GB1091525A - New titanium compounds and compositions containing them - Google Patents

New titanium compounds and compositions containing them

Info

Publication number
GB1091525A
GB1091525A GB26803/63A GB2680363A GB1091525A GB 1091525 A GB1091525 A GB 1091525A GB 26803/63 A GB26803/63 A GB 26803/63A GB 2680363 A GB2680363 A GB 2680363A GB 1091525 A GB1091525 A GB 1091525A
Authority
GB
United Kingdom
Prior art keywords
anhydride
wax
formula
titanium compound
residue
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26803/63A
Inventor
Raoul Feld
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Laporte Titanium Ltd
Original Assignee
Laporte Titanium Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Laporte Titanium Ltd filed Critical Laporte Titanium Ltd
Priority to GB26803/63A priority Critical patent/GB1091525A/en
Priority to BE650036A priority patent/BE650036A/xx
Priority to FR980708A priority patent/FR1404767A/en
Priority to NL6407597A priority patent/NL6407597A/xx
Publication of GB1091525A publication Critical patent/GB1091525A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0001—Post-treatment of organic pigments or dyes
    • C09B67/0004—Coated particulate pigments or dyes
    • C09B67/0008—Coated particulate pigments or dyes with organic coatings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds

Abstract

Liquid coating compositions for rendering paper, and like sheet material, masonry, concrete and brick water-repellent comprise a wax and at least one compound of the formula <FORM:1091525/C4-C5/1> where x is 2 and y is 2 or x is 3 and y is 1 and wherein R represents a substituted or unsubstituted alkyl radical and R1 represents the residue of a carboxylic anhydride R1(CO)2O and a solvent for the wax and the titanium compound. Preferred compositions comprise paraffin wax. Specified solvents are white spirit, trichloroethylene and perchloroethylene.ALSO:The invention comprises titanium compounds of the formula <FORM:1091525/C2/1> wherein x is 2 and y is 2, or x is 3 and y is 1 and R represents a substituted or unsubstituted alkyl group and R1 represents the residue of a dicarboxylic anhydride having the formula R1(CO)2O, provided that when x is 3 and y is 1, the dicarboxylic anhydride is not phthalic anhydride, and mixtures thereof. The compounds are made by reacting a titanate of the formula Ti(OR)4 with an anhydride R1(CO)2O provided that when the anhydride is phthalic anhydride, the ratio of anhydride and titanate is such that x is 2 and y is 2. Mixtures of the novel compounds can be made by adjusting the proportions of the reactants and/or using a mixture of titanates and/or anhydrides. Preferred values of R are C1- 8 alkyl groups, particularly butyl groups. Specified anhydrides are succinic, citraconic, cyclohexane dicarboxylic, tetrachlorophthalic, camphoric, maleic and phthalic anhydrides. The compounds are used in water-proofing compositions (see Division D1). Examples are provided.ALSO:Textile materials, paper and non-fibrous porous materials are rendered water-repellent by treatment with a composition comprising a wax, a titanium compound of the formula: <FORM:1091525/D1-D2/1> where x is 2 and y is 2, or x is 3 and y is 1, R is a substituted or unsubstituted alkyl group and R\sv represents the residue of a dicarboxylic anhydride R\sv(CO)2O, and a solvent for the wax and the titanium compound. Preferred compositions comprise paraffin wax. Specified solvents are white spirit, trichloroethylene and perchloroethylene. The treatment is effected by dipping, preferably followed by oven drying at 50 DEG C. Improved results are obtained by drying the material prior to treatment at 50 DEG C. Examples describe the treatment of cotton and wool fabrics.ALSO:Paper, masonry, brick and concrete are rendered water repellent by coating with a liquid composition comprise a wax, a titanium compound: <FORM:1091525/B1-B2/1> where x is 2 or y is 2 or x is 3 and v is 1, R represents a substituted or unsubstituted alkyl group and R1 represents the residue of a dicarboxylic anhydride R1(CO)2O, and a solvent for the wax and the titanium compound. Preferred compositions comprise paraffin wax. Specified solvents are white spirit, trichloroethylene and perchloroethylene.
GB26803/63A 1963-07-05 1963-07-05 New titanium compounds and compositions containing them Expired GB1091525A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB26803/63A GB1091525A (en) 1963-07-05 1963-07-05 New titanium compounds and compositions containing them
BE650036A BE650036A (en) 1963-07-05 1964-07-02
FR980708A FR1404767A (en) 1963-07-05 1964-07-03 New organic titanium compounds, their preparation and applications, in particular for the treatment of pigments
NL6407597A NL6407597A (en) 1963-07-05 1964-07-03

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB26803/63A GB1091525A (en) 1963-07-05 1963-07-05 New titanium compounds and compositions containing them

Publications (1)

Publication Number Publication Date
GB1091525A true GB1091525A (en) 1967-11-15

Family

ID=10249473

Family Applications (1)

Application Number Title Priority Date Filing Date
GB26803/63A Expired GB1091525A (en) 1963-07-05 1963-07-05 New titanium compounds and compositions containing them

Country Status (3)

Country Link
BE (1) BE650036A (en)
GB (1) GB1091525A (en)
NL (1) NL6407597A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4507246A (en) * 1983-06-09 1985-03-26 General Electric Company Titanium chelate catalyst
US4600789A (en) * 1984-05-14 1986-07-15 Kenrich Petrochemicals, Inc. Neoalkoxy organo-titanate useful as coupling and polymer processing agents
US4623738A (en) 1985-04-22 1986-11-18 Kenrich Petrochemicals, Inc. Neoalkoxy organo-titanates and organo-zirconates useful as coupling and polymer processing agents
US5260466A (en) * 1991-08-08 1993-11-09 Tioxide Specialties Limited Preparation of titanium derivatives

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4507246A (en) * 1983-06-09 1985-03-26 General Electric Company Titanium chelate catalyst
US4600789A (en) * 1984-05-14 1986-07-15 Kenrich Petrochemicals, Inc. Neoalkoxy organo-titanate useful as coupling and polymer processing agents
US4623738A (en) 1985-04-22 1986-11-18 Kenrich Petrochemicals, Inc. Neoalkoxy organo-titanates and organo-zirconates useful as coupling and polymer processing agents
US5260466A (en) * 1991-08-08 1993-11-09 Tioxide Specialties Limited Preparation of titanium derivatives

Also Published As

Publication number Publication date
BE650036A (en) 1964-11-03
NL6407597A (en) 1965-01-06

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