GB1120457A - Polymerization process - Google Patents
Polymerization processInfo
- Publication number
- GB1120457A GB1120457A GB5027965A GB5027965A GB1120457A GB 1120457 A GB1120457 A GB 1120457A GB 5027965 A GB5027965 A GB 5027965A GB 5027965 A GB5027965 A GB 5027965A GB 1120457 A GB1120457 A GB 1120457A
- Authority
- GB
- United Kingdom
- Prior art keywords
- pentadiene
- polymerization
- isoprene
- diene
- silica
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Polymers of an unsymmetrical conjugated diolefin in which the units are predominantly 3,4, are made by effecting the polymerization of the diene at a temperature of from 0 DEG to 100 DEG C. and a pressure from atmospheric to 100 atmospheres in the presence of a catalyst comprising sodium and/or potassium disposed on a precalcined adsorptive solid support having a surface area of from about 25 to 500 square metres per gram. Specified dienes are isoprene, 1,3 - pentadiene, 2 - methyl - 1,3 - pentadiene, 2,3 - dimethyl - 1,3 - pentadiene or 2 - ethyl - 1,3-butadiene. Preferred supports are crystalline aluminas, charcoal, magnesia, silica-aluminas, and silica - alumina - magnesia composites. The polymerization may be effected in a substantially dry hydrocarbon or ether-type diluent. The process may be carried out as a continuous process. The diene exemplified is isoprene.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5027965A GB1120457A (en) | 1965-11-26 | 1965-11-26 | Polymerization process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5027965A GB1120457A (en) | 1965-11-26 | 1965-11-26 | Polymerization process |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1120457A true GB1120457A (en) | 1968-07-17 |
Family
ID=10455335
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5027965A Expired GB1120457A (en) | 1965-11-26 | 1965-11-26 | Polymerization process |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1120457A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2459357A1 (en) * | 1973-12-20 | 1975-07-03 | Gole Jean | VIBRATION-DAMPING MATERIALS |
-
1965
- 1965-11-26 GB GB5027965A patent/GB1120457A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2459357A1 (en) * | 1973-12-20 | 1975-07-03 | Gole Jean | VIBRATION-DAMPING MATERIALS |
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