GB1090122A - Method for the preparation of organosilicon compounds - Google Patents
Method for the preparation of organosilicon compoundsInfo
- Publication number
- GB1090122A GB1090122A GB865765A GB865765A GB1090122A GB 1090122 A GB1090122 A GB 1090122A GB 865765 A GB865765 A GB 865765A GB 865765 A GB865765 A GB 865765A GB 1090122 A GB1090122 A GB 1090122A
- Authority
- GB
- United Kingdom
- Prior art keywords
- radical
- represented
- compound containing
- monovalent
- bond
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003961 organosilicon compounds Chemical class 0.000 title abstract 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- AQRLNPVMDITEJU-UHFFFAOYSA-N triethylsilane Chemical compound CC[SiH](CC)CC AQRLNPVMDITEJU-UHFFFAOYSA-N 0.000 abstract 2
- VMAWODUEPLAHOE-UHFFFAOYSA-N 2,4,6,8-tetrakis(ethenyl)-2,4,6,8-tetramethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C=C[Si]1(C)O[Si](C)(C=C)O[Si](C)(C=C)O[Si](C)(C=C)O1 VMAWODUEPLAHOE-UHFFFAOYSA-N 0.000 abstract 1
- WZJUBBHODHNQPW-UHFFFAOYSA-N 2,4,6,8-tetramethyl-1,3,5,7,2$l^{3},4$l^{3},6$l^{3},8$l^{3}-tetraoxatetrasilocane Chemical compound C[Si]1O[Si](C)O[Si](C)O[Si](C)O1 WZJUBBHODHNQPW-UHFFFAOYSA-N 0.000 abstract 1
- 229910018540 Si C Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- XNAFLNBULDHNJS-UHFFFAOYSA-N dichloro(phenyl)silicon Chemical compound Cl[Si](Cl)C1=CC=CC=C1 XNAFLNBULDHNJS-UHFFFAOYSA-N 0.000 abstract 1
- MQIKJSYMMJWAMP-UHFFFAOYSA-N dicobalt octacarbonyl Chemical group [Co+2].[Co+2].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] MQIKJSYMMJWAMP-UHFFFAOYSA-N 0.000 abstract 1
- VDCSGNNYCFPWFK-UHFFFAOYSA-N diphenylsilane Chemical compound C=1C=CC=CC=1[SiH2]C1=CC=CC=C1 VDCSGNNYCFPWFK-UHFFFAOYSA-N 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 150000005826 halohydrocarbons Chemical class 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 229910010271 silicon carbide Inorganic materials 0.000 abstract 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0801—General processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/50—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms by carbon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/60—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/62—Nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
Abstract
An organosilicon compound containing a Si-C bond is prepared by reacting in the presence of a dicobalt octacarbonyl catalyst: (A) a Si-compound containing at least one Si-H bond, and (B) a compound containing aliphatic carbon atoms linked by double or triple bonds. A may be represented by ZaSiHbX4- ab where Z represents a monovalent hydrocarbon, halogenated hydrocarbon or cyanoalkyl radical, X is halogen, an organoxy or acyloxy radical, a is from 0 to 3, b is 1 or 2 and a + b is from 1 to 4. (A) may also be represented by a siloxane of average formula <FORM:1090122/C3/1> where Z is a monovalent organic radical, e has a value 0.5 to 2.49, f has a value 0.001 to 1.0 and e + f = 1.0 to 2.5. (B) may be represented by a siloxane average formula <FORM:1090122/C3/2> where Y represents a monovalent hydrocarbon, monovalent halohydrocarbon or cyanoalkyl radical, Y1 represents an organic radical containing aliphatic carbon atoms linked by double or triple bonds. Examples of (A) are diphenylsilane, tetramethylcyclotetrasiloxane, phenyldichlorosilane, triethylsilane or trimethoxysilane. (B) may be tetramethyltetravinylcyclotetrasiloxane or octene-1. In the examples the catalyst is used as a 5% solution in toluene in amounts of 0.02 to 0.08 parts by weight per part by weight of total reactants.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US34886764A | 1964-03-02 | 1964-03-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1090122A true GB1090122A (en) | 1967-11-08 |
Family
ID=23369893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB865765A Expired GB1090122A (en) | 1964-03-02 | 1965-03-01 | Method for the preparation of organosilicon compounds |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1245956B (en) |
| FR (1) | FR1433631A (en) |
| GB (1) | GB1090122A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2618329A1 (en) * | 1987-07-22 | 1989-01-27 | Dow Corning Sa | METHOD FOR MANUFACTURING A RING CAPABLE OF ENSURING RELEASE OF A THERAPEUTIC AGENT, AND RING MADE THEREBY |
| US5886115A (en) * | 1997-02-18 | 1999-03-23 | Rensselaer Polytechnic Institute | Process for the direct polymerization of allyl ethers, crotyl ethers and allyl alcohols |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6198735A (en) * | 1984-10-22 | 1986-05-17 | Toshiba Silicone Co Ltd | Polysiloxane containing ethylidenenorbornyl group |
-
1965
- 1965-02-20 DE DE1965G0042892 patent/DE1245956B/de active Pending
- 1965-03-01 GB GB865765A patent/GB1090122A/en not_active Expired
- 1965-03-02 FR FR7554A patent/FR1433631A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2618329A1 (en) * | 1987-07-22 | 1989-01-27 | Dow Corning Sa | METHOD FOR MANUFACTURING A RING CAPABLE OF ENSURING RELEASE OF A THERAPEUTIC AGENT, AND RING MADE THEREBY |
| US5886115A (en) * | 1997-02-18 | 1999-03-23 | Rensselaer Polytechnic Institute | Process for the direct polymerization of allyl ethers, crotyl ethers and allyl alcohols |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1245956B (en) | 1967-08-03 |
| FR1433631A (en) | 1966-04-01 |
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