GB1066458A - Unsaturated sulphonic acids and salts thereof - Google Patents
Unsaturated sulphonic acids and salts thereofInfo
- Publication number
- GB1066458A GB1066458A GB33497/64A GB3349764A GB1066458A GB 1066458 A GB1066458 A GB 1066458A GB 33497/64 A GB33497/64 A GB 33497/64A GB 3349764 A GB3349764 A GB 3349764A GB 1066458 A GB1066458 A GB 1066458A
- Authority
- GB
- United Kingdom
- Prior art keywords
- salts
- sulphonic acids
- formula
- acids
- valence
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Detergent compositions, particularly washing-up and laundry compositions, comprise unsaturated sulphonic acids and salts of formula <FORM:1066458/C4-C5/1> where R and R1 are each H or a C1-21 hydrophobic organic group which may contain substituents, the arithmetic sum of the number of carbon atoms in R plus R1 being 7 to 21, M is H, NH4 or an alkali or alkaline earth metal, including Mg, and x is the valence of M. The usual anionic, nonionic or ampholytic surfactants, builders, anti-redeposition agents, optical brighteners and bleaching agents may be present.ALSO:The invention comprises unsaturated sulphonic acids and salts of formula <FORM:1066458/C2/1> where R and R1 are each H or a C1- 21 hydrophobic organic group, the arithmetic sum of the number of carbon atoms in R plus R1 being 7 to 21, M is H, NH4 or an alkali or alkaline earth metal, including Mg, and x is the valence of M. The sulphonic acids are preferably prepared by reacting an olefinic compound of formula R-CH2-CH = CHR1, preferably dissolved in a neutral, anhydrous solvent, with SO3 or a complex of SO3 with a nitrogen-free organic substance at a temperature below 15 DEG C., and decomposing the resulting sultone by warming above 15 DEG C., preferably in the presence of a Lewis base solvent. Alternatively R-CH = CH-CHBrR1 may be reacted with a bisulphite. The salts are prepared by neutralizing the acids.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US302440A US3346629A (en) | 1963-08-15 | 1963-08-15 | Process for preparing beta-ethylenically unsaturated organic sulfonates |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1066458A true GB1066458A (en) | 1967-04-26 |
Family
ID=23167740
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB33497/64A Expired GB1066458A (en) | 1963-08-15 | 1964-08-17 | Unsaturated sulphonic acids and salts thereof |
Country Status (8)
Country | Link |
---|---|
US (1) | US3346629A (en) |
AU (1) | AU403871B2 (en) |
BE (1) | BE651783A (en) |
DE (1) | DE1299791B (en) |
FR (1) | FR1411808A (en) |
GB (1) | GB1066458A (en) |
LU (1) | LU46754A1 (en) |
NL (1) | NL6409378A (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3332877A (en) * | 1965-01-04 | 1967-07-25 | Procter & Gamble | Detergent composition |
CA787878A (en) * | 1965-01-04 | 1968-06-18 | F. Pflaumer Phillip | Detergent composition |
US3332880A (en) * | 1965-01-04 | 1967-07-25 | Procter & Gamble | Detergent composition |
GB1171617A (en) * | 1966-03-18 | 1969-11-26 | Unilever Ltd | Toilet Bar |
US3487104A (en) * | 1966-04-28 | 1969-12-30 | Gulf Research Development Co | Process for preparing alkene sulfonates |
US3531564A (en) * | 1966-09-15 | 1970-09-29 | Colgate Palmolive Co | Fluoride dental preparation |
US3332878A (en) * | 1966-12-05 | 1967-07-25 | Procter & Gamble | Detergent composition having synergistic sudsing properties containing amides and sulfonate-containing detergents |
US3332879A (en) * | 1966-12-05 | 1967-07-25 | Procter & Gamble | Ternary synergistic sudsing detergent compositions |
US3565809A (en) * | 1967-11-27 | 1971-02-23 | Chevron Res | Alpha olefin sulfonate detergent compositions |
US3637512A (en) * | 1968-07-22 | 1972-01-25 | Continental Oil Co | Hydrocarbon solvent composition |
US3676372A (en) * | 1968-10-24 | 1972-07-11 | Chevron Res | Hydrogenated olefin sulfonate-fatty acid amide detergent compositions |
US3819519A (en) * | 1968-11-27 | 1974-06-25 | Chevron Res | Foam circulation fluids |
US3673122A (en) * | 1969-03-27 | 1972-06-27 | Chevron Res | Hydrogenated olefin sulfonate detergent bars |
GB8900023D0 (en) * | 1989-01-03 | 1989-03-01 | Shell Int Research | Detergent composition |
JP6224390B2 (en) | 2012-09-20 | 2017-11-01 | 花王株式会社 | Internal olefin sulfonate composition and detergent composition containing the same |
CN104937088B (en) | 2013-02-13 | 2018-07-03 | 花王株式会社 | Internal alkene sulfonate composition |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2240920A (en) * | 1941-05-06 | Sulphonation of organic compounds | ||
US2303212A (en) * | 1939-05-26 | 1942-11-24 | Solvay Process Co | Soap composition |
US2243331A (en) * | 1939-08-29 | 1941-05-27 | Shell Dev | Sulphonate |
US2337552A (en) * | 1940-08-15 | 1943-12-28 | Du Pont | Purification of saturated hydrocarbon sulphonic acids |
DE899939C (en) * | 1943-03-04 | 1953-12-17 | Boehme Fettchemie G M B H | Process for the production of chlorinated or brominated sultones |
US2789133A (en) * | 1954-07-13 | 1957-04-16 | Rohm & Haas | Alkoxypentenyl sulfonates |
US2894912A (en) * | 1954-09-21 | 1959-07-14 | Lever Brothers Ltd | Isethionate detergent bar |
US2807642A (en) * | 1954-12-31 | 1957-09-24 | Universal Oil Prod Co | Method of sulfonation to produce inorganic salt-free product |
FR1307710A (en) * | 1960-12-09 | 1962-10-26 | Hoechst Ag | Process for the preparation of beta-hydroxy-alpha-sulfonic acid anhydrides and their derivatives |
-
1963
- 1963-08-15 US US302440A patent/US3346629A/en not_active Expired - Lifetime
-
1964
- 1964-08-10 FR FR984682A patent/FR1411808A/en not_active Expired
- 1964-08-12 LU LU46754A patent/LU46754A1/xx unknown
- 1964-08-13 BE BE651783A patent/BE651783A/xx unknown
- 1964-08-13 AU AU48110/64A patent/AU403871B2/en not_active Expired
- 1964-08-14 DE DEM62100A patent/DE1299791B/en active Pending
- 1964-08-14 NL NL6409378A patent/NL6409378A/xx unknown
- 1964-08-17 GB GB33497/64A patent/GB1066458A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
US3346629A (en) | 1967-10-10 |
NL6409378A (en) | 1965-02-16 |
BE651783A (en) | 1965-02-15 |
AU403871B2 (en) | 1970-06-25 |
DE1299791B (en) | 1969-07-24 |
FR1411808A (en) | 1965-09-24 |
AU4811064A (en) | 1966-02-17 |
LU46754A1 (en) | 1965-02-12 |
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