GB1110396A - Process for the production of alcohols by oxidation of hydrocarbons - Google Patents
Process for the production of alcohols by oxidation of hydrocarbonsInfo
- Publication number
- GB1110396A GB1110396A GB35990/65A GB3599065A GB1110396A GB 1110396 A GB1110396 A GB 1110396A GB 35990/65 A GB35990/65 A GB 35990/65A GB 3599065 A GB3599065 A GB 3599065A GB 1110396 A GB1110396 A GB 1110396A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alcohol
- boric acid
- oxidation
- alcohols
- hydrocarbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
- C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
- C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Alcohols are prepared by the liquid phase oxidation of saturated aliphatic hydrocarbons having at least 10 carbon atoms or cycloaliphatic hydrocarbons having at least 6 carbon atoms with a molecular oxygen-containing gas at an elevated temperature and aqueous boric acid is continuously mixed, at a rate equivalent to the formation of the alcohol, with the hydrocarbon during the whole of the oxidation period and the water added and formed during esterification; the borate ester is subsequently hydrolysed to give the alcohol. The boric acid is preferably added as a hot saturated solution or as moist boric acid crystals. It is preferred to operate at 130-190 DEG C. Examples describe the preparation of cyclodecanol and n-tetradecanol; some ketone corresponding to the alcohol is also formed.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEC33707A DE1294960B (en) | 1964-08-24 | 1964-08-24 | Process for the production of aliphatic or cycloaliphatic alcohols by oxidation of hydrocarbons |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1110396A true GB1110396A (en) | 1968-04-18 |
Family
ID=7020970
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB35990/65A Expired GB1110396A (en) | 1964-08-24 | 1965-08-23 | Process for the production of alcohols by oxidation of hydrocarbons |
Country Status (7)
Country | Link |
---|---|
AT (1) | AT256058B (en) |
BE (1) | BE668681A (en) |
CH (1) | CH450376A (en) |
DE (1) | DE1294960B (en) |
GB (1) | GB1110396A (en) |
NL (1) | NL6510994A (en) |
SE (1) | SE316158B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19848730A1 (en) * | 1998-10-22 | 2000-04-27 | Degussa | Process for the production of cyclic alcohols |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE633933A (en) * | ||||
NL288365A (en) * | 1963-02-07 |
-
0
- BE BE668681D patent/BE668681A/xx unknown
-
1964
- 1964-08-24 DE DEC33707A patent/DE1294960B/en active Pending
-
1965
- 1965-08-19 SE SE10882/65A patent/SE316158B/xx unknown
- 1965-08-20 CH CH1174665A patent/CH450376A/en unknown
- 1965-08-23 NL NL6510994A patent/NL6510994A/xx unknown
- 1965-08-23 AT AT771665A patent/AT256058B/en active
- 1965-08-23 GB GB35990/65A patent/GB1110396A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
NL6510994A (en) | 1966-02-25 |
BE668681A (en) | |
AT256058B (en) | 1967-08-10 |
DE1294960B (en) | 1969-05-14 |
CH450376A (en) | 1968-01-31 |
SE316158B (en) | 1969-10-20 |
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