GB1090986A - Sulphur-containing oxime carbamates - Google Patents

Sulphur-containing oxime carbamates

Info

Publication number
GB1090986A
GB1090986A GB4767565A GB4767565A GB1090986A GB 1090986 A GB1090986 A GB 1090986A GB 4767565 A GB4767565 A GB 4767565A GB 4767565 A GB4767565 A GB 4767565A GB 1090986 A GB1090986 A GB 1090986A
Authority
GB
United Kingdom
Prior art keywords
reacting
appropriate
substituted
hydrocarbylthio
aldoxime
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4767565A
Inventor
Cyril Donninger
John Hugh Davies
Royston Henry Davis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1498899D priority Critical patent/FR1498899A/fr
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB4767565A priority patent/GB1090986A/en
Priority to IL6626830A priority patent/IL26830A/en
Priority to ES333163A priority patent/ES333163A1/en
Priority to NL6615725A priority patent/NL6615725A/xx
Priority to CH1605366A priority patent/CH483196A/en
Priority to DE1567142A priority patent/DE1567142C3/en
Priority to YU2102/66A priority patent/YU33188B/en
Priority to DK578066AA priority patent/DK120533B/en
Priority to OA52650A priority patent/OA02166A/en
Priority to SE15290/66A priority patent/SE329391B/xx
Priority to BR18438266A priority patent/BR6684382D0/en
Priority to AT643268A priority patent/AT291284B/en
Priority to BE689551D priority patent/BE689551A/xx
Publication of GB1090986A publication Critical patent/GB1090986A/en
Priority to MY6900016A priority patent/MY6900016A/en
Priority to US14894A priority patent/US3639620A/en
Priority to NL7012526.A priority patent/NL157780B/en
Priority to NL707012605A priority patent/NL145222B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C259/00—Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups
    • C07C259/02—Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups with replacement of the other oxygen atom of the carboxyl group by halogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Novel oxime carbamate derivatives of the general formula <FORM:1090986/C2/1> wherein R1 is a substituted or unsubstituted hydrocarbyl group and R2 is the same as R1, or may be a nitrile group, and R3 and R4 each represent hydrogen or a substituted or unsubstituted alkyl or aryl group, are prepared by reacting the appropriate 1-hydrocarbylthio aldoxime with an appropriate isocyanate, or by reacting a salt of the appropriate 1-hydrocarbylthio aldoxime with phosgene and then an amine or ammonia. The 1-hydrocarbylthio aldoxime starting materials may be prepared by reacting a 1-halooxime with a salt of the appropriate mercaptan in an organic reaction medium, or by reacting a 1-halo-oxime with a solution of sodium hydrogen sulphide and reacting the product with an appropriate compound having a replaceable halogen atom such as an alkyl haloacetate, or by reacting an appropriate nitrile with a suitable mercaptan in the presence of hydrogen chloride and reacting the product with a hydroxy ammonium salt and a base, e.g. sodium acetate.ALSO:Biocidal compositions contain, as active ingredient, novel compounds of the formula <FORM:1090986/A5-A6/1> wherein R1 is a substituted or unsubstituted hydrocarbyl group and R2 is the same as R1 or may be a nitrile group, and R3 and R4 each represent hydrogen or a substituted or unsubstituted alkyl or aryl group. A carrier, which may be solid, liquid or a compressed gas, and/or a surface p active agent may also be present. The novel compounds may be used in combination with each other or with stabilisers, fertilisers and/or other biologically active materials. The composition may be in the form of a wettable powder, a dust, granules, a concentrate, a solution, an emulsifiable concentrate, a conventional emulsion, an invert emulsion, an aerosol or an encapsulated material.
GB4767565A 1965-11-10 1965-11-10 Sulphur-containing oxime carbamates Expired GB1090986A (en)

Priority Applications (18)

Application Number Priority Date Filing Date Title
FR1498899D FR1498899A (en) 1965-11-10
GB4767565A GB1090986A (en) 1965-11-10 1965-11-10 Sulphur-containing oxime carbamates
OA52650A OA02166A (en) 1965-11-10 1966-11-08 New oxime carbamates, their preparation, compositions containing them, and their use as pesticides.
BR18438266A BR6684382D0 (en) 1965-11-10 1966-11-08 PROCESS FOR THE PREPARATION OF NEW CARBAMATES OF OXY COMPOSITES THAT CONTAIN THEM AND THEIR USE AS PESTICIDES
NL6615725A NL6615725A (en) 1965-11-10 1966-11-08
CH1605366A CH483196A (en) 1965-11-10 1966-11-08 Pesticides
DE1567142A DE1567142C3 (en) 1965-11-10 1966-11-08 Oxime carbamates and their use as insecticides, akaricides and nematicides
YU2102/66A YU33188B (en) 1965-11-10 1966-11-08 Postupak za dobijanje derivata oksimkarbamata
DK578066AA DK120533B (en) 1965-11-10 1966-11-08 Pesticidally active oxime carbamate derivatives.
IL6626830A IL26830A (en) 1965-11-10 1966-11-08 Oxime carbamates,method for their preparation,compositions containing them,and their use as pesticides
SE15290/66A SE329391B (en) 1965-11-10 1966-11-08
ES333163A ES333163A1 (en) 1965-11-10 1966-11-08 A procedure for the preparation of pesticide compositions. (Machine-translation by Google Translate, not legally binding)
AT643268A AT291284B (en) 1965-11-10 1966-11-08 Process for the preparation of new oxime carbamates
BE689551D BE689551A (en) 1965-11-10 1966-11-10
MY6900016A MY6900016A (en) 1965-11-10 1969-12-31 Sulphur-containing oxime carbamates
US14894A US3639620A (en) 1965-11-10 1970-02-13 Insecticidal composition and a method of use comprising cyanoalkylthio oxime carbamates
NL7012526.A NL157780B (en) 1965-11-10 1970-08-25 PROCESS FOR THE PREPARATION OF OXIME CARBAMATES ACTIVE AS AN INSECTICIDES.
NL707012605A NL145222B (en) 1965-11-10 1970-08-26 PROCESS FOR PREPARING AGENTS FOR CONTROLLING HARMFUL ORGANISMS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4767565A GB1090986A (en) 1965-11-10 1965-11-10 Sulphur-containing oxime carbamates

Publications (1)

Publication Number Publication Date
GB1090986A true GB1090986A (en) 1967-11-15

Family

ID=10445872

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4767565A Expired GB1090986A (en) 1965-11-10 1965-11-10 Sulphur-containing oxime carbamates

Country Status (3)

Country Link
BR (1) BR6684382D0 (en)
GB (1) GB1090986A (en)
MY (1) MY6900016A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3953590A (en) * 1971-01-18 1976-04-27 Colgate-Palmolive Company Composition and method for inhibiting perspiration with S-substituted benzothiohydroximic acid and salts thereof
US4096166A (en) 1975-02-04 1978-06-20 E. I. Du Pont De Nemours And Company Process for the preparation of carbamates of N-hydroxythioimidates
US4415743A (en) 1977-03-02 1983-11-15 Ciba-Geigy Corporation Furanyl oximes
US4454134A (en) * 1976-06-14 1984-06-12 Union Carbide Corporation Amide carbamates and amide oxime compounds

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3953590A (en) * 1971-01-18 1976-04-27 Colgate-Palmolive Company Composition and method for inhibiting perspiration with S-substituted benzothiohydroximic acid and salts thereof
US4096166A (en) 1975-02-04 1978-06-20 E. I. Du Pont De Nemours And Company Process for the preparation of carbamates of N-hydroxythioimidates
US4454134A (en) * 1976-06-14 1984-06-12 Union Carbide Corporation Amide carbamates and amide oxime compounds
US4415743A (en) 1977-03-02 1983-11-15 Ciba-Geigy Corporation Furanyl oximes
US4472317A (en) * 1977-03-02 1984-09-18 Ciba-Geigy Corporation Compositions which promote plant growth and protect plants, based on oxime ethers and oxime esters
US4497745A (en) * 1977-03-02 1985-02-05 Ciba-Geigy Corporation Compositions, which promote plant growth and protect plants based on oxide ethers and oxime esters
US4518536A (en) * 1977-03-02 1985-05-21 Ciba-Geigy Corporation Compositions, which promote plant growth and protect plants, based on oxime ethers and oxime esters
US4530798A (en) * 1977-03-02 1985-07-23 Ciba-Geigy Corporation Compositions, which promote plant growth and protect plants, based on oxime ethers and oxime esters

Also Published As

Publication number Publication date
BR6684382D0 (en) 1973-12-04
MY6900016A (en) 1969-12-31

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