GB1116150A - Amine-epichlorhydrin reaction products and compositions containing same for use in the treatment of textiles - Google Patents
Amine-epichlorhydrin reaction products and compositions containing same for use in the treatment of textilesInfo
- Publication number
- GB1116150A GB1116150A GB821067A GB821067A GB1116150A GB 1116150 A GB1116150 A GB 1116150A GB 821067 A GB821067 A GB 821067A GB 821067 A GB821067 A GB 821067A GB 1116150 A GB1116150 A GB 1116150A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- textile
- ingredient
- weight
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/385—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing epoxy groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2164—Coating or impregnation specified as water repellent
- Y10T442/2197—Nitrogen containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2352—Coating or impregnation functions to soften the feel of or improve the "hand" of the fabric
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Detergent compositions comprise: (A) at least 0.01% by weight of a textile treating agent prepared by the reaction of a primary alkylamine (alkyl chain C12- 30) with epichlorohydrin in a molar ratio of epichlorohydrin to amine of from 1.25: 1 to 2: 1 at a temperature of 80-200 DEG F. for 30 minutes to 10 hours; (B) from 0-10% by weight of ingredient (A) of a nonionic surfactant whose molecule contains (i) an hydrophobic group which is a C9-C18 alkyl or an alkyl phenyl group (C9-C15 alkyl) and (ii) an hydrophilic group which consists of or includes from 10 to 60 ethylene oxide units; (C) 0-10% by weight of the total composition of a water-soluble organic solvent; and (D) the balance substantially water. Such compositions may include as an additional ingredient, 5-20% by weight of ingredient (A) of sodium tetraphosphate or sodium hexametaphosphate, or a mixture thereof. These compositions may also comprise as an additional ingredient a textile lubricant in a weight ratio of textile lubricant to ingredient (A) of from 0.125: 1 to 1.5: 1, the said textile lubricant consisting of a homogeneous water suspension of an oxidized Fischer-Tropsch wax with a chain length of C40- 55, emulsified by an emulsifier selected from (a) at least one cationic quaternary ammonium compound having the formula <FORM:1116150/C4-C5/1> where R1 is C14- 20 alkyl; R2 is C1- 3 alkyl, phenyl, naphthyl, or a C1- 3 alkyl substituted phenyl; R3 is C2- 4 alkylene; Z is an anion; and x + y ranges from 1-6 and x ranges from 1-6, and (b) mixtures of said cationic quaternary ammonium compound and said nonionic surfactant constituting ingredient (B) in a weight ratio of at least 3: 7 and wherein the weight ratio of oxidized Fischer-Tropsch wax to total of emulsifier and nonionic surfactant ranges from 10: 1 to 3: 7.ALSO:A process for preparing a water-dispersible textile treating agent comprises reacting a primary alkyl amine having from 12 to 30 carbon atoms in the alkyl chain (which may contain cycloaliphatic moieties) with epichlorohydrin in a molar ratio of epichlorohydrin to amine of from 1.25:1 to 2:1 at a temperature of from 80 DEG F. to 200 DEG F. for a period of from 30 minutes to 10 hours. The reaction product is preferably neutralized at a temperature of 60-100 DEG F. to an acid value of 5-30. Examples of primary alkyl amines which may be used in the process are those wherein the alkyl groups may be derived from naturally occurring glycerides (e.g tallow, lard) or from petroleum sources and/or olefins such as ethylene polymers. Amines included in these groups which may be use are dodecyl, tetradecyl, hexadecyl, octadecyl, pentapropylene, hexapropylene, dodecyl-cyclohexyl, eicosly and docosyl amines. The amine group is preferably attached to the terminal carbon atom of the chain. The use of these amines is in textile treatment to improve fibre-to-fibre lubricity; soften, and improve water repellency.ALSO:A composition for imparting durable effects to textile materials comprises (A) at least 0.01% by weight of a textile treating agent prepared by the reaction of a primary C12-30 alkyl amine with epichlrohydrin; (B) from 0% to 10% by weight of ingredient (A) of a non-ionic surfactant whose molecule contains (i) a hydrophobic group, which is a C9-C18 alkyl group or a C9-C15 alkyl phenyl group and (ii) a hydrophilic group which consists of or includes from 10-60 ethylene oxide groups; (C) from 0-10% by weight of the total composition of a water soluble organic solvent; and (D) the balance substantially water. 5-20% of ingredient (A) of sodium tetraphosphate or sodium hexametaphosphate may be added to the composition. A textile lubricant consisting of a homogenous water suspension of an oxidised Fischer-Tropsch wax, having a chain length from 40,55 carbon atoms, emulsified by an emulsifier selected from (a) at least one cationic quaternary ammonium compound having the formula: <FORM:1116150/D1-D2/1> where R1 is C14 - C20 alkyl; R2 is C1 - C3 alkyl, phenyl, naphthyl, or a C1 - C3 alkyl substituted phenyl; R3 is an alkylene group with 2-4 carbon atoms; Z represents an anion; and x + y ranges from 1 to 6 and x ranges from 1-6 and (b) mixtures of said cationic quaternary ammonium compound and said non ionic surfactant constituting ingredient (B) in a weight ratio of at least 3:7, and wherein the weight ratio of oxidised Fischer-Tropsch wax to total of emulsifier and non ionic surfactant ranges from 10:1 to 3:7, may also be added. The composition may be applied to filament, staple fibres or fabric, knitted or woven from thread or yarn and/or fabric which is formed by bonding. The textile material can be cotton, linen, wool, rayon, nylon, cellulose esters or chemically modified cotton. The composition is applied from an aqueous medium by dipping; circulating the dispersion through the textile material; spraying the dispersion onto the surface; and applying the dispersion to the textile material my means of a kiss roll. Thereafter the water is removed and the treated textile material is dried by heating at 80 DEG - 375 DEG F. Application of this composition to textile materials can improve their stretchability, produce durable fabric softeners, increase their lubricity, body, firmness and/or water repellency.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US52879366A | 1966-02-21 | 1966-02-21 | |
US55688066A | 1966-05-13 | 1966-05-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1116150A true GB1116150A (en) | 1968-06-06 |
Family
ID=27062825
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB821067A Expired GB1116150A (en) | 1966-02-21 | 1967-02-21 | Amine-epichlorhydrin reaction products and compositions containing same for use in the treatment of textiles |
Country Status (3)
Country | Link |
---|---|
US (1) | US3497556A (en) |
DE (1) | DE1593950A1 (en) |
GB (1) | GB1116150A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104562686A (en) * | 2015-02-02 | 2015-04-29 | 苏州爱立方服饰有限公司 | Textile waterproof agent with good durability and preparation method thereof |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3623880A (en) * | 1968-12-20 | 1971-11-30 | Ball Corp | Product for permanently attaching long chain moieties to textile materials |
US3686315A (en) * | 1969-02-24 | 1972-08-22 | Universal Oil Prod Co | Reaction product of epichlorohydrin compound and beta-alkylamine |
US3945964A (en) * | 1971-03-19 | 1976-03-23 | Garth Winton Hastings | Aqueous epoxy emulsions |
DE2525610C2 (en) * | 1975-06-09 | 1985-04-11 | Henkel KGaA, 4000 Düsseldorf | Cationic softeners with improved cold water solubility |
DE2853241A1 (en) * | 1978-12-09 | 1980-06-26 | Henkel Kgaa | METHOD FOR PRODUCING QUATERNAUS AMMONIUM HALOGENIDES IN POWDER OR GRANULATE FORM |
US6642192B1 (en) * | 2000-01-28 | 2003-11-04 | Applied Carbochemicals Inc | Amphoteric surfactants based upon epoxy succinic acid in personal care applications |
US6642193B1 (en) * | 2000-01-28 | 2003-11-04 | Applied Carbochemicals Inc | Carboxylated surfactants in personal care applications |
US6346648B1 (en) * | 2000-01-28 | 2002-02-12 | Applied Carbo Chemicals Inc | Amphoteric surfactants based upon epoxy succinic acid |
US8446096B1 (en) * | 2009-10-02 | 2013-05-21 | The United States Of America As Represented By The Secretary Of The Navy | Terahertz (THz) reverse micromagnetron |
CN102247778A (en) * | 2011-05-21 | 2011-11-23 | 孙安顺 | Efficient binary surface active agent for displacing oil as well as preparation method and application thereof |
CN112127149B (en) * | 2020-08-19 | 2023-04-14 | 杭州传化精细化工有限公司 | Hydrophilic small-layer-difference smoothing agent for cheese and preparation method thereof |
US11795374B2 (en) | 2021-09-30 | 2023-10-24 | Saudi Arabian Oil Company | Composition and method of making cationic surfactants with two quaternary ammonium head groups |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2891970A (en) * | 1959-06-23 | Process for preparing basic | ||
US3102112A (en) * | 1960-02-29 | 1963-08-27 | American Viscose Corp | Modification of cellulose with epoxypropyl amine compounds |
-
1966
- 1966-06-13 US US3497556D patent/US3497556A/en not_active Expired - Lifetime
-
1967
- 1967-02-18 DE DE1967P0041446 patent/DE1593950A1/en active Pending
- 1967-02-21 GB GB821067A patent/GB1116150A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104562686A (en) * | 2015-02-02 | 2015-04-29 | 苏州爱立方服饰有限公司 | Textile waterproof agent with good durability and preparation method thereof |
CN104562686B (en) * | 2015-02-02 | 2017-01-04 | 苏州爱立方服饰有限公司 | Waterproofing agent used for textiles that a kind of persistency is good and preparation method |
Also Published As
Publication number | Publication date |
---|---|
US3497556A (en) | 1970-02-24 |
DE1593950A1 (en) | 1971-02-25 |
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