GB1174148A - Method of producing Acrylic and Methacrylic Esters - Google Patents

Method of producing Acrylic and Methacrylic Esters

Info

Publication number
GB1174148A
GB1174148A GB3707067A GB3707067A GB1174148A GB 1174148 A GB1174148 A GB 1174148A GB 3707067 A GB3707067 A GB 3707067A GB 3707067 A GB3707067 A GB 3707067A GB 1174148 A GB1174148 A GB 1174148A
Authority
GB
United Kingdom
Prior art keywords
acrylic
hydric
methacrylic esters
esters
och
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3707067A
Inventor
Friziyan Nikolaevich Bondarjuk
Mikhail Alexeevich Korshunov
Vadim Emmanuilovich Lazariants
Valentin Mikhailovich Melekhov
Valery Solomonovich Mikhlin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NII MONOMEROV DLYA SINT KAUCHU
Original Assignee
NII MONOMEROV DLYA SINT KAUCHU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NII MONOMEROV DLYA SINT KAUCHU filed Critical NII MONOMEROV DLYA SINT KAUCHU
Priority to GB3707067A priority Critical patent/GB1174148A/en
Publication of GB1174148A publication Critical patent/GB1174148A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,174,148. Acrylic and methacrylic esters. NAUCHNO ISSLEDOVATELSKY INSTITUT MONOMEROV DLYA SINTETICHESKOGO KAUCHUKA. 11 Aug., 1967, No. 37070/67. Heading C2C. Acrylic and methacrylic esters of monohydric and poly-hydric alcohols and aminoalcohols are prepared by heating a C 1-2 alkyl ester of acrylic or methacrylic acid with a C 4-16 mono-hydric or poly-hydric alcohol or aminoalcohol in the presence of an alkaline earth metal or an alcoholate thereof as catalyst. The preferred catalysts are Mg, Mg(OCH 3 ) 2 , Mg(OC 2 H 5 ) 2 , Mg(OC 3 H 7 ) 2 , Ca and Ca(OC 2 H 5 ) 2 . In examples, methyl methacrylate is heated with (1) n-butyl alcohol, (2) 2-dimethylaminoethanol and (3) diethylene glycol using Mg(OCH 3 ) 2 as catalyst to yield n-butyl methacrylate, 2 - dimethylaminoethyl methacrylate and diethylene glycol dimethacrylate respectively, and many other esters are tabulated.
GB3707067A 1967-08-11 1967-08-11 Method of producing Acrylic and Methacrylic Esters Expired GB1174148A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3707067A GB1174148A (en) 1967-08-11 1967-08-11 Method of producing Acrylic and Methacrylic Esters

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3707067A GB1174148A (en) 1967-08-11 1967-08-11 Method of producing Acrylic and Methacrylic Esters

Publications (1)

Publication Number Publication Date
GB1174148A true GB1174148A (en) 1969-12-10

Family

ID=10393493

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3707067A Expired GB1174148A (en) 1967-08-11 1967-08-11 Method of producing Acrylic and Methacrylic Esters

Country Status (1)

Country Link
GB (1) GB1174148A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0160427A2 (en) * 1984-04-25 1985-11-06 Ciba Specialty Chemicals Water Treatments Limited Alcoholysis of esters and metal alcoholates used in this process
EP0240094A2 (en) * 1986-01-06 1987-10-07 The Dow Chemical Company Process for preparing isocyanatoalkyl esters
EP0365777A1 (en) * 1988-10-22 1990-05-02 Degussa Aktiengesellschaft Process for the preparation of high boiling acrylates or methacrylates
EP1663948A1 (en) * 2003-09-05 2006-06-07 Taminco N.V. Process for the preparation of (meth)acrylate di-ammonium salts and their use as monomers for the synthesis of polymers
US8518129B2 (en) 2009-05-25 2013-08-27 Shell Oil Company Gasoline compositions
US8741002B2 (en) 2009-05-25 2014-06-03 Shell Oil Company Gasoline compositions
US11098150B2 (en) 2010-09-22 2021-08-24 The Board Of Regents Of The University Of Texas System Block copolymer and micelle compositions and methods of use thereof
US11786464B2 (en) 2020-04-24 2023-10-17 The Board Of Regents Of The University Of Texas System PH responsive block copolymer compositions and micelles that inhibit MCT 1 and related proteins

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0160427A2 (en) * 1984-04-25 1985-11-06 Ciba Specialty Chemicals Water Treatments Limited Alcoholysis of esters and metal alcoholates used in this process
EP0160427A3 (en) * 1984-04-25 1986-06-25 Allied Colloids Limited Alcoholysis of esters and metal alcoholates used in this process
EP0240094A2 (en) * 1986-01-06 1987-10-07 The Dow Chemical Company Process for preparing isocyanatoalkyl esters
EP0240094A3 (en) * 1986-01-06 1987-12-02 The Dow Chemical Company Process for preparing isocyanatoalkyl esters
EP0365777A1 (en) * 1988-10-22 1990-05-02 Degussa Aktiengesellschaft Process for the preparation of high boiling acrylates or methacrylates
EP1663948A1 (en) * 2003-09-05 2006-06-07 Taminco N.V. Process for the preparation of (meth)acrylate di-ammonium salts and their use as monomers for the synthesis of polymers
US7799944B2 (en) 2003-09-05 2010-09-21 Taminco N.V. Process for the preparation of (meth)acrylate di-ammonium salts and their use as monomers for the synthesis of polymers
US8518129B2 (en) 2009-05-25 2013-08-27 Shell Oil Company Gasoline compositions
US8741002B2 (en) 2009-05-25 2014-06-03 Shell Oil Company Gasoline compositions
US11098150B2 (en) 2010-09-22 2021-08-24 The Board Of Regents Of The University Of Texas System Block copolymer and micelle compositions and methods of use thereof
US11786464B2 (en) 2020-04-24 2023-10-17 The Board Of Regents Of The University Of Texas System PH responsive block copolymer compositions and micelles that inhibit MCT 1 and related proteins

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees