GB1105561A - Acrylic/hexamethylol melamine hexamethyl ether coating compositions - Google Patents
Acrylic/hexamethylol melamine hexamethyl ether coating compositionsInfo
- Publication number
- GB1105561A GB1105561A GB869265A GB869265A GB1105561A GB 1105561 A GB1105561 A GB 1105561A GB 869265 A GB869265 A GB 869265A GB 869265 A GB869265 A GB 869265A GB 1105561 A GB1105561 A GB 1105561A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon atoms
- component
- alkyl
- interpolymer
- acrylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/32—Modified amine-aldehyde condensates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Coating compositions comprise a solution in an organic solvent of (1) an interpolymer of (a) 0-89% by weight of a monovinyl substituted or unsubstituted aromatic hydrocarbon having 8-12 carbon atoms, (b) 10-90% of a compound selected from alkyl acrylates of 4-15 carbon atoms, alkyl methacrylates of 5-16 carbon atoms, cyanoethyl, cyanopropyl or cyanobutyl acrylate, acrylamide and its N,N-dialkyl derivatives wherein the alkyl groups each contain 1-6 carbon atoms, and hydroxyalkyl acrylates or methacrylates wherein the alkyl group has 1-4 carbon atoms, (c) 0-50% of a compound selected from a ,b -olefinically unsaturated nitriles of 3-9 carbon atoms, vinyl acetate, and vinyl or vinylidene chloride or fluoride, and (d) 1-20% of an a ,b -olefinically unsaturated carboxylic acid having 3-10 carbon atoms; said interpolymer having a reduced viscosity of 0.1 to 0.8 (at 25 DEG C. in tetrahydrofuran) and a Tg of at least 25 DEG C.; and (2) 10-40%, based on the weight of the interpolymer, of hexamethylol melamine hexamethyl ether. In a modification, component (d) of the polymer (1) is replaced by hydroxyethyl or hydroxypropyl acrylate or methacrylate, the monoallyl ether of trimethylol propane, acrylamide or methacrylamide. Component (a) of the polymer may be styrene or a substituted derivative thereof or vinyl naphthalene. Suitable nitriles as component (c) include acrylonitrile, a -chloroacrylonitrile and a -trifluoromethyl acrylonitrile. The acid component (d) may be, for example, acrylic, methacrylic, crotonic, cinnamic, atropic, a -chloroacrylic, a -fluoroacrylic, maleic, fumaric or itaconic acid, or monoisopropyl maleate or mono-n-butyl fumarate. Suitable solvents include benzene, xylene, toluene, dioxane, and ethylene glycol monomethyl or monoethyl ether. Additives such as colorants, pigments and fillers may be included in the compositions. Coatings prepared from the compositions are easily cured by baking at 250-350 DEG C. Preparations are illustrated of the polymer component (1) wherein (i) ethyl acrylate, styrene and acrylic acid are copolymerized in 1,4-dioxane in the presence of t.-dodecyl mercaptan using benzoyl peroxide catalyst and (ii) ethyl acrylate and acrylic acid are copolymerized in 1,4-dioxane in the presence of t.-dodecyl mercaptan using di-t.-butyl peroxide catalyst.ALSO:Coatings which can be easily cured by baking at 250-350 DEG C in 10-30 minutes are obtained from compositions comprising a solution in an organic solvent of (1) an interpolymer of (a) 0-89% by weight of a monovinyl aromatic compound (b) 10-90% of a compound selected from alkyl acrylates of 4-15 carbon atoms, alkyl methacrylates of 5-16 carbon atoms, cyano-ethyl, -propyl or -butyl acrylate, acrylamide and its N,N-di-(C1-C6 alkyl) derivatives, and C1-C4-hydroxy alkyl esters of acrylic or methacrylic acid (c) 0-50% of a compound selected from C3-C9 a ,b -olefinically unsaturated nitriles, vinyl acetate, and vinyl or vinylidene chloride or fluoride and (d) 1-20% of an a ,b -olefinically unsaturated carboxylic acid of 3-10 carbon atoms; and (2) 10-40%, based on the weight of the interpolymer, of hexamethylol melamine hexamethyl ether. In a modification, component (d) of the polymer (1) is replaced by hydroxy ethyl or hydroxypropyl acrylate or methacrylate, the monoallyl ether of trimethylol propane, acrylamide or methacrylamide. Suitable solvents include benzene, xylene, toluene, dioxane and ethylene glycol monoethyl or monomethyl ether. Additives such as colourants, pigments and fillers may be included in the compositions. In Examples, coatings are drawn and cured on phosphatised steel; the polymer component being an ethyl acrylate/styrene/acrylic acid or ethyl acrylate/acrylic acid copolymer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB869265A GB1105561A (en) | 1965-03-01 | 1965-03-01 | Acrylic/hexamethylol melamine hexamethyl ether coating compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB869265A GB1105561A (en) | 1965-03-01 | 1965-03-01 | Acrylic/hexamethylol melamine hexamethyl ether coating compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1105561A true GB1105561A (en) | 1968-03-06 |
Family
ID=9857408
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB869265A Expired GB1105561A (en) | 1965-03-01 | 1965-03-01 | Acrylic/hexamethylol melamine hexamethyl ether coating compositions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1105561A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4185045A (en) * | 1977-02-26 | 1980-01-22 | Kansai Paint Company, Limited | Powdery coating composition |
-
1965
- 1965-03-01 GB GB869265A patent/GB1105561A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4185045A (en) * | 1977-02-26 | 1980-01-22 | Kansai Paint Company, Limited | Powdery coating composition |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB991904A (en) | Polymeric unsaturated carboxylic acids and derivatives thereof | |
GB1065780A (en) | Poly(vinylidene fluoride) compositions | |
GB989371A (en) | Hard and flexible stoving enamels | |
GB1109643A (en) | Interpolymers and coating compositions made therefrom | |
GB1009217A (en) | Vinyl addition polymers and their preparation | |
GB922582A (en) | Coating compositions and methods of coating materials with them | |
DE59405136D1 (en) | Aqueous dispersions of acrylic copolymers | |
GB893631A (en) | Coating compositions, coated articles and method of coating | |
GB1105561A (en) | Acrylic/hexamethylol melamine hexamethyl ether coating compositions | |
US3654213A (en) | Aliphatic hydrocarbon-compatible pressure-sensitive adhesive | |
GB971209A (en) | Stable polymeric coating compositions | |
ES341293A1 (en) | High molecular weight thermoplastic polycarbonates | |
DE1595243A1 (en) | Process for the production of new copolymers | |
GB725468A (en) | Improvements in or relating to a thermoplastic copolymer | |
GB1513384A (en) | Crosslinkable coating compositions and method of using the same | |
GB1123303A (en) | Production of pigmented resinous compositions | |
US3609161A (en) | Thermosetting acrylics containing oxazoline groups | |
US3692757A (en) | Thermosetting acrylics containing oxazoline groups | |
GB973528A (en) | Resinous compositions | |
JPS6234247B2 (en) | ||
ES481683A1 (en) | Water-dilutable heat curable compositions which provide coatings having a reduced tendency to surface defects such as cissing and pinholing comprise | |
GB1078415A (en) | Thermosetting compositions | |
GB1007723A (en) | Polymer compositions | |
GB806093A (en) | Unsaturated ureido compounds and polymers and copolymers thereof | |
GB1062286A (en) | Stoving lacquers |