GB1065515A - Production of polyester compositions and shaped articles therefrom having an improved color - Google Patents
Production of polyester compositions and shaped articles therefrom having an improved colorInfo
- Publication number
- GB1065515A GB1065515A GB102165A GB102165A GB1065515A GB 1065515 A GB1065515 A GB 1065515A GB 102165 A GB102165 A GB 102165A GB 102165 A GB102165 A GB 102165A GB 1065515 A GB1065515 A GB 1065515A
- Authority
- GB
- United Kingdom
- Prior art keywords
- radical
- atoms
- halohydrocarbyl
- chain
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000728 polyester Polymers 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 5
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000005160 aryl oxy alkyl group Chemical group 0.000 abstract 1
- 239000006085 branching agent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 125000002541 furyl group Chemical group 0.000 abstract 1
- 150000002334 glycols Chemical class 0.000 abstract 1
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/32—Esters thereof
- C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/3211—Esters of acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
- C07F9/5304—Acyclic saturated phosphine oxides or thioxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
- C08K5/5337—Esters of phosphonic acids containing also halogens
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Linear polyesters are stabilized by addition of compounds <FORM:1065515/C3/1> <FORM:1065515/C3/2> where R is an alkyl, haloalkyl, alkenyl, haloalkenyl, alkoxyalkyl, aryloxyalkyl, alkoxyhaloalkyl or aryloxyhaloalkyl radical of 1-12 C atoms, R1 is -OR or an aromatic hydrocarbyl or halohydrocarbyl radical of 6-12 C atoms, Z is hydrogen, or a hydrocarbyl, halohydrocarbyl, carboalkoxyhydrocarbyl, alkylthiohydrocarbyl, alkoxyhydrocarbyl or cyanohydrocarbyl radical of 1-17 C atoms or a furyl or thienyl radical, and n is an integer. Amounts of stabilizer of 0.05 to 0.30% of the total composition are suitable. The polyesters may be prepared from dicarboxylic acids and glycols (lists given), preferably from dimethyl terephthalate or terephthalic acid and ethylene glycol. They may be modified by addition of 0.05-4.0 mole per cent of the diacid or ester of a chain-terminator, e.g. monohydroxy polyethers, e.g. methoxypolyethylene glycol, and/or 0.05-2.4 mole per cent of a chain-branching or cross-linking agent, e.g. aliphatic and aromatic polyalcohols, or polycarboxylic acid esters, having more than two functional groups.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US33714964A | 1964-01-13 | 1964-01-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1065515A true GB1065515A (en) | 1967-04-19 |
Family
ID=23319322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB102165A Expired GB1065515A (en) | 1964-01-13 | 1965-01-08 | Production of polyester compositions and shaped articles therefrom having an improved color |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE658241A (en) |
| FR (1) | FR1428007A (en) |
| GB (1) | GB1065515A (en) |
| LU (1) | LU47765A1 (en) |
| NL (1) | NL6500381A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4377653A (en) * | 1981-01-30 | 1983-03-22 | Fmc Corporation | Mixed ether compositions containing oligomers of polyfunctional phosphine oxides: flame retardants for polymers |
| IT1213588B (en) * | 1986-07-23 | 1989-12-20 | Enichem Sintesi | OLIGOMERIC FLAME RESISTANT ADDITIVE, PROCEDURE FOR ITS PREPARATION AND USE TO MAKE A LINEAR POLYESTER FLAME RESISTANT. |
-
1965
- 1965-01-08 GB GB102165A patent/GB1065515A/en not_active Expired
- 1965-01-11 LU LU47765D patent/LU47765A1/xx unknown
- 1965-01-13 NL NL6500381A patent/NL6500381A/xx unknown
- 1965-01-13 FR FR1728A patent/FR1428007A/en not_active Expired
- 1965-01-13 BE BE658241A patent/BE658241A/xx not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE658241A (en) | 1965-07-13 |
| FR1428007A (en) | 1966-02-11 |
| NL6500381A (en) | 1965-07-14 |
| LU47765A1 (en) | 1965-07-12 |
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