GB1095700A - Reinforcing thermoplastics - Google Patents

Reinforcing thermoplastics

Info

Publication number
GB1095700A
GB1095700A GB5382565A GB5382565A GB1095700A GB 1095700 A GB1095700 A GB 1095700A GB 5382565 A GB5382565 A GB 5382565A GB 5382565 A GB5382565 A GB 5382565A GB 1095700 A GB1095700 A GB 1095700A
Authority
GB
United Kingdom
Prior art keywords
silane
vinyl
polypropylene
filler
polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5382565A
Inventor
John Wilmar Edwards
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB5382565A priority Critical patent/GB1095700A/en
Priority to BR18544666A priority patent/BR6685446D0/en
Priority to BE691392D priority patent/BE691392A/xx
Priority to FR88237A priority patent/FR1505256A/en
Priority to ES0334695A priority patent/ES334695A1/en
Publication of GB1095700A publication Critical patent/GB1095700A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06—Fibrous reinforcements only
    • B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06—Fibrous reinforcements only
    • B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/12—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of short length, e.g. in the form of a mat
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/10—Encapsulated ingredients

Abstract

Reinforced thermoplastic organic polymeric material is prepared by incorporating a mineral filler into the thermoplastic material, (i) the mineral filler having been first treated with a silane containing one or more reactive groups, and a compatible polymer containing groups reactive with the silane having been either coated on the silane treated filler or incorporated in the thermoplastic material, or (ii) an adduct of such a silane and such a polymer having been coated on the filler before incorporation thereof in the thermoplastic material, or such an adduct having been incorporated in the thermoplastic material before incorporation of the filler therein. Specified thermoplastic polymers are polyethylene, polypropylene, polybutene-1, poly - 4 - methylpentene - 1, polyamides, polyoxymethylenes, polyethylene terephthalate, polystyrene, copolymers of styrene with butadiene or acrylonitrile, polyvinyl chloride and copolymers of vinyl chloride with vinyl acetate, methyl and ethyl esters of acrylic, methacrylic, maleic and fumaric acids, acrylonitrile, methacrylonitrile, maleic anhydride or vinylidene chloride. Plasticizers may be present. Specified fillers are glass fibres, asbestos, glass plates and mica. Specified silanes are vinyl trichlorosilane, g -aminopropyl triethoxysilane, vinyl triethoxysilane, vinyl triacetoxy silane, ethylaminotrichlorosilane, a -glycidoxy propyl trimethoxy silane and methacryloxy silanes. Specified reactive polymers are those containing epoxy, carboxyl, carboxylic anhydride, amino and hydroxyl groups; examples of polymers compatible with ethylene and propylene polymers being glycidyl methacrylate/ethylene copolymers and propylene polymers modified with maleic anhydride. In Examples (1) glass fibres treated with an adduct of an ethylene/glycidyl methacrylate copolymer and g -aminopropyl triethoxysilane are compounded with polypropylene, and (2) glass fibres treated with g -aminopropyl triethoxysilane are compounded with a mixture of polypropylene and maleic anhydride modified polypropylene.
GB5382565A 1965-12-20 1965-12-20 Reinforcing thermoplastics Expired GB1095700A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
GB5382565A GB1095700A (en) 1965-12-20 1965-12-20 Reinforcing thermoplastics
BR18544666A BR6685446D0 (en) 1965-12-20 1966-12-16 PROCESS FOR MANUFACTURING REINFORCED THERMOPLASTIC ORGANIC POLYMERS AND COMPOSITION UNDERSTANDING POLYMER PREPARED TASASTICS
BE691392D BE691392A (en) 1965-12-20 1966-12-19
FR88237A FR1505256A (en) 1965-12-20 1966-12-20 Reinforcement of thermoplastic materials
ES0334695A ES334695A1 (en) 1965-12-20 1966-12-20 Procedure for the preparation of a reinforced thermoplastic polymer material. (Machine-translation by Google Translate, not legally binding)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5382565A GB1095700A (en) 1965-12-20 1965-12-20 Reinforcing thermoplastics

Publications (1)

Publication Number Publication Date
GB1095700A true GB1095700A (en) 1967-12-20

Family

ID=10469106

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5382565A Expired GB1095700A (en) 1965-12-20 1965-12-20 Reinforcing thermoplastics

Country Status (2)

Country Link
ES (1) ES334695A1 (en)
GB (1) GB1095700A (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2242324A1 (en) * 1971-08-30 1973-06-07 Mitsubishi Rayon Co PROCESS FOR THE PRODUCTION OF GLASS REINFORCED POLYOLEFINE COMPOSITIONS
JPS48101424A (en) * 1972-04-04 1973-12-20
JPS4936749A (en) * 1972-07-05 1974-04-05
US3997503A (en) * 1972-11-27 1976-12-14 Imperial Chemical Industries Limited Polymer composition
US4000111A (en) * 1971-05-28 1976-12-28 Imperial Chemical Industries Limited Polymer composition
US4016134A (en) 1972-07-03 1977-04-05 Japan Atomic Energy Research Institute Novel composite comprising a special graft-copolymer
US4054549A (en) 1972-11-27 1977-10-18 Imperial Chemical Industries Limited Polymer composition
US4134848A (en) * 1976-06-28 1979-01-16 The United States Of America As Represented By The Secretary Of The Navy Composite for improved stripline board material
US4318960A (en) * 1977-11-07 1982-03-09 Owens-Corning Fiberglas Corporation Glass fiber size composition comprising maleic anhydride graft copolymer
GB2143831A (en) * 1983-06-08 1985-02-20 Mitsubishi Petrochemical Co Glass fiber reinforced resin compositions
US4574131A (en) * 1983-09-02 1986-03-04 Basf Aktiengesellschaft Preparation of high-impact nylon molding materials
EP0202635A2 (en) * 1985-05-21 1986-11-26 Shin-Etsu Chemical Co., Ltd. A method for the preparation of shaped articles of a vinyl chloride-based resin having improved surface properties
WO2017204635A1 (en) 2016-05-27 2017-11-30 Ibr Consult B.V. Fibre-reinforced plastic objects
CN107735378A (en) * 2015-07-31 2018-02-23 日本板硝子株式会社 Flake glass and resin combination
CN107849360A (en) * 2015-07-31 2018-03-27 日本板硝子株式会社 Flake glass and resin combination

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4000111A (en) * 1971-05-28 1976-12-28 Imperial Chemical Industries Limited Polymer composition
DE2242324A1 (en) * 1971-08-30 1973-06-07 Mitsubishi Rayon Co PROCESS FOR THE PRODUCTION OF GLASS REINFORCED POLYOLEFINE COMPOSITIONS
US4003874A (en) 1971-08-30 1977-01-18 Mitsubishi Rayon Co., Ltd. Producing glass-reinforced polyolefin compositions
JPS48101424A (en) * 1972-04-04 1973-12-20
JPS5247487B2 (en) * 1972-04-04 1977-12-02
US4016134A (en) 1972-07-03 1977-04-05 Japan Atomic Energy Research Institute Novel composite comprising a special graft-copolymer
JPS4936749A (en) * 1972-07-05 1974-04-05
US3997503A (en) * 1972-11-27 1976-12-14 Imperial Chemical Industries Limited Polymer composition
US4054549A (en) 1972-11-27 1977-10-18 Imperial Chemical Industries Limited Polymer composition
US4134848A (en) * 1976-06-28 1979-01-16 The United States Of America As Represented By The Secretary Of The Navy Composite for improved stripline board material
US4318960A (en) * 1977-11-07 1982-03-09 Owens-Corning Fiberglas Corporation Glass fiber size composition comprising maleic anhydride graft copolymer
GB2143831A (en) * 1983-06-08 1985-02-20 Mitsubishi Petrochemical Co Glass fiber reinforced resin compositions
US4574131A (en) * 1983-09-02 1986-03-04 Basf Aktiengesellschaft Preparation of high-impact nylon molding materials
EP0202635A2 (en) * 1985-05-21 1986-11-26 Shin-Etsu Chemical Co., Ltd. A method for the preparation of shaped articles of a vinyl chloride-based resin having improved surface properties
EP0202635A3 (en) * 1985-05-21 1988-06-22 Shin-Etsu Chemical Co., Ltd. A method for the preparation of shaped articles of a vinyl chloride-based resin having improved surface properties
CN107735378A (en) * 2015-07-31 2018-02-23 日本板硝子株式会社 Flake glass and resin combination
CN107849360A (en) * 2015-07-31 2018-03-27 日本板硝子株式会社 Flake glass and resin combination
US10590023B2 (en) 2015-07-31 2020-03-17 Nippon Sheet Glass Company, Limited Glass flakes and resin composition
US10611898B2 (en) 2015-07-31 2020-04-07 Nippon Sheet Glass Company, Limited Glass flakes and resin composition
WO2017204635A1 (en) 2016-05-27 2017-11-30 Ibr Consult B.V. Fibre-reinforced plastic objects

Also Published As

Publication number Publication date
ES334695A1 (en) 1967-11-01

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