GB1113580A - Separation of crystals from solutions,by evaporation of solvent - Google Patents

Separation of crystals from solutions,by evaporation of solvent

Info

Publication number
GB1113580A
GB1113580A GB3613/67A GB361367A GB1113580A GB 1113580 A GB1113580 A GB 1113580A GB 3613/67 A GB3613/67 A GB 3613/67A GB 361367 A GB361367 A GB 361367A GB 1113580 A GB1113580 A GB 1113580A
Authority
GB
United Kingdom
Prior art keywords
line
effect
crystals
solution
passed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3613/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chicago Bridge and Iron Co
Original Assignee
Chicago Bridge and Iron Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chicago Bridge and Iron Co filed Critical Chicago Bridge and Iron Co
Publication of GB1113580A publication Critical patent/GB1113580A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D1/00—Oxides or hydroxides of sodium, potassium or alkali metals in general
    • C01D1/04—Hydroxides
    • C01D1/42—Concentration; Dehydration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D1/00—Evaporating
    • B01D1/26—Multiple-effect evaporating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D9/00—Crystallisation
    • B01D9/0018—Evaporation of components of the mixture to be separated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D9/00—Crystallisation
    • B01D9/0059—General arrangements of crystallisation plant, e.g. flow sheets
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S159/00—Concentrating evaporators
    • Y10S159/08—Multieffect or multistage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S159/00—Concentrating evaporators
    • Y10S159/25—Decant, press, centrifuge
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S159/00—Concentrating evaporators
    • Y10S159/34—Caustic

Abstract

1,113,580. Separation of crystals from solution by flash and multiple-effect evaporation. CHICAGO BRIDGE & IRON CO. 24 Jan., 1967 [25 Jan., 1966], No. 3613/67. Heading BIB. An aqueous solution of two crystallizable compounds, e.g. caustic soda and sodium chloride, is concentrated so that one of the compounds crystallizes out, by conducting the solution through line 10, regenerative heaters 12, 14, 16, 18, and preheater 22 into the vertical tubes of falling-film evaporator 30, the hot liquor is then conducted through line 38 to flash zones 40, 42, 44, where flash vaporization and cooling occurs accompanied by formation of sodium chloride crystal nuclei. The nucleated liquor is passed through line 52 into the second effect 54 of a multiple-effect evaporator system 58, 54, 56, a slurry of salt crystals in liquor is withdrawn from effect 54 through line 66, and passed to tank 70, where the crystals are separated. The liquor is conducted through line 76 into the third-effect evaporator 56 where further sodium chloride crystallizes, the slurry being collected in tank 84, where the crystals are separated. The motherliquor is conducted through line 88 to firsteffect evaporator 58 which is heated by the vapours evolved from the solution in filmevaporator 30. The concentrated solution. withdrawn from effect 58, is passed through line 102 into flash evaporator 103 where the residual sodium chloride crystallizes out. These crystals are separated in tank 118, and a solution of caustic soda is withdrawn through line 124. The condensate withdrawn from the heat-exchanger 91 of effect 58 through line 99, is passed through heaters 18 . . . 12. The condensate withdrawn from the heat-exchanver 63 of effect 54 is passed via line 106 into the heat-exchanger 133 of effect 56. Other solutions which may be treated are caustic soda containing sodium sulphate and sodium carbonate. and brines containing sodium chloride, calcium chloride, and magnesium salts.
GB3613/67A 1966-01-25 1967-01-24 Separation of crystals from solutions,by evaporation of solvent Expired GB1113580A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US522967A US3332470A (en) 1966-01-25 1966-01-25 Method for concentrating solutions

Publications (1)

Publication Number Publication Date
GB1113580A true GB1113580A (en) 1968-05-15

Family

ID=24083113

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3613/67A Expired GB1113580A (en) 1966-01-25 1967-01-24 Separation of crystals from solutions,by evaporation of solvent

Country Status (4)

Country Link
US (1) US3332470A (en)
BE (1) BE693174A (en)
GB (1) GB1113580A (en)
NL (1) NL6701170A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2219340A1 (en) * 1972-04-20 1973-11-08 Kali & Salz Ag Prodn of two salts from one soln - by crystallisation using evapn by expansion
WO1990015652A1 (en) * 1989-06-14 1990-12-27 A. Ahlstrom Corporation Multistage evaporating system
CN104001338A (en) * 2014-05-13 2014-08-27 上海金力泰化工股份有限公司 Desolventizing system and operation process thereof
CN111359240A (en) * 2020-03-30 2020-07-03 山东凯斯达机械制造有限公司 Tubular falling film evaporator, concentration device and using method and process of concentration device
CN111467821A (en) * 2020-06-22 2020-07-31 富海(东营)新材料科技有限公司 Device and process for recovering byproduct salt in production process of sulfone material
CN114949893A (en) * 2022-06-01 2022-08-30 启东神农机械有限公司 Evaporative crystallization process and device for producing lithium chloride from salt lake brine

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT291197B (en) * 1969-08-05 1971-07-12 Tatabanyai Szenbanyak Process for processing the autoclave liquor which is obtained from the continuous digestion of minerals containing aluminum oxide, especially of bauxite, with sodium aluminate liquor
US3912578A (en) * 1973-01-22 1975-10-14 United States Steel Corp Apparatus for and a method of purifying waste fluid
FR2305393A1 (en) * 1975-03-28 1976-10-22 Rhone Poulenc Ind NEW PROCESS FOR OBTAINING CAUSTIC SODA FROM A CHLORUROSODIUM LESSIVE, CONTAINING SULPHATE IONS, PROVIDED BY AN ELECTROLYSIS CELL
JPS53113299A (en) * 1977-03-15 1978-10-03 Asahi Glass Co Ltd Method of concentrating caustic alkaline sulution for ion exchange membrane electrolysis
IT1210981B (en) * 1981-01-27 1989-09-29 Giampaolo Teucci CONCENTRATION SYSTEM WORKING BY FORCED CIRCULATION OF THE PRODUCT TO BE CONCENTRATED HAVING LOW ENERGY CONSUMPTION.
DE3302809A1 (en) * 1983-01-28 1984-08-02 Chemische Werke Hüls AG, 4370 Marl METHOD FOR DEGRADING NAOH-CONTAINING MULTIPLE SALTS
DE3834716A1 (en) * 1988-10-12 1990-04-19 Metallgesellschaft Ag METHOD AND DEVICE FOR CONCENTRATING SOLUTIONS
US5209828A (en) * 1991-12-23 1993-05-11 Mobil Oil Corporation System for concentrating a spent caustic stream
ITPR20040050A1 (en) * 2004-07-20 2004-10-20 Fmc Technologies Italia Spa EVAPORATION PLANT FOR FRUITS AND VEGETABLE PRODUCTS WITH LOW ENERGY CONSUMPTION AND VERY LIMITED THERMAL DAMAGE.
DE102011108211A1 (en) * 2011-07-21 2013-01-24 Thyssenkrupp Uhde Gmbh A process for concentrating aqueous liquor and apparatus therefor
CN105209388B (en) * 2013-03-14 2018-04-03 死海工业有限公司 From the method for water-soluble liquid precipitate carnallite
CN104162285B (en) * 2014-07-31 2015-09-02 河南中原黄金冶炼厂有限责任公司 Multiple-effect rotation vapo(u)rization system
WO2016090259A1 (en) * 2014-12-05 2016-06-09 Westlake Vinyl Corporation System and method for purifying depleted brine
CN105381620B (en) * 2015-11-12 2017-04-12 浙江星月药物科技股份有限公司 Double-effect concentration device
EP3436417A4 (en) 2016-03-22 2020-01-01 Dead Sea Works Ltd. Spherical fertilizers and process for the production thereof
EP3529226A1 (en) 2016-10-22 2019-08-28 Dead Sea Works Ltd. Binders for the granulation of fertilizers
CN106669210B (en) * 2016-12-12 2022-03-22 江苏迈安德节能蒸发设备有限公司 Sodium chloride's methanol-water solution evaporation recovery system
AU2017377149A1 (en) 2016-12-17 2019-07-25 Dead Sea Works Ltd. A process for the production of potassium sulphate and magnesium sulphate from carnallite and sodium sulphate
CN106477796A (en) * 2016-12-21 2017-03-08 北京燕山翔宇环保工程技术有限公司 Desulfurization wastewater treatment system and method
MX2019009446A (en) 2017-02-10 2019-10-09 Cleveland Potash Ltd Polyhalite granulation process.
CN111392753B (en) * 2020-03-31 2022-03-15 中国铝业股份有限公司 Method for separating out sodium bicarbonate from deep carbonation mother liquor
CN111569450B (en) * 2020-05-22 2023-12-26 浙江省天正设计工程有限公司 Continuous evaporation concentration device and concentration process for methylphosphonic aldehyde reaction liquid
CN111792772A (en) * 2020-06-10 2020-10-20 华电电力科学研究院有限公司 Online removal method for organic pollutants in wastewater evaporation crystal slurry
CN111875556B (en) * 2020-06-16 2023-08-25 湖北远大生物技术有限公司 Preparation method and system for producing important precursor ATC of L-cysteine by enzyme method
CN112044108A (en) * 2020-09-07 2020-12-08 广西田东锦鑫化工有限公司 Double-stock solution flash evaporation double-six-effect evaporator
DE102020131827A1 (en) * 2020-12-01 2022-06-02 Andreas Wilk Device and method for concentrating corrosive liquids
CN114291825A (en) * 2021-12-27 2022-04-08 重庆博张智能装备有限公司 Process production line and process method for preparing caustic soda
CN114288694B (en) * 2021-12-31 2023-04-07 天津农学院 Flash steam compression type continuous crystallization system and process for high-purity lithium carbonate

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1799478A (en) * 1925-02-05 1931-04-07 David D Peebles Method of evaporating liquids and apparatus therefor
GB381439A (en) * 1931-07-15 1932-10-06 Metallgesellschaft Ag Process of and apparatus for the separation of solid substances from liquids by vacuum cooling in stages
US2330221A (en) * 1937-10-04 1943-09-28 Buffalo Foundry & Machine Co Method and apparatus for concentrating liquids which upon concentration deposit crystals and leave a residual concentrated liquor
US2459302A (en) * 1942-12-10 1949-01-18 American Viscose Corp Concentration of salts having minimum solubilities at temperatures above those of the initial solutions
DE906691C (en) * 1951-01-09 1954-03-18 Metallgesellschaft Ag Process for evaporation of liquids
US2744571A (en) * 1953-09-28 1956-05-08 Goslin Birmingham Mfg Company Evaporating process

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2219340A1 (en) * 1972-04-20 1973-11-08 Kali & Salz Ag Prodn of two salts from one soln - by crystallisation using evapn by expansion
WO1990015652A1 (en) * 1989-06-14 1990-12-27 A. Ahlstrom Corporation Multistage evaporating system
CN104001338A (en) * 2014-05-13 2014-08-27 上海金力泰化工股份有限公司 Desolventizing system and operation process thereof
CN104001338B (en) * 2014-05-13 2018-02-02 上海金力泰化工股份有限公司 A kind of desolventizing system and its operating procedure
CN111359240A (en) * 2020-03-30 2020-07-03 山东凯斯达机械制造有限公司 Tubular falling film evaporator, concentration device and using method and process of concentration device
CN111467821A (en) * 2020-06-22 2020-07-31 富海(东营)新材料科技有限公司 Device and process for recovering byproduct salt in production process of sulfone material
CN114949893A (en) * 2022-06-01 2022-08-30 启东神农机械有限公司 Evaporative crystallization process and device for producing lithium chloride from salt lake brine
CN114949893B (en) * 2022-06-01 2024-04-19 启东神农机械有限公司 Evaporation crystallization process and device for producing lithium chloride from salt lake brine

Also Published As

Publication number Publication date
BE693174A (en) 1967-07-03
NL6701170A (en) 1967-07-26
US3332470A (en) 1967-07-25

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