyzers
DE3131255C2 (en) * 1981-08-07 1986-02-13 VEG-Gasinstituut N.V., Apeldoorn Process for the preparation of a ferric oxide catalyst or absorbent
NL8200544A (en) * 1982-02-12 1983-09-01 Veg Gasinstituut Nv METHOD FOR PREPARING METHANE FROM CARBON MONOXIDE-CONTAINING GAS MIXTURES USING CATALYSTS USING NICKEL
DE3228482C2 (en) * 1982-07-30 1986-09-11 VEG-Gasinstituut N.V., Apeldoorn Process for the reaction of carbon monoxide with water vapor to form carbon dioxide and hydrogen and the use of a catalyst therefor
GB2144446A (en) * 1983-08-04 1985-03-06 Veg Gasinstituut Nv Process for the production of methane rich gases
SE8400426L (en) * 1984-01-30 1985-07-31 Eka Ab SET TO MAKE FINE PARTICLES WITH A COATING OF METAL OR METAL COMPOUND, SPECIFICALLY A CATALYTIC ACTIVE SUBSTANCE
BR8504994A (en) * 1984-01-30 1986-01-21 Eka Ab LOAD OR SUPPORT FOR CATALYTICALLY ACTIVE SUBSTANCES, A PROCESS TO PRODUCE THAT LOAD OR SUPPORT, A CATALYST PRODUCED FROM THAT SUPPORT, AND THE USE OF THAT CATALYST
SE8402916L (en) * 1984-01-30 1985-07-31 Eka Ab CATALYTIC EXHAUST CLEANER AND WAY TO MAKE IT
DE10054457A1 (en) * 2000-11-03 2002-05-08 Sued Chemie Ag Catalyst for oxidation of methane to formaldehyde and methanol comprises a silica support having a specified iron content
JP7194629B2 (en) * 2019-03-29 2022-12-22 日揮触媒化成株式会社 Nickel catalyst and its production method

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4113658A (en) * 1967-04-14 1978-09-12 Stamicarbon, N.V. Process for homogeneous deposition precipitation of metal compounds on support or carrier materials
US4077912A (en) * 1972-10-12 1978-03-07 Standard Oil Company Catalysts useful for exothermic reactions
US3853791A (en) * 1973-02-06 1974-12-10 American Cyanamid Co Oxide and molybdenum oxide on an alumina support and catalyst obtained
US4073750A (en) * 1976-05-20 1978-02-14 Exxon Research & Engineering Co. Method for preparing a highly dispersed supported nickel catalyst
EP0044117A2 (en) * 1980-07-16 1982-01-20 Dyson Refractories Limited Catalyst
EP0044118A2 (en) * 1980-07-16 1982-01-20 Dyson Refractories Limited A method of preparing a catalyst
EP0044117A3 (en) * 1980-07-16 1982-01-27 Dyson Refractories Limited Catalyst
EP0044118A3 (en) * 1980-07-16 1982-01-27 Dyson Refractories Limited A method of preparing a catalyst
US4522940A (en) * 1980-07-16 1985-06-11 Dyson Refractories Limited Method of preparing a catalyst and catalyst prepared by the method
US4478800A (en) * 1981-08-07 1984-10-23 Veg Gasinstituut N.V. Process for removal of sulfur compounds from gases
US4629612A (en) * 1982-07-30 1986-12-16 Veg-Gasinstituut N.V. Reaction mass, method for the manufacture thereof and use thereof
US4657888A (en) * 1983-12-31 1987-04-14 Veg-Gasinstituut N.V. Process for the production of a catalyst
US4725573A (en) * 1983-12-31 1988-02-16 Veg-Gasinstituut, N.V. Copper-nickel catalyst and process for its production
EP1101734A2 (en) * 1999-11-19 2001-05-23 Praxair Technology, Inc. Purification of argon
EP1101734A3 (en) * 1999-11-19 2003-01-15 Praxair Technology, Inc. Purification of argon
CN1662300B (en) * 2002-06-21 2010-04-14 Isis创新有限公司 Catalyst
WO2005056164A1 (en) * 2003-12-05 2005-06-23 Jayalekshmy Ayyer A catalyst useful for h2s removal from gas stream preparation thereof and use thereof
US9216402B2 (en) 2012-11-06 2015-12-22 H R D Corporation Reactor and catalyst for converting natural gas to organic compounds
US10626064B2 (en) 2018-05-30 2020-04-21 Exxonmobil Chemical Patents Inc. Processes to make neopentane using shell and tube reactors
US10994264B2 (en) 2018-05-30 2021-05-04 Exxonmobil Chemical Patents Inc. Catalysts and processes for making catalysts for producing neopentane
CN112619659A (en) * 2020-12-18 2021-04-09 齐鲁工业大学 Nickel oxide nanosheet and bismuth molybdate nanofiber heterojunction photocatalytic material as well as preparation method and application thereof
CN112619659B (en) * 2020-12-18 2022-09-16 齐鲁工业大学 Nickel oxide nanosheet and bismuth molybdate nanofiber heterojunction photocatalytic material as well as preparation method and application thereof

Also Published As

Publication number Publication date
NL145778B (en) 1975-05-15
BE713656A (en) 1968-10-14
DE1767202A1 (en) 1971-03-18
AT289040B (en) 1971-03-25
DE1767202C3 (en) 1975-05-22
JPS502398B1 (en) 1975-01-25
ES352710A1 (en) 1970-04-16
NL6712004A (en) 1969-03-04
CH517522A (en) 1972-01-15
SE345393B (en) 1972-05-29
NL6705259A (en) 1968-10-15
DE1767202B2 (en) 1974-09-05
DK124925B (en) 1972-12-11
NL143139B (en) 1974-09-16
FR1569895A (en) 1969-06-06

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