GB1191741A - Improvements relating to new Reactive Heavy Metal-containing Formazane Dyestuffs, and their use - Google Patents

Improvements relating to new Reactive Heavy Metal-containing Formazane Dyestuffs, and their use

Info

Publication number
GB1191741A
GB1191741A GB3343467A GB3343467A GB1191741A GB 1191741 A GB1191741 A GB 1191741A GB 3343467 A GB3343467 A GB 3343467A GB 3343467 A GB3343467 A GB 3343467A GB 1191741 A GB1191741 A GB 1191741A
Authority
GB
United Kingdom
Prior art keywords
formula
heavy metal
radical
substituent
formazane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3343467A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
JR Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JR Geigy AG filed Critical JR Geigy AG
Publication of GB1191741A publication Critical patent/GB1191741A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/002—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the linkage of the reactive group being alternatively specified
    • C09B62/018—Formazane dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/002—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the linkage of the reactive group being alternatively specified
    • C09B62/006—Azodyes
    • C09B62/0068—Azodyes dyes containing in the molecule at least one azo group and at least one other chromophore group
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
    • C09B62/20—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a pyrimidine ring
    • C09B62/205—Specific dyes not provided for in groups C09B62/22 - C09B62/26

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

1,191,741. Reactive dyes. J. R. GEIGY A.G. 20 July, 1967 [21 July, 1966], No. 33434/67. Heading C4P. The invention comprises reactive, heavy metal-containing formazane dyestuffs of Formula I wherein A represents the radical of a diazo component which has a substituent X in the o-position to the azo bond; X represents a metal-binding substituent; R represents an optionally substituted aliphatic hydrocarbon radical, a cycloaliphatic radical or a carbocyclic-aromatic or heterocyclic-aromatic radical; R<SP>1</SP> represents hydrogen or a C 1-5 alkyl.group; Y represents an acyl radical which forms at least one covalent bond with the substrate under dyeing conditions; Z represents a salt-forming, water-solubilizing group which dissociates acid in neutral water. Me represents a heavy metal of the atomic numbers 24 to 30, and m represents a positive whole number of at most 7 by coupling the diazonium compound of an amine X<SP>1</SP>-A-NH 2 , wherein A has the meaning for Formula I, and X<SP>1</SP> represents a metallizable group or a substituent which can be converted thereto during metallization with a coupling component of Formula III wherein Y, R<SP>1</SP> and R have the meanings given for Formula I, and Q represents hydrogen or a substituent which can be replaced by azo coupling to form a formazane dyestuff of Formula IV wherein A, R, R<SP>1</SP>, Y, Z and m have the meanings given for Formula I, and X<SP>1</SP> has that given for Formula II, the components being so chosen that the formazane dyestuff of Formula IV contains at most six Z groups, and reacting the formazane dyestuff obtained of Formula IV simultaneously or subsequently with an agent introducing a heavy metal Me to form a formazane dyestuff of Formula I. The dyes may be used to colour wool, silk, synthetic polyamides and polyurethanes and, in particular, cellulose fibres in green and blue shades.
GB3343467A 1966-07-21 1967-07-20 Improvements relating to new Reactive Heavy Metal-containing Formazane Dyestuffs, and their use Expired GB1191741A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH1058266A CH484996A (en) 1966-07-21 1966-07-21 Process for the production of formazan dyes containing heavy metals

Publications (1)

Publication Number Publication Date
GB1191741A true GB1191741A (en) 1970-05-13

Family

ID=4364729

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3343467A Expired GB1191741A (en) 1966-07-21 1967-07-20 Improvements relating to new Reactive Heavy Metal-containing Formazane Dyestuffs, and their use

Country Status (6)

Country Link
BE (1) BE701656A (en)
CH (1) CH484996A (en)
DE (1) DE1794395A1 (en)
ES (1) ES343250A1 (en)
GB (1) GB1191741A (en)
NL (1) NL6710087A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH501713A (en) * 1968-01-29 1971-01-15 Ciba Geigy Ag Process for the production of fiber-reactive, heavy metal-containing formazan dyes
FR2000895B2 (en) * 1968-01-29 1974-02-22 Geigy Ag J R

Also Published As

Publication number Publication date
DE1644258B2 (en) 1975-07-31
DE1644258A1 (en) 1970-07-09
NL6710087A (en) 1968-01-22
CH484996A (en) 1970-01-31
DE1794395A1 (en) 1974-08-29
BE701656A (en) 1968-01-22
ES343250A1 (en) 1968-10-01

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Legal Events

Date Code Title Description
PS Patent sealed
PLE Entries relating assignments, transmissions, licences in the register of patents
PE20 Patent expired after termination of 20 years